Insulating glass unit transparent conductive coating technology

• US 10,000,965 B2
• Filed: 11/06/2015
• Issued: 06/19/2018
• Est. Priority Date: 01/16/2010
• Status: Active Grant

• Current Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Original Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Inventors: Burrows, Keith James, Myli, Kari B.
• Primary Examiner(s): Loney, Donald J
• Application Number:
  US14/934,664
• Publication Number:
  US 20160060949A1
• Time in Patent Office: 956 Days
• CPC Class Codes: B32B 17/10055 with at least one intermediate air space
• CPC Class Codes: B32B 17/10467 Variable transmission
• CPC Class Codes: C03C 17/3411 with at least two coatings of inorganic materials C03C17/36, C03C17/42 take precedence
• CPC Class Codes: C03C 2217/94 Transparent conductive oxide layers [TCO] being part of a multilayer coating
• CPC Class Codes: C03C 2217/948 Layers comprising indium tin oxide [ITO]
• CPC Class Codes: E06B 3/6612 Evacuated glazing units
• CPC Class Codes: E06B 3/6715 specially adapted for increased thermal insulation or for controlled passage of light E06B3/66323 takes precedence; coating of glass pains C03C17/00; devices or arrangements for controlling the intensity, colour, phase, polarisation or direction of light G02F1/00
• CPC Class Codes: E06B 3/6722 with adjustable passage of light
• CPC Class Codes: E06B 3/677 Evacuating or filling the gap between the panes ; Equilibration of inside and outside pressure; Preventing condensation in the gap between the panes by means of spacing elements E06B3/663; Cleaning the gap between the panes
• CPC Class Codes: Y02A 30/249 Glazing, e.g. vacuum glazing
• CPC Class Codes: Y02B 80/22 Glazing, e.g. vaccum glazing

Abstract

The invention provides flash-treated transparent conductive coatings based on indium tin oxide. Some embodiments provide a multiple-pane insulating glazing unit that includes two glass panes and a between-pane space. The two glass panes respectively define two opposed external pane surfaces. At least one of the two external pane surfaces has a flash-treated transparent conductive oxide coating.

Claims

1. A multiple-pane insulating glazing unit comprising two glass panes and a between-pane space, the two glass panes respectively defining two opposed external pane surfaces, a desired one of the two external pane surfaces having a flash-treated transparent electrically conductive coating such that a desired one of the two glass panes is a coated glass pane, said coated glass pane being annealed glass having a surface stress of less than 3,500 psi, the flash-treated transparent electrically conductive coating comprising a flash-treated indium tin oxide film and an overcoat film on the flash-treated indium tin oxide film, wherein the overcoat film comprises silicon nitride and/or silicon oxynitride, the overcoat film comprising silicon nitride and/or silicon oxynitride being in contact with the flash-treated indium tin oxide film, the flash-treated transparent electrically conductive coating being exposed such that the overcoat film comprising silicon nitride and/or silicon oxynitride is an outermost film, the flash-treated indium tin oxide film having a thickness of less than 1,800Å

, the flash-treated indium tin oxide film being a sputtered film having a surface roughness of less than 3 nm, the flash-treated indium tin oxide film having a sheet resistance of less than 15Ω

/square in combination with said coated glass pane having a monolithic visible transmittance of greater than 0.82, the flash-treated indium tin oxide film having an optical bandgap of 370 nm or shorter and being characterized by a pre-flash optical bandgap of 400 nm or longer, the flash-treated indium tin oxide film having a morphology characterized by ultra-high-power flash treatment at 15-45 kW/cm², the flash-treated indium tin oxide film having a carrier concentration of 9-13 ×

10²⁰/cm³.

2. The multiple-pane insulating glazing unit of claim 1 wherein the flash-treated indium tin oxide film is characterized by a carrier concentration factor of at least 5.

3. The multiple-pane insulating glazing unit of claim 2 wherein the carrier concentration factor is at least 7.5.

4. The multiple-pane insulating glazing unit of claim 1 wherein the flash-treated indium tin oxide film is characterized by a Δ

A of five percent or more.

5. The multiple-pane insulating glazing unit of claim 4 wherein the Δ

A is seven percent or more.

