Solid fast draining/drying rinse aid for high total dissolved solid water conditions

• US 10,000,725 B2
• Filed: 03/17/2015
• Issued: 06/19/2018
• Est. Priority Date: 06/22/2012
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: Kieffer, Janel Marie, Man, Victor Fuk-Pong, Hunter, Melissa
• Primary Examiner(s): Douyon, Lorna M
• Application Number:
  US14/659,679
• Publication Number:
  US 20150191680A1
• Time in Patent Office: 1,190 Days
• Field of Search: None
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/722 Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups C11D1/721 takes precedence
• CPC Class Codes: C11D 1/825 Mixtures of compounds all of which are non-ionic
• CPC Class Codes: C11D 17/0047 Detergents in the form of bars or tablets
• CPC Class Codes: C11D 2111/18 Glass; Plastics
• CPC Class Codes: C11D 3/0021 Dye-stain or dye-transfer inhibiting compositions
• CPC Class Codes: C11D 3/2068 Ethers
• CPC Class Codes: C11D 3/3418 Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates

Abstract

A solid rinse aid composition and methods of making and using the same are described. Applicants have surprisingly found that the crystal modifier sodium xylene sulfonate (short chain alkyl benzene or alkyl naphthalene sulfonates) at higher percentage can act as a solidification agent. The solid rinse aid composition generally includes a short chain alkyl benzene or alkyl naphthalene sulfonates solidification agent and an effective amount of a surfactant which can include a sheeting agent component, defoamer component and/or association disruption agent. The solid rinse aid composition may be phosphate-free, aminocarboxylate-free, and GRAS if desired.

Claims

1. A solid rinse aid composition consisting of:

from about 65 wt. % to about 85 wt. % of one or more short chain alkyl benzene and/or alkyl naphthalene sulfonates, selected from the group consisting of;

sodium xylene sulfonate, sodium toluene sulfonate, sodium cumene sulfonate, potassium toluene sulfonate, ammonium xylene sulfonate, calcium xylene sulfonate, sodium alkyl naphthalene sulfonate, sodium butylnaphthalene sulfonate, and mixtures thereof for solidification of the rinse aid composition;

a surfactant system including;

an association disruption agent, from about 1 wt. % to about 10 wt. % of a sheeting agent and a defoamer; and

optionally;

preservative;

solidification agent;

water;

chelating/sequestering agent;

bleaching agent;

bleach activator;

sanitizer/antimicrobial agent;

anti-redeposition agent;

optical brightener;

dye;

odorant;

polydimethylsiloxane;

humectant;

enzyme and/or pH modifier, wherein the solid rinse aid is in a form of a solid block and wherein a use solution of the solid rinse aid composition has a pH of less than 4.

2. The solid rinse aid composition of claim 1 wherein said short chain alkyl benzene and/or alkyl naphthalene sulfonate is sodium xylene sulfonate.

3. The solid rinse aid composition of claim 1 wherein said one or more short chain alkyl benzene and/or alkyl maphthalene sulfonate is present in an amount of from about 70 wt % to about 80 wt % and wherein said one or more short chain alkyl benzene and/or alkyl naphthalene sulfonates is sodium xylene sulfonate.

4. The solid rinse aid composition of claim 1 wherein said association disruption agent is an alcohol alkoxylate and the alkoxylate is selected from the group consisting of ethylene oxides, propylene oxides, butylene oxides, pentylene oxides, hexylene oxides, heptylene oxides, octylene oxides, nonylene oxides, decylene oxides and mixtures and derivatives thereof.

5. The solid rinse aid composition of claim 1 wherein said sheeting agent comprises one or more alcohol ethoxylates of Formula (I):

R—

O—

(CH₂CH₂O)_n—

H 

 

(I)

wherein R is a C₁-C₁₂ alkyl group, and n is an integer in the range of 1 to 100.

6. The solid rinse aid composition of claim 5, wherein n is an integer in the range of 15 to 30.

7. The solid rinse aid composition of claim 1 wherein the preservative is present in the solid rinse aid composition.

8. The solid rinse aid composition of claim 1 wherein said defoamer component comprises a block copolymer compound including one or more ethylene oxide groups.

