Method and apparatus for producing high purity phosgene

• US 10,059,594 B2
• Filed: 07/25/2014
• Issued: 08/28/2018
• Est. Priority Date: 07/26/2013
• Status: Expired due to Fees

• Current Assignee: SABIC Global Technologies BV (Government of Saudi Arabia)
• Original Assignee: SABIC Global Technologies BV (Government of Saudi Arabia)
• Inventors: Gautam, Pankaj Singh, Hollar, Jr., William E.
• Primary Examiner(s): Zucker, Paul A
• Application Number:
  US14/907,383
• Publication Number:
  US 20160207779A1
• Time in Patent Office: 1,495 Days
• CPC Class Codes: B01J 2208/00212 Plates; Jackets; Cylinders
• CPC Class Codes: B01J 2208/00513 using inert heat absorbing solids in the bed
• CPC Class Codes: B01J 2208/0084 inside the bed, e.g. baffles
• CPC Class Codes: B01J 2208/025 Two or more types of catalyst
• CPC Class Codes: B01J 2208/065 Heating or cooling the reactor
• CPC Class Codes: B01J 8/067 Heating or cooling the reactor B01J8/062 takes precedence
• CPC Class Codes: C01B 32/80 Phosgene

Abstract

In an embodiment, a method of producing phosgene in a tube reactor comprises introducing a feed comprising carbon monoxide and chlorine to a tube of the reactor, the tube having a particulate catalyst disposed therein, wherein a thermally conductive material separate from the tube contacts at least a portion of the particulate catalyst; to produce a product composition comprising phosgene, and carbon tetrachloride in an amount of 0 to 10 ppm by volume based on the volume of the phosgene.

Claims

1. A tube reactor comprising:

a shell and a tube located within the shell, with a cooling medium between the shell and the tube,

the tube having a particulate catalyst effective to convert carbon monoxide and chlorine to phosgene disposed therein,

wherein a thermally conductive material separate from the tube contacts at least a portion of the particulate catalyst; and

wherein the tube reactor is configured such that the peak temperature in the reactor is less than 800°

C.;

wherein the tube reactor has a heat transfer area per unit volume of 500 to 10,000 m²/m³.

2. The reactor of claim 1, wherein the thermally conductive material provides a thermally conductive path between the particulate catalyst and the tube.

3. The reactor of claim 1, wherein the thermally conductive material comprises a coating disposed on at least a portion of an exterior surface of the particulate catalyst particle, or a portion of an exterior surface of an agglomerate of the particulate catalyst, or both, and wherein the coating has a coating thickness of 0.001 to 1 micrometer.

4. The reactor of claim 1, wherein the thermally conductive material comprises a particulate material distributed within and in contact with the particulate catalyst, and the particulate material and the particulate catalyst are contacted by a mesh disposed within the tube.

5. The reactor of claim 4, wherein the mesh has openings and wherein the openings of the mesh have an average diameter smaller than the average diameter of the particulate material.

6. The reactor of claim 1, wherein the thermally conductive material comprises a doping material that is doped in the catalyst in an amount of greater than or equal to 10,000 ppm by weight of the particulate catalyst, and wherein the thermally conductive material has a thermal conductivity greater than 200 W/(m·

K).

9. A method of producing phosgene in the tube reactor of claim 1, the method comprising:

introducing a feed comprising carbon monoxide and chlorine to a tube of the reactor having a peak temperature of less than 800°

C., the tube having a particulate catalyst disposed therein, wherein a thermally conductive material separate from the tube contacts at least a portion of the particulate catalyst; and

producing a product composition comprising phosgene, and carbon tetrachloride in an amount of 0 to 10 ppm by volume based on the volume of the phosgene.

10. The method of claim 9, wherein the thermally conductive material comprises a coating disposed on at least a portion of an exterior surface of the particulate catalyst, or a portion of an exterior surface of an agglomerate of the particulate catalyst, or both.

11. The method of claim 10, wherein the coating has a coating thickness of 0.001 to 1 micrometer.

12. The method of claim 9, wherein the thermally conductive particulate material comprises a thermally conductive, 3-dimensional mesh, and wherein the mesh has openings and wherein the openings of the mesh have an average diameter larger than the average diameter of the particulate catalyst.

13. The method of claim 9, wherein the thermally conductive material comprises a particulate material distributed within and in contact with the particulate catalyst.

14. The method of claim 9, wherein the thermally conductive material comprises a doping material that is doped in the catalyst in an amount of greater than or equal to 10,000 ppm by weight of the particulate catalyst.

15. The method of claim 9, wherein the thermally conductive material has a thermal conductivity greater than 50 W/(m·

K).

16. The method of claim 9, wherein the thermally conductive material comprises aluminum, antimony, beryllium, brass, bronze, cadmium, carbon, copper, gold, iridium, iron, lead, magnesium, molybdenum, nickel, silver, chromium, or a combination comprising at least one of the foregoing.

17. The method of claim 9, wherein the catalyst varies in concentration, activity, or both from a feed end of the tube to an outlet end of the tube, wherein the variance is from low activity, concentration, or both at the feed end to relatively higher concentration, activity, or both, at the outlet end.

18. The method of claim 9, wherein the peak temperature in the reactor is less than or equal to 400°

C.

19. The method of claim 9, wherein the thermally conductive material forms a thermally conductive path between the particulate catalyst and the tube;

and wherein, during use, the thermally conductive material conducts heat away from the catalyst and/or increases the thermal conductivity of catalyst.

20. The reactor of claim 9, wherein the particulate catalyst comprises a carbon-containing catalyst.

7. A tube reactor comprising:

a shell and a tube located within the shell, with a cooling medium between the shell and the tube,

the tube having a particulate catalyst effective to convert carbon monoxide and chlorine to phosgene disposed therein,

wherein a thermally conductive material separate from the tube contacts at least a portion of the particulate catalyst; and

wherein the tube reactor is configured such that the peak temperature in the reactor is less than 800°

C.;

wherein the catalyst varies in concentration, activity, or both from a feed end of the tube to an outlet end of the tube, wherein the variance is from low activity, concentration, or both at the feed end to relatively higher concentration, activity, or both, at the outlet end.

8. The reactor of claim 7, wherein the method has a heat transfer area per unit volume of 500 to 10,000 m²/m³.