Catalytic depolymerisation of polymeric materials

• US 10,000,715 B2
• Filed: 01/17/2013
• Issued: 06/19/2018
• Est. Priority Date: 01/17/2013
• Status: Active Grant

• Current Assignee: Greenmantra Recycling Technologies Ltd.
• Original Assignee: Greenmantra Recycling Technologies Ltd.
• Inventors: Kumar, Anil, Kumar, Pushkar
• Primary Examiner(s): Louie, Philip Y
• Assistant Examiner(s): Pierpont, Aaron W
• Application Number:
  US14/761,779
• Publication Number:
  US 20150361374A1
• Time in Patent Office: 1,979 Days
• Field of Search: 585241, 585832, 502211
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 10/02 Ethene
• CPC Class Codes: C08F 110/06 Propene
• CPC Class Codes: C08F 8/50 Partial depolymerisation
• CPC Class Codes: C08J 11/10 by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation depolymerisation to the original monomer C07
• CPC Class Codes: C08J 2323/06 Polyethene
• CPC Class Codes: C10G 1/10 from rubber or rubber waste
• CPC Class Codes: C10M 107/02 Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
• CPC Class Codes: C10M 175/0025 by thermal processes
• CPC Class Codes: C10M 177/00 Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
• CPC Class Codes: C10M 2205/0225 used as base material
• CPC Class Codes: C10M 2205/0245 used as base material
• CPC Class Codes: C10M 2205/14 Synthetic waxes, e.g. polythene waxes
• CPC Class Codes: C10M 2207/126 monocarboxylic
• CPC Class Codes: C10N 2020/02 Viscosity; Viscosity index
• CPC Class Codes: C10N 2050/10 Semi-solids; greasy
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling

Abstract

A process for converting a molten polymeric material is provided. The process includes effecting disposition of a molten polymeric material, having at least one carbon-carbon double bond, in sufficient proximity to a catalyst material within a reaction zone, to effect a reactive process that effects generation of a reaction product. The reactive process effects cleaving of at least one carbon-carbon double bond. The catalyst material includes [Fe—Cu—Mo—P]/Al₂O₃ prepared by binding a ferrous-copper complex to an alumina support to generate an intermediate material, and reacting the intermediate material with a heteropolyacid.

Claims

1. A process for converting a molten polymeric material, comprising:

providing a molten polymeric material having at least one carbon-carbon double bond; and

contacting the molten polymeric material with a catalyst material in a reaction zone to cleave at least one carbon-carbon double bond and produce a reaction product,

wherein the catalyst material includes [Fe—

Cu—

Mo—

P]/Al₂O₃ prepared by binding a ferrous-copper complex to an alumina support to generate an intermediate material, and reacting the intermediate material with an Mo- and P-containing heteropolyacid.

2. The process as claimed in claim 1, wherein the contacting further comprises:

heating the reaction zone to a temperature suitable for cleaving at least one carbon-carbon double bond to produce the reaction product and suspending the heating when the pressure within the reaction zone reaches a predetermined pressure.

3. The process as claimed in claim 2,

wherein the predetermined pressure is correlated with at least one property of the reaction product.

4. The process as claimed in claim 1, wherein providing the molten polymeric material comprises heating a polymeric material to produce the molten polymeric material.

5. The process as claimed in claim 2, wherein the reaction product comprises waxes and grease base stocks, further comprising:

varying the predetermined pressure to produce different grades of waxes and grease base stocks.

6. The process as claimed in claim 1,

wherein the molten polymeric material further comprises at least one second polymeric material, wherein the second polymeric material is selected from the group consisting of polyethylene, polypropylene, polyethylene terephthalate, ethylene-vinyl acetate, polyphenylene ether, polyvinyl chloride, polystyrene, lignin, nylon, cellulose, and mixtures thereof.

7. The process as claimed in claim 1, wherein the molten polymeric material further comprises polyethylene.

8. The process as claimed in claim 1, wherein the molten polymeric material further comprises polypropylene.

9. The process as claimed in claim 1,

wherein the molten polymeric material includes waste polymeric material.

10. The process as claimed in claim 1, wherein cleaving the at least one carbon-carbon double bond comprises depolymerisation.

