Inspectable black glass containers

• US 10,018,575 B2
• Filed: 02/09/2016
• Issued: 07/10/2018
• Est. Priority Date: 11/01/2012
• Status: Active Grant

• Current Assignee: Owens-Brockway Glass Container Incorporated (O-I Glass, Inc.)
• Original Assignee: Owens-Brockway Glass Container Incorporated (O-I Glass, Inc.)
• Inventors: Smith, Roger P., Click, Carol A., Mullen, Rebecca, Barton, Stephen Daniel
• Primary Examiner(s): FRANKLIN, JODI COHEN
• Application Number:
  US15/019,405
• Publication Number:
  US 20160153919A1
• Time in Patent Office: 882 Days
• Field of Search: 65158, 65 2912, 65 2911, 65160, 65377
• CPC Class Codes: C03B 32/00 Thermal after-treatment of glass products not provided for in groups C03B19/00 , C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
• CPC Class Codes: C03C 3/087 containing calcium oxide, e.g. common sheet or container glass
• CPC Class Codes: C03C 4/02 for coloured glass
• CPC Class Codes: G01J 5/28 using photoemissive or photovoltaic cells
• CPC Class Codes: G01N 2021/8845 Multiple wavelengths of illumination or detection
• CPC Class Codes: G01N 21/8806 Specially adapted optical and illumination features
• CPC Class Codes: G01N 21/909 in opaque containers or opaque container parts, e.g. cans, tins, caps, labels
• CPC Class Codes: G01N 21/958 Inspecting transparent materials or objects, e.g. windscreens for conveyed flat sheet or rod G01N21/896
• CPC Class Codes: G01N 33/386 Glass
• CPC Class Codes: Y10T 428/131 Glass, ceramic, or sintered, fused, fired, or calcined metal oxide or metal carbide containing [e.g., porcelain, brick, cement, etc.]

Abstract

A soda-lime-silica glass container and related methods of manufacturing. A black-strikable glass composition having a base glass portion and a latent colorant portion is prepared. The base glass portion includes soda-lime-silica glass materials and one or more blue colorant materials, and the latent colorant portion includes cuprous oxide (Cu₂O), stannous oxide (SnO), bismuth oxide (Bi₂O₃), and carbon (C). Glass containers may be formed from the black-strikable glass composition, and these glass containers may be heated to a temperature greater than 600 degrees Celsius to strike black therein. The glass containers formed from the black-strikable glass composition may be inspected—before or after striking—by infrared inspection equipment.

Claims

1. A method of inspecting a black glass container for commercial variations that affect optical characteristics of the glass container, the method including the steps of:

providing a black glass container having a transmittance of less than 10% to all visible light energy having wavelengths between 390 nm and 675 nm and having a transmittance of greater than 30% to infrared light energy having wavelengths between 750 nm and 1100 nm so as to be inspectable using infrared light energy, the black glass container having a composition that includes a base glass portion and a latent colorant portion, with the base glass portion including;

60-75 wt. % SiO₂, 7-15 wt. % Na₂O, 6-12 wt. % CaO, 0.1-3.0 wt. % Al₂O₃, 0.0-2.0 wt. % MgO, 0.0-2.0 wt. % K₂O, 0.01-0.25 wt. % SO₃, 0.01-0.25 wt. % Fe₂O₃, and 0.01-0.15 wt. % CoO and the latent colorant portion including;

0.0875-0.35 wt. % cuprous oxide (Cu₂O), 0.06-0.5 wt. % stannous oxide (SnO), and 0.006-0.05 wt. % bismuth oxide (Bi₂O₃);

directing infrared light energy onto the black glass container; and

receiving infrared light energy from the black glass container on an infrared light sensor, the infrared light sensor being responsive to infrared light energy having wavelengths in the range of 750 nm to 1100 nm.

2. The method as set forth in claim 1 wherein the infrared light sensor is a laser optic sensor and is responsive to infrared light energy having wavelengths in the range of 750 nm to 850 nm.

3. The method set forth in claim 1 including the additional steps of:

providing electrical signals from the infrared light sensor to an information processor in response to infrared light energy received from the black glass container; and

analyzing the electrical signals at the information processor to determine whether commercial variations in the black glass container are acceptable or unacceptable.

