Phosphor-containing identification substance and method for producing the same

• US 10,017,000 B2
• Filed: 03/18/2015
• Issued: 07/10/2018
• Est. Priority Date: 05/09/2014
• Status: Active Grant

• Current Assignee: Fuji Polymer Industries Co., Ltd. (Chugai Co., Ltd.)
• Original Assignee: Fuji Polymer Industries Co., Ltd. (Chugai Co., Ltd.)
• Inventors: Saruyama, Toshio, Goto, Makoto, Kataishi, Takumi
• Primary Examiner(s): Loewe, Robert S
• Application Number:
  US14/903,219
• Publication Number:
  US 20160144650A1
• Time in Patent Office: 1,210 Days
• Field of Search: None
• CPC Class Codes: B29C 43/003 characterised by the choice of material
• CPC Class Codes: B29C 43/305 Making multilayered articles
• CPC Class Codes: B29K 2083/00 Use of polymers having silicon, with or without sulfur, nitrogen, oxygen, or carbon only, in the main chain, as moulding material
• CPC Class Codes: B29K 2105/007 Paste, dough
• CPC Class Codes: B29K 2995/0018 having particular optical properties, e.g. fluorescent or phosphorescent
• CPC Class Codes: B29K 2995/0098 Peel strength; Peelability
• CPC Class Codes: B42D 25/36 comprising special materials
• CPC Class Codes: B42D 25/387 absorbing or reflecting ultraviolet light
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: C09K 11/08 containing inorganic luminescent materials
• CPC Class Codes: D21H 21/48 Elements suited for physical verification, e.g. by irradiation

Abstract

A phosphor-containing identification substance of the present invention includes a substrate and a phosphor-containing silicone thin layer. The whole or part of the surface of the substrate is covered with the phosphor-containing silicone thin layer. The phosphor has identification properties that the phosphor emits light when irradiated with ultraviolet rays or black light, and does not emit light when irradiated with visible rays. A method for producing the phosphor-containing identification substance of the present invention includes bringing a silicone composition for forming a phosphor-containing thin layer into contact with the substrate after or simultaneously with the molding of the substrate, followed by heating. This provides the phosphor-containing identification substance that can be applied to a silicone thin film, has excellent adhesive properties with the substrate, and maintains the inherent properties of the substrate without being impaired by marking, and the method for producing the same.

Claims

1. A phosphor-containing identification substance comprising:

a substrate comprising a main polymer component; and

a phosphor-containing silicone thin layer,

wherein a whole or part of a surface of the substrate is covered with the phosphor-containing silicone thin layer,

the main polymer component of the substrate is silicone, and the substrate and the phosphor-containing silicone thin layer are in an inseparable state,

the phosphor-containing silicone thin layer is present on the surface of the substrate,

a silicone composition that forms the phosphor-containing silicone thin layer does not have self-curing performance, but is cured in contact with the substrate, and

the phosphor-containing silicone thin layer has identification properties in which the phosphor-containing silicone thin layer emits visible light when irradiated with ultraviolet rays or black light, and does not emit visible light when irradiated with visible rays.

2. The phosphor-containing identification substance according to claim 1, wherein the substrate is a cured material.

3. The phosphor-containing identification substance according to claim 1, wherein silicone as the main polymer component of the substrate is compatible with the silicone contained in the silicone composition that forms the phosphor-containing the silicone thin layer.

4. The phosphor-containing identification substance according to claim 1, wherein the substrate is a thermally conducting silicone composition.

5. The phosphor-containing identification substance according to claim 1, wherein the phosphor-containing silicone thin layer has a thickness of 0.1 to 20 μ

m.

6. The phosphor-containing identification substance according to claim 1, wherein the substrate is in the form of putty.

7. The phosphor-containing identification substance according to claim 1, wherein the phosphor has a needle shape or a particle shape.

8. A method for producing a phosphor-containing identification substance comprising:

a substrate comprising a main polymer component; and

a phosphor-containing silicone thin layer,

wherein a whole or part of a surface of the substrate is covered with the phosphor-containing silicone thin layer,

the main polymer component of the substrate is silicone, and the substrate and the phosphor-containing silicone thin layer are in an inseparable state,

the phosphor-containing silicone thin layer is present on the surface of the substrate, and

the phosphor-containing silicone thin layer has identification properties in which the phosphor-containing silicone thin layer emits visible light when irradiated with ultraviolet rays or black light, and does not emit visible light when irradiated with visible rays,

the method comprising;

bringing a thin layer of a phosphor-containing silicone composition into contact with the surface of the substrate after or simultaneously with molding of the substrate; and

then

heat-curing the substrate and the thin layer of the phosphor-containing silicone composition simultaneously,

wherein the phosphor-containing silicone composition comprises

(A) a silicone polymer having two or more alkenyl groups per molecule,

(B) an organohydrogensiloxane having a number of SiH groups sufficient to allow the component (A) to be cured, and

(C) a phosphor as a component, and does not contain a compound that serves as a catalyst for a reaction between the component (A) and the component (B), and

wherein the substrate contains a compound that serves as a curing catalyst for the silicone polymer.

9. The method for producing the phosphor-containing identification substance according to claim 8, wherein the phosphor-containing silicone composition further comprises as a component (D) a compound that retards an addition reaction between the alkenyl groups and the SiH groups.

10. The method for producing the phosphor-containing identification substance according to claim 8, wherein the substrate is cured by a hydrosilylation reaction or a peroxide.

11. The method for producing the phosphor-containing identification substance according to claim 8, wherein a surface on which the thin layer of the phosphor-containing silicone composition is to be formed is covered with a release film.

12. The method for producing the phosphor-containing identification substance according to claim 8, comprising:

coating a whole or part of a surface of a release film with the phosphor-containing silicone composition; and

bringing the coated surface into contact with the substrate so that the phosphor-containing silicone composition is transferred to the surface of the substrate.

13. The method for producing the phosphor-containing identification substance according to claim 8, wherein silicone as the main polymer component of the substrate is compatible with silicone contained in the phosphor-containing silicone composition.