Three-dimensional waveguide sensors for sample analysis

• US 10,073,188 B2
• Filed: 10/02/2014
• Issued: 09/11/2018
• Est. Priority Date: 10/02/2014
• Status: Active Grant

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Pearl, Jr., William Cecil, Pearl, Megan Renee, Perkins, David L., Skinner, Neal G.
• Primary Examiner(s): Smith, Chad H
• Application Number:
  US14/781,053
• Publication Number:
  US 20160231460A1
• Time in Patent Office: 1,440 Days
• Field of Search: None
• CPC Class Codes: G01B 9/02049 characterised by particular mechanical design details
• CPC Class Codes: G01N 2021/458 using interferential sensor, e.g. sensor fibre, possibly on optical waveguide
• CPC Class Codes: G01N 21/45 using interferometric methods; using Schlieren methods
• CPC Class Codes: G01N 21/7703 using reagent-clad optical fibres or optical waveguides using measurement of total internal reflection or attenuated total reflection G01N21/552; optical fibres or waveguides per se G02B
• CPC Class Codes: G01V 8/16 using optical fibres
• CPC Class Codes: G02B 1/10 Optical coatings produced by application to, or surface treatment of, optical elements G02B1/08 takes precedence
• CPC Class Codes: G02B 6/00 Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
• CPC Class Codes: G02B 6/10 of the optical waveguide type G02B6/02, G02B6/24 take precedence; devices or arrangements for the control of light by electric, magnetic, electro-magnetic or acoustic means G02F1/00; transferring the modulation of modulated light G02F2/00; optical logic elements G02F3/00; optical analogue/digital converters G02F7/00
• CPC Class Codes: G02B 6/29352 in a light guide

Abstract

Systems and methods for measuring a characteristic of a fluid are provided. The system includes a plurality of waveguides embedded in a substrate, and an exposed surface of the substrate comprising a portion of a side surface of at least one of the plurality of waveguides. The system also includes a sensitized coating in the at least one of the plurality of waveguides. The exposed surface is curved in a direction perpendicular to a light propagation in the waveguide. A method of fabricating a system as above is also provided.

Claims

1. A sensor for measuring a characteristic of a substance, comprising:

a plurality of sensing channels positioned along an exposed surface of a substrate, each of the plurality of sensing channels comprising a plurality of waveguides embedded in the substrate, wherein a first group of sensing channels of the plurality of sensing channels share a first reference waveguide of the plurality of waveguides and a second group of sensing channels of the plurality of sensing channels share a second reference waveguide of the plurality of waveguides, the first reference waveguide being different from the second reference waveguide, the exposed surface comprising a portion of a side surface of at least one of the plurality of waveguides;

a sensitized coating positioned on the exposed surface of the at least one of the plurality of waveguides along a longitudinal axis of the sensor; and

a mask disposed on an end surface of the substrate that is orthogonal to the longitudinal axis of the sensor, the mask being in contact with transparent portions of the substrate and the plurality of waveguides.

2. The sensor of claim 1, wherein the exposed surface is curved in a direction perpendicular to a light propagation in the waveguide.

3. The sensor of claim 1, further comprising a detector arranged to receive an interference pattern generated from two waveguides of the plurality of waveguides, the detector being configured to generate a signal corresponding to a change in an interference pattern, the change in the interference pattern induced by the characteristic of the substance.

4. The sensor of claim 3, wherein the interference pattern is formed in a free space between the detector and an optical output of the waveguides.

5. The sensor of claim 1, wherein the sensitized coating comprises one of a chemically sensitive layer, a biologically sensitive layer, a hydrophilic layer, or a hydrophobic layer.

6. The sensor of claim 1, wherein the plurality of waveguides comprise:

a sample waveguide having the sensitized coating positioned thereon and being optically coupled with a signal electromagnetic radiation; and

a reference waveguide adjacent the sample waveguide and being optically coupled with a reference electromagnetic radiation, the reference radiation having a determined phase relation with the signal electromagnetic radiation.