4. The method as set forth in claim 1 wherein the black glass container has a transmittance in the range of 30% to 65% to infrared light energy having wavelengths in the range of 750 nm to 850 nm.

5. The method as set forth in claim 1 wherein the black glass container has a transmittance of greater than 30% to light having wavelengths between 750 nm and 850 nm.

6. The method as set forth in claim 1 wherein the black glass container has a transmittance of at least 40% to light having a wavelength of 750 nm.

7. The method as set forth in claim 1 wherein the black glass container has a wall thickness of greater than one millimeter.

8. The method set forth in claim 3 including:

analyzing the electrical signals at the information processor to detect for dimensional anomalies in a sidewall, heel, bottom, shoulder, or neck of the glass container.

15. The glass container set forth in claim 1 wherein the black glass container has a transmittance of greater than 30% to all infrared light energy having wavelengths between 750 nm and 1100 nm.

9. A method of making black glass containers including:

preparing a molten black-strikable glass composition, the black-strikable glass composition having a base glass portion and a latent colorant portion, with the base glass portion comprising;

60-75 wt. % SiO₂, 7-15 wt. % Na₂O, 6-12 wt. % CaO, 0.1-3.0 wt. % Al₂O₃, 0.0-2.0 wt. % MgO, 0.0-2.0 wt. % K₂O, 0.01-0.25 wt. % SO₃, 0.01-0.25 wt. % Fe₂O₃, and 0.01-0.15 wt. % CoO, and the latent colorant portion comprising;

0.0875-0.35 wt. % cuprous oxide (Cu₂O), 0.06-0.5 wt. % stannous oxide (SnO), 0.006-0.05 wt. % bismuth oxide (Bi₂O₃), and 0.02-0.10 wt. % carbon (C);

forming glass containers from the molten black-strikable glass composition;

raising the temperature of the glass containers above 600 degrees Celsius to strike black coloration into the glass containers to produce black glass containers having a transmittance of less than 10% to all visible light energy having wavelengths in the range of 390 nm to 675 nm and a transmittance of greater than 30% to infrared light energy having wavelengths in the range of 750 nm to 1100 nm so as to be inspectable using infrared light energy; and

inspecting the black glass containers by directing infrared light energy from an infrared light source through the black glass containers and onto an infrared light sensor, the infrared light sensor being responsive to infrared light energy having wavelengths in the range of 750 nm to 1100 nm.

10. The method set forth in claim 9 including:

transmitting electrical signals from the infrared light sensor to an information processor in response to infrared light energy received by the infrared light source; and

analyzing the electrical signals at the information processor to detect for commercial variations that affect optical characteristics of the black glass containers.

11. The method set forth in claim 9 wherein the glass containers are formed from the molten black-strikable glass composition by measuring out gobs of the molten black-strikable glass composition and delivering the gobs to glass container-forming machines.

12. An inspectable black glass container comprising:

a base glass portion comprising 60-75 wt. % SiO₂, 7-15 wt. % Na₂O, 6-12 wt. % CaO, 0.1-3.0 wt. % Al₂O₃, 0.0-2.0 wt. % MgO, 0.0-2.0 wt. % K₂O, 0.01-0.25 wt. % SO₃, 0.01-0.25 wt. % Fe₂O₃, and 0.01-0.15 wt. % CoO; and

a latent colorant portion comprising;

0.0875-0.35 wt. % cuprous oxide (Cu₂O), 0.06-0.5 wt. % stannous oxide (SnO), 0.006-0.05 wt. % bismuth oxide (Bi₂O₃), and 0.02-0.10 wt. % carbon (C),

wherein the black glass container has a transmittance of less than 10% to all visible light energy having wavelengths between 390 nm and 675 nm, and

wherein the black glass container transmits 30% to 65% infrared light so as to be inspectable using an infrared light source.

13. The glass container set forth in claim 12 wherein the black glass container has a transmittance of greater than 30% to light having wavelengths between 750 nm and 850 nm.

14. The glass container set forth in claim 12 wherein the black glass container has a transmittance of at least 40% to light having a wavelength of 750 nm.