System and process for combusting cleaned coal and beneficiated organic-carbon-containing feedstock

• US 10,024,533 B2
• Filed: 02/18/2015
• Issued: 07/17/2018
• Est. Priority Date: 06/16/2014
• Status: Active Grant

• Current Assignee: CTP Biotechnology, LLC
• Original Assignee: CTP Biotechnology, LLC
• Inventors: Van Thorre, Douglas M, Tait, Carleton Drew, Catto, Michael L, Scalzo, Philip James
• Primary Examiner(s): Toomer, Cephia D
• Application Number:
  US14/625,074
• Publication Number:
  US 20150362185A1
• Time in Patent Office: 1,245 Days
• CPC Class Codes: C10L 2200/0469 Renewables or materials of biological origin
• CPC Class Codes: C10L 2290/02 Combustion or pyrolysis
• CPC Class Codes: C10L 2290/06 Heat exchange, direct or indirect
• CPC Class Codes: C10L 2290/08 Drying or removing water
• CPC Class Codes: C10L 2290/24 Mixing, stirring of fuel components
• CPC Class Codes: C10L 2290/28 Cutting, disintegrating, shredding or grinding
• CPC Class Codes: C10L 2290/30 Pressing, compressing or compacting
• CPC Class Codes: C10L 2290/36 Applying radiation such as microwave, IR, UV
• CPC Class Codes: C10L 2290/545 Washing, scrubbing, stripping, scavenging for separating fractions, components or impurities during preparation or upgrading of a fuel
• CPC Class Codes: C10L 5/08 without the aid of extraneous binders briquetting peat C10F
• CPC Class Codes: C10L 5/143 with lignin-containing products
• CPC Class Codes: C10L 5/363 Pellets or granulates
• CPC Class Codes: C10L 5/366 Powders
• CPC Class Codes: C10L 5/447 Carbonized vegetable substances, e.g. charcoal, or produced by hydrothermal carbonization of biomass
• CPC Class Codes: C10L 9/08 by heat treatments, e.g. calcining
• CPC Class Codes: F23G 2201/40 Gasification
• CPC Class Codes: F23G 2204/203 Microwave
• CPC Class Codes: F23G 5/0273 using indirect heating
• CPC Class Codes: F23G 5/033 comminuting or crushing
• CPC Class Codes: F23G 5/08 having supplementary heating
• CPC Class Codes: F23G 5/14 : including secondary combustion
• CPC Class Codes: F23G 7/10 : of field or garden waste or biomasses
• CPC Class Codes: F23J 15/02 : of purifiers, e.g. for removing noxious material traps for solid residues F23J3/04
• CPC Class Codes: Y02E 50/10 : Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 : Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

A coal combustion process is described using cleaned coal and processed biomass to reduce adverse by-products in a coal combusting apparatus including the reduction of carbon dioxide by at least 50 volume %. The coal feedstock comprises an aggregate blend of cleaned coal and processed biomass. The biomass feedstock comprises processed biomass pellets. The total energy density is predetermined and can be similar to the coal component or higher than the coal component. The intracellular salt in the processed biomass is at least 60 wt % less for the processed organic-carbon-containing feedstock used to make the processed biomass pellets than that of the starting un-processed processed organic-carbon-containing feedstock. The cleaned coal has a sulfur content that is 50 wt % less than that of un-cleaned coal before it passed through the coal-cleaning sub-system.

Claims

1. A coal combusting system for combusting coal in a coal combusting apparatus comprising:

a first input chamber of a coal combusting apparatus configured to pulverize a coal feedstock comprising a processed biomass/cleaned coal blended compact aggregate that comprises at least 10 wt % of a coal having a sulfur content of at least 50 wt % less than that of the content of sulfur in the coal before it passed through a coal cleaning sub-system and at least 10 wt % of a processed biomass from a processed biomass system and to feed the pulverized cleaned coal feedstock into the coal combusting apparatus in a first concentration of feedstock;

a second input chamber of the coal combusting apparatus configured to pulverize a processed biomass pellet feedstock from the processed biomass system and to feed the pulverized processed biomass pellet feedstock into the coal combusting apparatus in a second concentration of feedstock with the weight ratio of the first concentration to the second concentration between 1 to 9 and 9 to 1;

at least one exhaust chamber having a gaseous waste stream and comprising at least one gas separation sub-system configured to separate at least 50 volume % of carbon dioxide from the gaseous waste stream;

