Anti-reflection glass with tin oxide nanoparticles

• US 10,059,622 B2
• Filed: 05/07/2012
• Issued: 08/28/2018
• Est. Priority Date: 05/07/2012
• Status: Expired due to Fees

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Inventors: Liang, Liang, Blacker, Richard
• Primary Examiner(s): Burkhart, Elizabeth A
• Application Number:
  US13/465,311
• Publication Number:
  US 20130295392A1
• Time in Patent Office: 2,304 Days
• Field of Search: 427162-169
• CPC Class Codes: C03C 17/007 containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
• CPC Class Codes: C03C 2217/211 SnO2
• CPC Class Codes: C03C 2217/213 SiO2
• CPC Class Codes: C03C 2217/42 consisting of particles only
• CPC Class Codes: C03C 2217/732 made of a single layer
• CPC Class Codes: C03C 2217/77 Coatings having a rough surface
• CPC Class Codes: C03C 2218/113 by sol-gel processes
• CPC Class Codes: C03C 2218/116 by spin-coating, centrifugation
• CPC Class Codes: C03C 2218/365 Coating different sides of a glass substrate
• CPC Class Codes: G02B 1/115 Multilayers

Abstract

An improved anti-reflection glass with higher transmittance (ΔTqe %) results from a coating of or including tin oxide (e.g., SnO₂) nanoparticles (e.g., 10-20 nm in size) applied to a surface of solar float or matte/matte glass. The tin oxide based coating layer shows improved chemical stability and durability and can be prepared using a sol-gel process and applied by spin coating. Matte/matte anti-reflection glass samples may have two coating layers (e.g., SnO₂ nanoparticles on the rough side and SiO₂ nanoparticles on the smooth side) and exhibit an improved transmittance (e.g., visible transmittance) of at least 2.0%, e.g., about 3.5%. As high as a 30% increase of ΔTqe % has been observed when anti-reflection matte/matte glass coated with SnO₂ is exposed in a salt fog chamber for 5 days. The increase in transmittance may be due to the different pore structure of the SnO₂ coating layer, while the increase of Tqe % in a salt fog chamber may be due to the crystalline SnO₂ formation.

Claims

1. A method of forming a coated article with an anti-reflection coating, the method comprising:

forming a coating consisting essentially of silica particles and a binder directly on a first surface of a glass substrate; and

forming a coating comprising tin oxide directly on a second surface of the glass substrate,

wherein the glass substrate is disposed between the silica coating and the tin oxide coating.

2. The method according to claim 1, wherein forming the coating comprising tin oxide comprises

depositing at least a portion of a colloidal solution comprising the tin oxide on a glass substrate;

and

curing the coating comprising tin oxide at least by heating said glass substrate and the coating comprising tin oxide.

3. The method according to claim 2, wherein said colloidal solution contains a binder comprising tetraethyl orthosilicate.

4. The method according to claim 2, wherein the weight percentage of said tin oxide in the colloidal solution is about 2-5%.

5. The method according to claim 2, wherein said colloidal solution comprising tin oxide is applied directly to said glass substrate using a spin coating method.

6. The method according to claim 5, wherein said colloidal solution is applied using spin coating to a roughened side of said glass substrate.

7. The method according to claim 1, wherein the thickness of the coating comprising tin oxide is between 20 and 100 nm.

8. The method according to claim 1, wherein a glass transmittance of the coated article is about 2% higher than a glass transmittance of a glass substrate without the coating comprising tin oxide, wherein the glass transmittance is defined as:

9. The method according to claim 8, wherein the glass transmittance is about 3.5% higher.

10. The method according to claim 1, wherein said glass substrate is a matte/matte glass so that opposing major surfaces of the glass substrate are matte.

11. The method according to claim 1, wherein the coating comprising a silica is formed by applying a colloidal solution comprising silica to a smooth side of said glass substrate.

12. The method according to claim 11, wherein the amount of said silica in said coating is about 3% by wt.

13. The method according to claim 11, wherein said colloidal solution comprising silica contains a binder comprising tetraethyl orthosilicate.

14. The method according to claim 11, wherein the colloidal solution comprises silica nanoparticles.

15. The method of claim 1, wherein providing of the coating comprising tin oxide and the coating comprising silica increases transmittance of the coated article by at least 2% compared to if the coating comprising tin oxide and the coating comprising silica were not present.

16. The method according to claim 15, wherein the glass transmittance is about 3.5% higher.

17. The method according to claim 1, wherein the tin oxide comprises tin oxide nanoparticles.

18. The method according to claim 17, wherein the tin oxide nanoparticles range in size from about 10 to 20 nm.

19. A method of forming a coated article with an anti-reflection coating, the method comprising:

forming a first coating containing a first coating layer comprising a silica on a first surface of a glass substrate; and

forming a second coating containing a second coating layer comprising tin oxide on a second surface of the glass substrate,

wherein the glass substrate is disposed between the first coating and the second coating, and

wherein the second coating on the second surface of the glass substrate only includes the second coating layer, and wherein the first coating on the first surface of the glass substrate only includes the first coating layer.