7. The sensor of claim 6, further comprising:

a second sample waveguide being optically coupled with a second signal electromagnetic radiation, wherein the second signal electromagnetic radiation has a determined phase relation with the reference electromagnetic radiation.

8. The sensor of claim 1, wherein the mask is applied to the substrate to prevent background radiation in the substrate from reaching a detector.

9. The sensor of claim 1, wherein the sensitized coating targets one of the group consisting of water, gas, oil, methane, a hydrocarbon, a unicellular microorganism, an iron ion, and an alkali metal.

10. The sensor of claim 1, wherein the plurality of waveguides include at least a sample waveguide and a reference waveguide, the sensor further comprising a detector array to measure at least a portion of an interference pattern generated by the sample waveguide and the reference waveguide.

11. The sensor of claim 1, wherein the sensitized coating is configured to contact a substance including a target analyte.

12. The sensor of claim 1, wherein the substrate is cylindrical and the exposed surface is positioned at an inner diameter of the substrate.

13. A method for measuring a characteristic of a substance, the method comprising:

exposing a surface of a sensor to the substance, the sensor including a substrate and a plurality of sensing channels positioned along the exposed surface of the sensor, each of the plurality of sensing channels comprising a plurality of waveguides embedded in the substrate, wherein a first group of sensing channels of the plurality of sensing channels share a first reference waveguide of the plurality of waveguides and a second group of sensing channels of the plurality of sensing channels share a second reference waveguide of the plurality of waveguides, the first reference waveguide being different from the second reference waveguide, the exposed surface of the sensor including a sensitized coating positioned on a portion of at least one of the plurality of waveguides along a longitudinal axis of the sensor, the substrate including a mask disposed on an end surface of the substrate that is orthogonal to the longitudinal axis of the sensor, the mask being in contact with transparent portions of the substrate and the plurality of waveguides;

directing a first portion of light through a first waveguide of the plurality of waveguides and thereby generating a first output signal;

directing a second portion of light through a second waveguide of the plurality of waveguides and thereby generating a second output signal;

obtaining a phase relation between the first portion of light and the second portion of light at an output of the first and second waveguides;

generating an interference signal by combining the first and second output signals;

detecting at least a portion of the interference signal with a detector; and

determining the characteristic of the substance based on a change in a feature of the interference signal detected with the detector.

14. The method of claim 13, wherein exposing the surface of the sensor comprises allowing a target analyte to reach equilibrium on the surface of the sensor.

15. The method of claim 13, wherein obtaining a phase relation between the first portion of light and the second portion of light comprises splitting a light beam from a light source into the first portion of light and the second portion of light with a phase-preserving beam splitter element.

16. The method of claim 13, wherein detecting the interference signal with the detector comprises detecting a portion of the interference signal comprising at least one of a peak, a dark node, or a portion of a peak and a dark node.

17. The method of claim 13, wherein detecting the interference signal with the detector comprises coupling at least a portion of the interference signal to an optical fiber and transmitting the coupled portion to a remotely located detector.

18. The method of claim 13, wherein obtaining a phase relation between the first portion of light and the second portion of light comprises illuminating the first and second waveguides with a collimated and coherent light.

19. The method of claim 13, wherein determining the characteristic of the substance comprises finding the characteristic of the substance in a lookup table having a list of characteristics of the substance and a list of changes in interference signal values.

20. The method of claim 13, wherein determining the characteristic of the substance comprises determining at least one of a water concentration, a gas concentration, an oil concentration, a water-to-oil ratio, a methane concentration, or a hydrocarbon concentration, a unicellular microorganism presence or a unicellular microorganism concentration.

21. The method of claim 13, wherein determining the characteristic of the substance comprises determining a characteristic of a mud in a wellbore of a drilling system.

22. The method of claim 13, wherein determining the characteristic of the substance comprises determining a characteristic of a well fluid present in a wellbore of well a system.