Method and device for detecting PH value of a solution

• US 10,024,815 B2
• Filed: 11/30/2012
• Issued: 07/17/2018
• Est. Priority Date: 12/02/2011
• Status: Active Grant

• Current Assignee: Koninklijke Philips N.V.
• Original Assignee: Koninklijke Philips N.V.
• Inventors: Wang, Guangwei, Hu, Peixin
• Primary Examiner(s): Warden, Jill A
• Assistant Examiner(s): Fisher, Brittany I
• Application Number:
  US14/360,970
• Publication Number:
  US 20140291171A1
• Time in Patent Office: 2,055 Days
• Field of Search: None
• CPC Class Codes: G01N 27/302 pH sensitive, e.g. quinhydron, antimony or hydrogen electrodes ion selective electrodes G01N27/333, glass electrodes G01N27/36
• CPC Class Codes: G01N 27/4167 pH electrodes therefor G01N27/302, G01N27/36

Abstract

A PH value detection device for detecting a PH value of a solution includes first and a second electrodes to be inserted into the solution; and a power source configured to apply a bipolar rectangular potential pulse signal to the first and second electrodes. A current detector is connected between the first and second electrodes and is configured to detect a current flowing through the first and second electrodes. A calculator is configured to calculate the PH value of the solution, based on the detected current.

Claims

1. A PH value detection device for detecting the PH value of a solution, comprising:

a first electrode and a second electrode, wherein the first electrode and the second electrode are configured to be inserted into the solution, the first electrode comprises a transition metal/transition metal oxide electrode, and the second electrode comprises an inert electrode;

a power source configured to apply a bipolar rectangular potential pulse signal to the first electrode and the second electrode;

a current detector connected between the first electrode and the second electrode and configured to detect a current flowing through the first electrode and the second electrode;

a memory configured to pre-store a plurality of functions correlating current and PH values for a plurality of solution types, each function of the plurality of functions being associated with a type of solution to be detected; and

a calculator configured to calculate the PH value of the solution, based on the detected current and the plurality of functions stored in the memory,

wherein the plurality of functions are linear functions having slopes and y-intercepts which are determined using a plurality of types of solutions having different PH values that are in a first range, the first range being larger than a second range of PH values that includes the PH value of the solution to be detected.

2. The device as claimed in claim 1, wherein the transition metal/transition metal oxide electrode is selected from an Ag/Ag₂O electrode, W/WO₃ electrode, Mn/MnO electrode or Ir/IrO₂ electrode, and the inert electrode is selected from a Cu electrode, Pt electrode, Au electrode or stainless steel electrode.

3. The device as claimed in claim 1, further comprising a user interface configured to receive data reflecting the type of solution to be detected to select a pre-stored function from said plurality of functions associated with the type of solution to be detected.

4. The device as claimed in claim 3, wherein the calculating unit is configured to calculate the PH value of the solution to be detected according to the detected current and the selected pre-stored function.

5. The device of claim 1, wherein the plurality of functions include a pre-stored function which is a linear function having a slope and a y-intercept which are determined using a type of solution having a PH value approximate to the PH value of the solution to be detected.

6. A method of detecting a PH value of a solution, comprising acts of:

applying a bipolar rectangular potential pulse signal to a first electrode and a second electrode inserted into the solution, wherein the first electrode comprises a transition metal/transition metal oxide electrode, and the second electrode comprises an inert electrode;

detecting a current flowing through the first electrode and the second electrode;

calculating the PH value of the solution, based on the detected current; and

pre-storing a plurality of functions correlating current and PH values for a plurality of solution types, each function of the plurality of functions being associated with a type of solution to be detected.

7. The method as claimed in claim 6, wherein the transition metal/transition metal oxide electrode is selected from an Ag/Ag₂O electrode, W/WO₃ electrode, Mn/MnO electrode or Ir/IrO₂ electrode, and the inert electrode is selected from a Cu electrode, Pt electrode, Au electrode or stainless steel electrode.

8. The method as claimed in claim 6, further comprising an act of pre-storing a function which correlates current and PH values.

9. The method as claimed in claim 6, further comprising an act of receiving data reflecting the type of solution to be detected from a user interface for selecting pre-stored a function from said plurality of functions associated with the type of solution to be detected.

10. The method as claimed in claim 9, wherein the calculating act calculates the PH value of the solution to be detected based on the detected current and the selected pre-stored function.

11. A PH value detection device for detecting the PH value of a solution, comprising:

means for applying a bipolar rectangular potential pulse signal to a first electrode and a second electrode inserted into the solution, wherein the first electrode comprises a transition metal/transition metal oxide electrode, and the second electrode comprises an inert electrode;

means for detecting a current flowing through the first electrode and the second electrode;

means for calculating the PH value of the solution, based on the detected current; and

means for pre-storing a plurality of functions correlating current and PH values for a plurality of solution types, each function of the plurality of functions being associated with a type of solution to be detected.