Low solar transmittance coatings

• US 10,040,719 B2
• Filed: 01/16/2013
• Issued: 08/07/2018
• Est. Priority Date: 01/17/2012
• Status: Active Grant

• Current Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Original Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Inventors: Eby, Eric H., Hartig, Klaus H. W.
• Primary Examiner(s): Ewald, Maria V
• Assistant Examiner(s): Utt, Ethan A.
• Application Number:
  US14/371,242
• Publication Number:
  US 20150004369A1
• Time in Patent Office: 2,029 Days
• Field of Search: 428213, 428216, 428426, 428432, 428433, 428434, 428457, 428469, 428472, 428688, 428689, 428697, 428698, 428699, 428701, 428702
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10201 Dielectric coatings
• CPC Class Codes: B32B 17/10229 Metallic layers sandwiched by dielectric layers
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 2037/243 Coating
• CPC Class Codes: B32B 2309/022 Temperature vs pressure profiles
• CPC Class Codes: B32B 2311/08 Silver
• CPC Class Codes: B32B 37/06 characterised by the heating method
• CPC Class Codes: B32B 37/10 characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
• CPC Class Codes: B32B 37/24 with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate B32B37/15 takes precedence
• CPC Class Codes: B32B 38/1866 conforming the layers or laminate to a convex or concave profile
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3626 one layer at least containing a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 23/007 by thermal treatment
• CPC Class Codes: G02B 1/11 Anti-reflection coatings
• CPC Class Codes: Y10T 428/24628 : Nonplanar uniform thickness material
• CPC Class Codes: Y10T 428/2495 : Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/24975 : No layer or component greater than 5 mils thick

Abstract

The invention provides low solar transmittance coatings that have particularly low solar transmittance. The coating includes three infrared-reflection film regions, which may each comprise silver. In some cases, the coating is incorporated into a laminated glass assembly.

Claims

1. A laminated glass assembly including two panes and an interlayer, each of the two panes having an uncoated, exposed outer side surface, one of the panes having an interior major surface bearing a low solar transmittance coating, the low solar transmittance coating comprising a first infrared-reflection film region having a thickness, a second infrared-reflection film region having a thickness, and a third infrared-reflection film region having a thickness, the low solar transmittance coating comprising, in sequence moving away from said interior major surface and toward said interlayer:

a) a first transparent dielectric film region having an optical thickness;

b) the first infrared-reflection film region;

c) a second transparent dielectric film region having an optical thickness;

d) the second infrared-reflection film region;

e) a third transparent dielectric film region having an optical thickness;

f) the third infrared-reflection film region; and

g) a fourth transparent dielectric film region having an optical thickness;

the thicknesses of the three infrared-reflection film regions providing the laminated glass assembly with a solar transmittance of less than 0.34, a solar heat gain coefficient of about 0.36-0.38, and a visible transmittance of greater than 0.705,

wherein the laminated glass assembly exhibits a Delta T_vis,lami of less than 5%,

the three infrared-reflection film regions having a combined thickness of greater than 300 Å

in combination with the third infrared-reflection film region being thinner than the second infrared-reflection film region, the thickness of the first infrared-reflection film region being less than the thickness of the third infrared-reflection film region, the thickness of the first infrared-reflection film region being in a range from 85 to 140 Å

, the thickness of the second infrared-reflection film region being in a range from 120 to 180 Å

, and the thickness of the third infrared-reflection film region being in a range from 110 to 170 Å

, the first infrared-reflection film region being thinner than the second infrared-reflection film region by at least 25 Å

,

wherein the low solar transmittance coating has a first reflection-region ratio of less than 0.80, the first reflection-region ratio defined as the thickness of the first infrared-reflection film region divided by the thickness of the second infrared-reflection film region,

wherein the low solar transmittance coating has a first dielectric-region ratio defined as the optical thickness of the first transparent dielectric film region divided by the optical thickness of the fourth transparent dielectric film region, the first dielectric-region ratio being less than 0.75, and

wherein the thickness of at least one of the infrared-reflection film regions is greater than 130 Å

while the thickness of at least one of the other infrared-reflection film regions is less than 125 Å

.

2. The laminated glass assembly of claim 1 wherein the laminated glass assembly is a bent automobile windshield, the two panes are both heat-bent glass, and the low solar transmittance coating is a heat-bent coating.

3. The laminated glass assembly of claim 1 wherein the combined thickness of the three infrared-reflection film regions is greater than 325 Å

and the solar transmittance is less than 0.32.

4. The laminated glass assembly of claim 1 wherein the combined thickness of the three infrared-reflection film regions is greater than 350 521 and the visible transmittance is greater than 0.7075.

5. The laminated glass assembly of claim 1 wherein the combined thickness of the three infrared-reflection film regions is greater than 375 Å

, the solar transmittance is less than 0.32, and the visible transmittance is in the range of about 0.71-0.72.

6. The laminated glass assembly of claim 1 wherein the first dielectric-region ratio is less than 0.7.

7. The laminated glass assembly of claim 1 wherein the laminated glass assembly has an exterior side and an interior side, the exterior side having a reflected color characterized by an a_h color coordinate of between −

3 and 1, and a b_h color coordinate of between −

5 and 0.

8. The laminated glass assembly of claim 1 wherein the thickness of the third infrared-reflection film region is more than 5 Å

less than the thickness of the second infrared-reflection film region.

9. The laminated glass assembly of claim 1 wherein the thickness of said at least one of the other infrared-reflection film regions is less than 120 Å

.

10. The laminated glass assembly of claim 1 wherein the first reflection-region ratio is less than 0.79.

11. The laminated glass assembly of claim 1 wherein the solar transmittance is about 0.29-0.3.

12. The laminated glass assembly of claim 1 wherein the fourth transparent dielectric film region comprises an outermost oxide layer over a nitride or oxynitride layer, the outermost oxide layer having a thickness of less than 75 Å

.