11. A process for converting polymeric material to make waxes or grease base stocks through catalytic depolymerisation, comprising:

preheating the polymeric material to form a molten polymeric material;

catalytically depolymerizing the molten polymeric material in a high pressure reactor in the presence of a catalyst material at a temperature in the range of 300°

C. to 600°

C. until a pressure in the high pressure reactor reaches a predetermined value in the range of 50 psig to 350 psig, wherein the high pressure reactor comprises heaters and wherein the temperature is maintained using the heaters; and

turning off the heaters and stopping the catalytic depolymerisation when the pressure in the high pressure reactor reaches the predetermined value and wherein the molten polymeric material is converted to a wax or a grease base stock,

wherein the catalyst material is [Fe—

Cu—

Mo—

P]/Al₂O₃ prepared by binding a ferrous-copper complex to an alumina support to generate an intermediate material, and reacting the intermediate material with an Mo- and P-containing heteropolyacid.

12. The process as claimed in claim 11, further comprising:

draining the wax or grease base stock into a container when the wax or grease base stock is liquid and is at a temperature above the flash point of the wax or grease base stock, respectively.

13. The process as claimed in claim 11, wherein preheating the polymeric material to form the molten polymeric material comprises:

preheating the polymeric material using an extruder to form the molten polymeric material, wherein the extruder is in fluid communication with the high pressure reactor for feeding the molten polymeric material to the high pressure reactor.

14. The process as claimed in claim 13, further comprising:

continuously feeding the molten polymeric material into the high pressure reactor.

15. The process as claimed in claim 11, further comprising:

varying the predetermined value of the pressure in the high pressure reactor to produce different grades of waxes and grease base stocks.

16. The process as claimed in claim 12, further comprising:

inducing coalescence of pigment particles/impurities in the drained wax or drained grease base stock using a high to low pressure cycle, wherein

(i) the pigment particles/impurities and (ii) the drained wax or drained grease base stock settle in the container as separate layers.

17. The process as claimed in claim 11,

wherein the polymeric material includes polyethylene, polypropylene, polyethylene terephthalate, ethylene-vinyl acetate, polyphenylene ether, polyvinyl chloride, polystyrene, lignin, nylon, or cellulose.

18. The process as claimed in claim 11,

wherein the polymeric material is polyethylene.

19. The process as claimed in claim 11,

wherein the polymeric material is polypropylene.

20. The process as claimed in claim 11,

wherein the polymeric material includes waste polymeric material.

21. A process for converting primary granules of polymeric material to make waxes or grease base stocks through catalytic depolymerisation, comprising:

preheating the primary granules of polymeric material to form molten primary granules of polymeric material;

catalytically depolymerizing the molten primary granules of polymeric material in a high pressure reactor in the presence of a catalyst material at a temperature in the range of 300°

C. to 600°

C. until a pressure in the high pressure reactor reaches a predetermined value in the range of 50 psig to 350 psig, wherein the high pressure reactor comprises heaters and wherein the temperature is maintained using the heaters; and

turning off the heaters and stopping the catalytic depolymerisation when the pressure in the high pressure reactor reaches the predetermined value and wherein the molten primary granules of polymeric material are converted to a wax or a grease base stock,

wherein the catalyst material is [Fe—

Cu—

Mo—

P]/Al₂O₃ prepared by binding a ferrous-copper complex to an alumina support to generate an intermediate material, and reacting the intermediate material with an Mo- and P-containing heteropolyacid.

22. The process of claim 21, further comprising:

draining the wax or grease base stock into a container when the wax or grease base stock is liquid and is at a temperature above the flash point of the wax or grease base stock, respectively;

inducing coalescence of pigment particles/impurities in the drained wax or drained grease base stock using a high to low pressure cycle, wherein (i) the pigment particles/impurities and (ii) the drained wax or drained grease base stock settle in the container as separate layers.

23. The process of claim 21, wherein preheating the primary granules of polymeric material to form the molten primary granules of polymeric material comprises:

preheating the primary granules of polymeric material using an extruder to form the molten primary granules of polymeric material, wherein the extruder is in fluid communication with the high pressure reactor for feeding the molten primary granules of polymeric material to the high pressure reactor; and

continuously feeding the molten primary granules of polymeric material into the high pressure reactor.