Solid silver-copper alloy having mainly a non-eutectic structure not containing a eutectic at room temperature

• US 10,006,105 B2
• Filed: 08/16/2012
• Issued: 06/26/2018
• Est. Priority Date: 11/16/2011
• Status: Active Grant

• Current Assignee: M Technique Co., Ltd.
• Original Assignee: M Technique Co., Ltd.
• Inventors: Maekawa, Masaki, Honda, Daisuke, Enomura, Masakazu
• Primary Examiner(s): Dunn, Colleen P
• Assistant Examiner(s): Wang, Nicholas A
• Application Number:
  US14/355,855
• Publication Number:
  US 20140301892A1
• Time in Patent Office: 2,140 Days
• CPC Class Codes: B22F 1/054 Nanosized particles
• CPC Class Codes: B22F 7/06 of composite workpieces or articles from parts, e.g. to form tipped tools B22F7/002 takes precedence
• CPC Class Codes: B22F 9/24 starting from liquid metal compounds, e.g. solutions
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C22C 9/00 Alloys based on copper
• CPC Class Codes: Y02P 10/25 Process efficiency

Abstract

The present invention addresses the problem of providing a novel, solid silver-copper alloy. Provided is a solid silver-copper alloy in which the concentration of copper contained in the silver-copper alloy is 0.1-99.94 wt %, and which has, as the principal constituent thereof, a non-eutectic structure which does not contain a eutectic when the solid silver-copper alloy is at room temperature. This silver-copper alloy can be produced by mixing a fluid containing silver ions and copper ions with a fluid containing a reducing agent, and separating silver-copper alloy particles therefrom. It is preferable to mix the fluid containing the silver ions and copper ions with the fluid containing the reducing agent in a thin-film fluid formed between processing surfaces arranged so as to face one another, capable of approaching toward and separating from one another, and capable of having at least one surface rotate relative to the other. The diameter of the particles of the silver-copper alloy is preferably 50 nm or less. This solid silver-metal alloy may also be a solid alloy comprising one or more types of other metals in addition to silver and copper.

Claims

1. A method for producing a silver-copper alloy particle, that is a solid silver-copper alloy having 0.1 to 99.94% by weight of copper concentration contained in the silver-copper alloy, and said solid silver-copper alloy has a non-eutectic structure in an amount of 50% or more by volume wherein the non-eutectic structure does not contain a eutectic at room temperature, said method comprising the steps of:

providing at least two fluids of a first fluid and a second fluid to be processed between at least two processing surfaces which are able to approach to and separate from each other and be made movable relatively, the first fluid containing silver ions and copper ions, the second fluid containing a reducing agent;

keeping a distance between the processing surfaces in a space being less than 1 mm by a balance between a force in the approaching direction and a force in the separating direction, including supply pressure of the fluid to be processed and pressure exerted between at least two processing surfaces that rotates relatively;

allowing the space maintained between at least two processing surfaces to serve as a flow path of the fluid to be processed, whereby the fluid to be processed forms a thin film fluid; and

mixing the fluids to be processed in the thin film fluid thereby separating particles of the silver-copper alloy in the thin film fluid;

wherein the reducing agent is comprised of at least two kinds of reducing agents, and silver and copper are separated simultaneously by using the at least two kinds of reducing agents.

2. A silver-copper alloy made by the method of claim 1, wherein the silver-copper alloy is a solid silver-copper alloy having 0.1 to 99.94% by weight of copper concentration contained in the silver-copper alloy, and the said solid silver-copper alloy has a non-eutectic structure in an amount of 50% or more by volume wherein the non-eutectic structure does not contain a eutectic at room temperature.

3. The silver-copper alloy according to claim 1, wherein the silver-copper alloy is obtained by mixing a silver ion, a copper ion, and a reducing agent in a thin film fluid formed between at least two processing surfaces which are disposed in a position they are faced with each other so as to be able to approach to and separate from each other, at least one of which rotates relative to the other, whereby separating a silver-copper alloy particle.

4. The silver-copper alloy according to claim 3, wherein the reducing agent comprises at least two reducing agents, wherein the said at least two reducing agents are at least two reducing agents selected from hydrazines and amines.

5. The silver-copper alloy according to claim 4, wherein the at least two reducing agents are hydrazine monohydrate and dimethylamino ethanol.

6. The silver-copper alloy according to claim 1, wherein the silver-copper alloy is a solid solution.

7. The silver-copper alloy according to claim 1, wherein both silver and copper are detected in the silver-copper alloy at all of the analysis points as a result of analysis within a space defined by the beam diameter of 5 nm by using TEM-EDS analysis.