a consumption sub-system configured to receive the separated carbon dioxide gas and consume it in the making of useful materials,

wherein the processed biomass system is configured to make processed biomass from unprocessed organic-carbon-containing feedstock that includes free water, intercellular water, intracellular water, intracellular water-soluble salts, and at least some plant cells comprising cell walls that include lignin, hemicellulose, and microfibrils within fibrils, the processed biomass system comprising;

a beneficiation sub-system configured to convert the unprocessed organic-carbon-containing feedstock into a processed organic-carbon-containing feedstock with characteristics that include having an energy density of at least 17 MMBTU/ton (20 GJ/MT), a water content of less than 20 wt %, and a water-soluble intracellular salt content that is decreased more than 60 wt % on a dry basis from that of the unprocessed organic-carbon-containing feedstock;

a coal cleaning sub-system configured to convert un-cleaned coal into cleaned coal having a sulfur content at least 50 wt % less than that of the content of sulfur in the un-cleaned coal before it passed through the coal cleaning sub-system;

a blending sub-system configured to convert the cleaned coal and some of the processed biomass into processed biomass/cleaned coal blended compact aggregate with a weight ratio of cleaned coal to processed biomass ranging from 1 to 9 to 9 to 1; and

a pelletizing sub-system configured to convert some of the processed organic-carbon-containing feedstock into processed biomass pellets.

2. The coal combusting system of claim 1, wherein the blending sub-system comprises:

a sizing chamber to properly sized particles of coal and processed biomass to a similar size;

a combining chamber configured to blend the similarly sized particles into a blended powder of a predetermined ratio of coal to processed biomass; and

a compacting chamber to compress the blended powder into blended compact aggregates, and wherein the pelletizing sub-system comprises;

a compression chamber configured to separate the processed organic-carbon-containing feedstock into discrete units of mass having a longest length of at least 0.16 inch (0.41 cm) and a density of at least 37.5 pounds per cubic foot (0.60 grams per cubic centimeter) to form processed biomass pellets; and

a collection chamber configured to gather aggregates of processed biomass pellets.

3. The coal combusting system of claim 1, wherein the first input chamber of the coal combusting apparatus and the second input chamber of the coal combusting apparatus are the same input chamber.

4. The coal combusting system of claim 1, wherein the processed biomass comprises processed biochar, the blended compact aggregate has an energy density of at least 21 MMBTU/ton (25 GJ/MT), the processed organic-carbon-containing feedstock is passed through a heating sub-system to form processed biochar that is blended with coal into a blended compact aggregate in a blending sub-system, and the water-soluble intracellular salt content decrease is based on comparing the processed organic-carbon-containing feedstock before it is passed through the heating sub-system to the unprocessed organic-carbon-containing feedstock.

5. The coal combusting system of claim 1, wherein the beneficiation sub-system comprises:

a transmission device configured to convey into a reaction chamber unprocessed organic-carbon-containing feedstock comprising free water, intercellular water, intracellular water, intracellular water-soluble salts, and at least some plant cells comprising cell walls that include lignin, hemicellulose, and microfibrils within fibrils;

at least one reaction chamber comprising at least one entrance passageway, at least one exit passageway for fluid, at least one exit passageway for processed organic-carbon-containing feedstock, and at least three sections, the sections comprising;

a wet fibril disruption section configured to interact with at least some of the lignin and hemicellulose between the fibrils to make at least some regions of the cell wall more susceptible to penetration by water-soluble salts without dissolving more than 25 percent of the lignin and hemicellulose;

a vapor explosion section in communication with the wet fibril disruption section and at least configured to volatilize plant fibril permeable fluid through rapid decompression to penetrate the more susceptible regions of the cell wall so as to create a porous organic-carbon-containing feedstock with plant cell wall passageways for intracellular water and intracellular water-soluble salts to pass from the plant cell; and

a compaction section in communication with the vapor explosion section and configured to compress the porous organic-carbon-containing feedstock between pressure plates configured to minimize formation of water-impermeable felt so as to permit the escape of intracellular water and intracellular water-soluble salt from the reaction chamber fluid exit passageway and to create processed organic-carbon-containing feedstock that passes out through its reaction chamber exit passageway; and

a collection device in communication with the reaction chamber and configured to gather the processed organic-carbon-containing feedstock having a water content of less than 20% by weight, a combined lignin and hemicellulose content that is decreased by at less than 25% on a dry basis from that of the unprocessed organic-carbon-containing feedstock, and a water-soluble intracellular salt content that is decreased by at least 60% on a dry basis from that of the unprocessed organic-carbon-containing feedstock.