6. The multiple-pane insulating glazing unit of claim 1 wherein the thickness of the flash-treated indium tin oxide film is less than 1,500Å

and the sheet resistance is less than 13 Ω

/square.

7. The multiple-pane insulating glazing unit of claim 6 wherein the thickness of the flash-treated indium tin oxide film is between 1,050Å

and 1,450Å

in combination with the monolithic visible transmittance of said coated glass pane being greater than 0.86 but less than 0.92 and the sheet resistance of the flash-treated indium tin oxide film being greater than 10 Ω

/square but less than 13Ω

/square.

8. The multiple-pane insulating glazing unit of claim 1 wherein the flash-treated indium tin oxide film is non-porous.

9. The multiple-pane insulating glazing unit of claim 1 wherein the overcoat film has a thickness of between 100Å

and 1,300Å

.

10. The multiple-pane insulating glazing unit of claim 1 wherein the flash-treated indium tin oxide film is in contact with said desired external pane surface, such that the flash-treated transparent electrically conductive coating is devoid of any sodium ion blocker layer between the flash-treated indium tin oxide film and the underlying glass pane, the flash-treated indium tin oxide film having a sodium concentration of less than 100 ppm.

11. The multiple-pane insulating glazing unit of claim 1 wherein the multiple-pane insulating glazing unit has an internal pane surface bearing a low-emissivity coating that includes at least one film comprising silver, the low-emissivity coating being exposed to the between-pane space, the multiple-pane insulating glazing unit having a U value of less than 0.25 together with an IGU visible transmittance of greater than 0.60.

12. The multiple-pane insulating glazing unit of claim 11 wherein the multiple-pane insulating glazing unit exhibits an exterior reflected color characterized by an “

a_h”

color coordinate of between −

7 and 2 and a “

b_h”

color coordinate of between −

9 and 0.

13. The multiple-pane insulating glazing unit of claim 1 wherein the surface roughness of the flash-treated indium tin oxide film is between 1.5 and 3.0.

14. A multiple-pane insulating glazing unit comprising two glass panes and a between-pane space, the two glass panes respectively defining two opposed external pane surfaces, a desired one of the two external pane surfaces having a flash-treated transparent electrically conductive coating such that a desired one of the two glass panes is a coated glass pane, said coated glass pane being annealed glass having a surface stress of less than 3,500 psi, the transparent electrically conductive coating comprising a flash-treated indium tin oxide film and an overcoat film on the flash-treated indium tin oxide film, wherein the overcoat film comprises silicon nitride and/or silicon oxynitride, the overcoat film comprising silicon nitride and/or silicon oxynitride being in contact with the flash-treated indium oxide film, the flash-treated transparent electrically conductive coating being exposed such that the overcoat film comprising silicon nitride and/or silicon oxynitride is an outermost film, the flash-treated indium tin oxide film having a thickness of between 1,050Å

and 1,800Å

, the flash-treated indium tin oxide film being a sputtered film having a surface roughness of between 1.5 nm and 3 nm, the flash-treated indium tin oxide film having a sheet resistance of greater than 10Ω

/square but less than 15Ω

/square in combination with said coated glass pane having a monolithic visible transmittance of greater than 0.86 but less than 0.92, the flash-treated indium tin oxide film having an optical bandgap of 370 nm or shorter and being characterized by a pre-flash optical bandgap of 400 nm or longer, the flash-treated indium tin oxide film having a morphology characterized by ultra-high-power flash treatment at 15-45 kW/cm², the flash-treated indium tin oxide film having a carrier concentration of 9-13 ×

10²⁰/cm³.

15. The multiple-pane insulating glazing unit of claim 14 wherein the flash-treated indium tin oxide film is characterized by a carrier concentration factor of at least 5.

16. The multiple-pane insulating glazing unit of claim 15 wherein the carrier concentration factor is at least 7.5.

17. The multiple-pane insulating glazing unit of claim 14 wherein the flash-treated indium tin oxide film is characterized by a Δ

A of nine percent or more.

18. The multiple-pane insulating glazing unit of claim 14 wherein the flash-treated indium tin oxide film is in contact with said desired external pane surface such that the flash-treated transparent electrically conductive coating is devoid of any sodium ion blocker layer between the flash-treated indium tin oxide film and the underlying glass pane, the flash-treated indium tin oxide film having a sodium concentration of less than 100 ppm.