8. The silver-copper alloy according to claim 1, wherein both silver and copper are detected in the silver-copper alloy at all of the analysis points as a result of analysis within a space defined by the beam diameter of 0.2 nm by using STEM-EDS analysis.

9. The silver-copper alloy according to claim 1, wherein the silver-copper alloy is a silver-copper alloy particle having 0.1 to 99.94% by weight as the concentration of copper contained in the silver-copper alloy.

10. The silver-copper alloy according to claim 1, wherein the silver-copper alloy comprises particles whose particle diameters are 50 nm or less.

11. The silver-copper alloy according to claim 1, wherein the silver-copper alloy does not have crystal grain boundary.

12. The silver-copper alloy according to claim 1, wherein the silver-copper alloy is a silver-copper alloy particle not treated by heat under dry condition.

13. The silver-copper alloy according to claim 1, wherein the silver-copper alloy is produced by mixing a fluid which contains a silver ion and a copper ion with a fluid which contains a reducing agent to separate a silver-copper alloy particle.

14. The silver-copper alloy according to claim 1, wherein the silver-copper alloy contains tin in addition to silver and copper.

15. The silver-copper alloy according to claim 1, wherein said solid silver-copper alloy has a non-eutectic structure in an amount of 65% or more by volume wherein the non-eutectic structure does not contain a eutectic at room temperature.

16. The silver-copper alloy according to claim 1, wherein said solid silver-copper alloy has 0.1 to 84.3% by weight of copper concentration contained in the silver-copper alloy.

17. The method for producing a silver-copper alloy particle according to claim 1, wherein the at least two kinds of reducing agents are at least two kinds of reducing agents selected from hydrazines and amines, and a pH of the fluid after mixing is in the range of 8 to 13.

18. The method for producing a silver-copper alloy particle according to claim 1, wherein at least one of the first fluid and the second fluid contains a dispersant showing a reducing property, and the reducing agent and the dispersant showing a reducing property are used together.

19. A silver-copper alloy, wherein the silver-copper alloy is a solid silver-copper alloy having 0.1 to 99.94% by weight of copper concentration contained in the silver-copper alloy, and the said solid silver-copper alloy has a non-eutectic structure in an amount of 50% or more by volume wherein the non-eutectic structure does not contain a eutectic at room temperature, wherein, as a result of analysis of mole ratios therein of silver to copper in a space defined by the beam diameter of 5 nm using TEM-EDS analysis, in 50% or more of analysis points, the mole ratios of silver to copper in the said solid silver-copper alloy are detected within ±

30% of the mole ratios of silver to copper obtained by ICP analysis results of the said solid silver-copper alloy.

20. The silver-copper alloy according to claim 19, wherein the silver-copper alloy is obtained by mixing a silver ion, a copper ion, and a reducing agent in a thin film fluid formed between at least two processing surfaces which are disposed in a position they are faced with each other so as to be able to approach to and separate from each other, at least one of which rotates relative to the other, whereby separating a silver-copper alloy particle.

21. The silver-copper alloy according to claim 19, wherein the silver-copper alloy is a solid solution.

22. The silver-copper alloy according to claim 19, wherein both silver and copper are detected in the silver-copper alloy at all of the analysis points as a result of analysis within a space defined by the beam diameter of 5 nm by using TEM-EDS analysis.

23. A silver-copper alloy, wherein the silver-copper alloy is a solid silver-copper alloy having 0.1 to 99.94% by weight of copper concentration contained in the silver-copper alloy, and the said solid silver-copper alloy has a non-eutectic structure in an amount of 50% or more by volume wherein the non-eutectic structure does not contain a eutectic at room temperature, wherein, as a result of analysis of mole ratios of silver to copper in a space defined by the beam diameter of 0.2 nm using STEM-EDS analysis, in 50% or more of analysis points, the mole ratios of silver to copper in the said solid silver-copper alloy are detected within ±

30% of the mole ratios of silver to copper obtained by ICP analysis results of the said solid silver-copper alloy.

24. The silver-copper alloy according to claim 23, wherein the silver-copper alloy is obtained by mixing a silver ion, a copper ion, and a reducing agent in a thin film fluid formed between at least two processing surfaces which are disposed in a position they are faced with each other so as to be able to approach to and separate from each other, at least one of which rotates relative to the other, whereby separating a silver-copper alloy particle.

25. The silver-copper alloy according to claim 23, wherein the silver-copper alloy is a solid solution.