9. The solid rinse aid composition of claim 1, wherein the chelating/sequestering agent is present in the rinse aid composition, and wherein the chelating agent/sequestering agent is a polymeric polycarboxylate.

10. The solid rinse aid composition of claim 1, wherein the chelating/sequestering agent is present in the rinse aid composition.

11. A method for making a pressed solid rinse aid composition according to claim 1 comprising:

(a) mixing from about 65 wt. % to about 85 wt. % of one or more short chain alkyl benzene and/or alkyl naphthalene sulfonates, selected from the group consisting of;

sodium xylene sulfonate, sodium toluene sulfonate, sodium cumene sulfonate, potassium toluene sulfonate, ammonium xylene sulfonate, calcium xylene sulfonate, sodium alkyl naphthalene sulfonate, and sodium butylnaphthalene sulfonate for solidification of the rinse aid composition;

a surfactant system including;

an association disruption agent, from about 1 wt. % to about 10 wt. % of a sheeting agent and a defoamer; and

optionally;

preservative;

solidification agent;

water;

chelating/sequestering agent;

bleaching agent;

bleach activator;

sanitizer/antimicrobial agent;

anti-redeposition agent;

optical brightener;

dye;

odorant;

polydimethylsiloxane;

humectant;

enzyme and/or pH modifier, and thereafter;

(b) pressing said composition to form a solid block and wherein a use solution of the solid rinse aid composition has a pH of less than 4.

12. The method of claim 11 wherein said one or more short chain alkyl benzene and/or alkyl naphthalene sulfonates is sodium xylene sulfonate.

13. The method of claim 11 wherein said association disruption agent includes two or more of ethylene oxides, propylene oxides, butylene oxides, pentylene oxides, hexylene oxides, heptylene oxides, octylene oxides, nonylene oxides, decylene oxides and mixtures and derivatives thereof.

14. The method of claim 11 wherein said defoamer is a polyoxypropylene-polyoxyethylene block copolymer surfactant.

15. The method of claim 11 wherein the chelating/sequestering agent is present in the rinse aid composition, and wherein the chelating agent/sequestering agent is a polymeric polycarboxylate.

16. The method of claim 15 wherein said polycarboxylate polymer is an acrylic acid homopolymer.

17. A solid rinse aid composition consisting of:

(a) from about 1 wt. % to about 10 wt. % of a sheeting agent, wherein the sheeting agent comprises at least one compound having the structure represented by formula I;

R—

O—

(CH₂CH₂O)_n—

H wherein R is a C₁-C₁₂ alkyl group, and n is an integer in the range of 1 to 100;

(b) a defoaming agent comprising a polyoxypropylene-polyoxyethylene block copolymer surfactant;

(c-1) a first association disruption agent which is an alcohol alkoxylate EO/BO surfactant;

(c-2) a second association disruption agent which is a C12-C14 fatty alcohol EO/PO surfactant;

(d) from about 65 wt. % to about 85 wt. % of a hardening agent of one or more of sodium toluene sulfonate, sodium cumene sulfonate, potassium toluene sulfonate, ammonium xylene sulfonate, calcium xylene sulfonate, sodium alkyl naphthalene sulfonate, and sodium butylnaphthalene sulfonate, and sodium xylene sulfonate; and

optionally;

preservative;

solidification agent;

water;

chelating/sequestering agent;

bleaching agent;

bleach activator;

sanitizer/antimicrobial agent;

anti-redeposition agent;

optical brightener;

dye;

odorant;

polydimethylsiloxane;

humectant;

enzyme and/or pH modifier,

wherein the solid rinse aid composition is in a form of a solid block and wherein a use solution of the solid rinse aid composition has a pH of less than 4.

18. The solid rinse aid composition of claim 17, wherein the solidification agent is present in the solid rinse aid composition in an amount from about 1 wt. % to about 10 wt. %.

19. The solid rinse aid composition of claim 17 wherein the chelating/sequestering agent is present in the rinse aid composition, and wherein the chelating agent/sequestering agent is a polymeric polycarboxylate.

20. The solid rinse aid composition of claim 19 wherein said polycarboxylate polymer is an acrylic acid homopolymer.