6. The coal combusting system of claim 4, wherein the heating sub-system is an oxygen-deprived thermal sub-system that comprises a reaction chamber configured to heat processed organic-carbon-containing feedstock in an atmosphere that contains less than 4 percent oxygen to a temperature sufficient to convert at least some processed organic-carbon-containing feedstock into processed biogas and processed biochar.

7. The coal combusting system of claim 6, wherein the oxygen-deprived thermal sub-system is selected from a group consisting of

a substantially horizontal sublimation system comprising:

a hot box configured to be able to heat from an ambient temperature to an operating sublimation temperature, maintain an initial operating sublimation temperature and a final operating sublimation temperature that are stable within less than ±

10°

C., and cool from operating sublimation temperatures to an ambient temperature without leaking any oxygen into the hot box and having at least one heat source in communication with the interior of the hot box to supply heat as needed;

at least one substantially horizontal reaction chamber largely located within the hot box, having a surface, configured to heat the processed organic-carbon-containing feedstock without external catalyst or additional water to an operating sublimation temperature in a time frame that is short enough to sublime at least part of the processed organic-carbon-containing feedstock without creating substantially any liquid, configured to heat from an ambient temperature to an operating sublimation temperature, operate at a sublimation temperature, and cool from an operating sublimation temperature to an ambient temperature without leaking any product gas fuel into the surrounding hot box, and comprising an input end outside the hot box and configured to receive compressed feedstock through an input line and an output end outside the hot box and configured to discharge product gas fuel gas through a discharge line and solid char fuel through an output line;

a first powered transport mechanism that is located within the reaction chamber and is configured to convey sublimation products of the processed organic-carbon-containing feedstock through the reaction chamber as the processed organic-carbon-containing feedstock is transformed into processed biogas and processed biochar; and

a gas-tight element on both the input line and output line and configured to prevent hot biogas from adversely escaping from the reaction chamber;

or

a substantially vertical sublimation system comprising;

at least one substantially vertical reaction chamber configured to heat the processed organic-carbon-containing feedstock without external catalyst or additional water, carbon dioxide, or carbon monoxide, to an operating sublimation temperature in a time frame that is short enough to sublime at least part of the processed organic-carbon-containing feedstock without creating substantially any liquid;

a first powered transport mechanism that is located partly within the reaction chamber, has an extended part that extends outside the reaction chamber, and is configured to convey sublimation products of the processed organic-carbon-containing feedstock through the reaction chamber as the processed organic-carbon-containing feedstock is transformed into biogas and processed biochar; and

a self-adjusting seal that is configured to continuously contain the processed biogas within the reaction chamber at the region surrounding the extended part of the powered transport mechanism during changing temperatures of startup and shutdown operations, and during steady-state sublimation temperature during operation.

8. The coal combusting system of claim 4, wherein the heating sub-system comprises:

at least one reaction chamber within a microwave reflecting enclosure, the reaction chamber comprising at least one microwave-transparent chamber wall and at least one reaction cavity within the reaction chamber that is configured to hold the organic-carbon-containing feedstock in an externally supplied oxygen free atmosphere;

a microwave subsystem comprising at least one device configured to emit microwaves when energized, the microwave device positioned relative to the reaction chamber so that the microwaves are directed through the microwave-transparent chamber wall and into the reaction cavity; and

a mechanism configured to provide relative motion between the microwave device and the reaction chamber.

9. The coal combusting system of claim 5, wherein the vapor explosion section of the beneficiation sub-system comprises a wash element that is configured to remove and clean microparticles of unprocessed organic-carbon-containing feedstock, lignin fragments, and hemicellulosic fragments from the vapor explosion section into a fine, sticky mass of biomass with high lignin content,

wherein a blending chamber of the blending sub-system is further configured to receive fine, sticky mass of biomass to permit lower temperatures in a compaction chamber formation during formation of blended compact aggregates.

10. The coal combusting system of claim 5, wherein the processed organic-carbon-containing feedstock has a water soluble intracellular salt content that is decreased by more than 75 wt % on a dry basis from that of unprocessed organic-carbon-containing feedstock and the compaction section of the beneficiated sub-system is configured to provide at least one rinsing step.