Method and system for the in-situ decontamination of contaminated soils

• US 10,065,223 B2
• Filed: 06/21/2016
• Issued: 09/04/2018
• Est. Priority Date: 12/03/2015
• Status: Active Grant

• Current Assignee: Geo-Bohrtechnik GMBH
• Original Assignee: Geo-Bohrtechnik GMBH
• Inventors: Klock, Benjamin
• Primary Examiner(s): Fiorello, Benjamin F
• Assistant Examiner(s): Toledo-Duran, Edwin J
• Application Number:
  US15/188,269
• Publication Number:
  US 20170157654A1
• Time in Patent Office: 805 Days
• Field of Search: 4051281-1289
• CPC Class Codes: B09C 1/00 Reclamation of contaminated soil
• CPC Class Codes: B09C 1/002 involving in-situ ground water treatment
• CPC Class Codes: B09C 1/08 chemically
• CPC Class Codes: B09C 1/10 microbiologically, biologically or by using enzymes
• CPC Class Codes: B09C 2101/00 In situ
• CPC Class Codes: C02F 1/72 by oxidation C02F1/4672 takes precedence
• CPC Class Codes: C02F 2101/16 Nitrogen compounds, e.g. ammonia
• CPC Class Codes: C02F 2103/06 Contaminated groundwater or leachate
• CPC Class Codes: C02F 2305/026 Fenton's reagent
• CPC Class Codes: C02F 2305/06 Nutrients for stimulating the growth of microorganisms
• CPC Class Codes: C02F 3/00 Biological treatment of water, waste water, or sewage C02F1/006 takes precedence

Abstract

A method and an associated system for in-situ decontamination of a contaminated soil region (2) which contains degradable pollutants, in which a fluid substance is introduced into the soil (1) using an injection device (4, 4′), wherein the fluid substance is introduced into the soil using a pressure injection method in a pressure-controlled manner and/or with an injection device that has a valve pipe with a pressure-controlled outlet valve.

Claims

1. A method for in-situ decontamination of a contaminated soil region which contains pollutants degradable with a decontaminating fluid substance through chemical oxidation, comprising:

selecting, with an injection device, an injection pressure from a plurality of available injection pressures,

introducing a first component of the fluid substance via a first conduit to a depth of the contaminated soil region,

introducing a second component of the fluid substance via a second conduit physically and chemically separated from the first conduit to the depth of the contaminated soil region,

mixing the introduced first component and the introduced second component at the depth to produce the decontaminating fluid substance,

injecting the decontaminating fluid substance at the selected pressure from at least one outlet valve, and

directing the injected fluid substance from the outlet valve into the contaminated soil region between horizontal bars that protrude radially towards the contaminated soil region.

2. The method as claimed in claim 1, wherein

injecting comprises repeated injections of the decontaminating fluid substance into at least the contaminated soil region.

3. The method as claimed in claim 1, wherein

at least one of the two components contains permanganate.

4. The method as claimed in claim 1, wherein the decontaminating fluid substance is an oxidant.

5. A method for in-situ decontamination of a contaminated soil region which contains pollutants degradable with a decontaminating fluid substance through chemical oxidation, comprising:

selecting, with an injection device, an injection pressure from a plurality of available injection pressures,

selecting, with the injection device, from among a plurality of available upper and lower axial boundaries,

constraining propagation elevations for the decontaminating fluid substance through the selected axial boundaries,

mixing components of the fluid substance, to produce the decontaminating fluid substance, between the selected upper and lower axial boundaries,

injecting the decontaminating fluid substance at the selected pressure and within the selected axial boundaries from at least one outlet valve into at least the contaminated soil region, and

directing the injected decontaminating fluid substance into the contaminated soil region with horizontal bars that protrude radially from and at least partly around the outlet valve towards the contaminated soil region.

6. The method as claimed in claim 5, wherein

at least one of the two components contains potassium permanganate.

7. The method as claimed in claim 5, wherein

the decontaminating fluid substance is a mixture of two components forming Fenton'"'"'s reagent.

8. The method as claimed in claim 5, further comprising:

forming a hole to extend at least into the contaminated soil region,

inserting a pipe into the hole to extend at least into the contaminated soil region, and filling an annular space between an inner wall of the hole and an outer wall of the pipe with a sheathing compound, to form a casing,

wherein the injection pressure suffices to break open the casing when the decontaminating fluid substance is injected into the contaminated soil region via the pipe.

9. A system for in-situ decontamination of a contaminated soil region in a soil which contains degradable pollutants, comprising:

a source configured to provide a first component of a fluid substance and

a second component of the fluid substance physically and chemically separated from the first component,

an outlet valve arranged at a depth of the contaminated soil region in the soil,

an injection line extending between the source and the outlet valve,

a pump and a valve pipe arranged in the injection line, and

a mixing device arranged in the injection line between the pump and the outlet valve, and configured to mix the first component and the second component to produce a decontaminating fluid substance,

wherein the valve pipe comprises an outer wall with radially protruding horizontal bars configured to direct the fluid substance radially away from the valve pipe and into the contaminated soil region, and configured to delimit a propagation direction of the decontaminating fluid substance in the soil,

wherein the injection line comprises a superterranean portion and a subterranean portion, and

wherein the mixing device is arranged in the subterranean portion of the injection line.

11. The system as claimed in claim 9, wherein

the valve pipe further comprises a sleeve pipe having at least one sleeve valve.

12. The system as claimed in claim 9, further comprising:

a casing of sheathing compound extending between the outer wall of the valve pipe and the contaminated soil region, and filling an annular space between the valve pipe and the soil,

wherein the casing fixes the valve pipe in the soil, and

wherein the casing is configured to break open in response to propagation of the fluid substance radially away from the valve pipe.

10. The system as claimed in 9,

wherein the mixing device is arranged at a depth in the soil corresponding at least substantially to a depth in the soil of the outlet valve.

13. A system for in-situ decontamination of a contaminated region which contains degradable pollutants in a soil, comprising:

a source configured to provide a first component and a second component of a decontaminating fluid substance,

an outlet valve in a valve pipe and arranged at a depth in the soil of the contaminated region, an injection line extending between the source and the outlet valve, and configured to convey the first component and the second component in mutually separated conduits to a mixing device for the components arranged upstream of the outlet valve,

a pump arranged in the injection line, and

horizontal bars extending radially from an outer wall of the valve pipe and at least partly circumferentially around the valve pipe towards the contaminated region, and configured to delimit elevations of propagation of the decontaminating fluid substance to a depth range within the soil that corresponds to the contaminated region.

14. The system as claimed in claim 13, wherein the horizontal bars extend fully circumferentially around the valve pipe.

15. The system as claimed in claim 13, wherein

the mixing device is arranged at the depth of the soil of the contaminated soil region.

16. The system as claimed in claim 13, wherein

the mixing device is arranged in an interior of the valve pipe.

17. The system as claimed in claim 13, further comprising:

a casing of sheathing compound extending between the outlet valve and the contaminated soil region, and filling an annular space between the valve pipe and the soil,

wherein the casing fixes the valve pipe in the soil, and

wherein the casing is configured to break open in response to the propagation of the decontaminating fluid substance.