Methods of mitigating bituminous material adhesion using nano-particles

• US 10,077,606 B2
• Filed: 03/27/2013
• Issued: 09/18/2018
• Est. Priority Date: 03/27/2013
• Status: Active Grant

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Hall, Lee J., Livanec, Philip W.
• Primary Examiner(s): Tran, Binh X
• Assistant Examiner(s): Cathey, Jr., David
• Application Number:
  US13/851,374
• Publication Number:
  US 20140290692A1
• Time in Patent Office: 2,001 Days
• Field of Search: None
• CPC Class Codes: B08B 3/04 Cleaning involving contact with liquid
• CPC Class Codes: C09K 2208/10 Nanoparticle-containing well treatment fluids
• CPC Class Codes: C09K 8/03 Specific additives for general use in well-drilling compositions
• CPC Class Codes: C09K 8/524 organic depositions, e.g. paraffins or asphaltenes
• CPC Class Codes: E21B 37/06 using chemical means for preventing or limiting , e.g. eliminating, the deposition of paraffins or like substances
• CPC Class Codes: E21B 7/00 Special methods or apparatus for drilling

Abstract

Embodiments relate to solid nano-particles applied to the surface of well equipment to treat bituminous material adhesion. An embodiment provides a method of treating the surface of well equipment. The method may comprise applying a solid nanoparticle film to the surface of the well equipment with a treatment fluid comprising solid nanoparticles. The method may further comprise allowing the solid nanoparticles to interact with the surface of the well equipment and/or bituminous materials adhered to the surface of the well equipment to remove at least a portion of the bituminous materials from the surface of the well equipment.

Claims

1. A method of treating bituminous materials, comprising:

providing solid nanoparticles that are functionalized, wherein the solid nanoparticles comprise Fe2O3 or CaCO3 wherein the solid nanoparticles are functionalized with polyvinyl pyrrolidone or polyethyleneimine, wherein the solid nanoparticles have an average particle size of about 5 nm to about 50 nm, wherein the solid nanoparticles have a roundness of greater than 0.7 measured on the Krumbein scale, and wherein the solid nanoparticles have a sphericity of greater than 0.7 measured on the Krumbein scale;

using a drill bit to enlarge a well bore in a subterranean formation, wherein bituminous materials from the subterranean formation enters the well bore and adheres to well bore equipment in the well bore;

circulating a treatment fluid past the drill bit, the treatment fluid comprising the solid nanoparticles, wherein the solid nanoparticles interact with the surface of the well bore equipment and/or the bituminous materials to remove at least a portion of the bituminous materials from the well bore equipment;

forming a solid nanoparticle film at the surface of the well bore equipment wherein the solid nanoparticle film exerts a disjointing force on the bituminous materials that forms a wedge driving separation of the bituminous materials from the surfaces of the well equipment; and

filtering the bituminous materials from the treatment fluid.

2. The method of claim 1 wherein the concentration of solid nanoparticles in the treatment fluid is between about 0.1% and about 5% by volume of the treatment fluid.

3. The method of claim 1 wherein the treatment fluid further comprises an additive selected from the group consisting of:

salts, surfactants, fluid-loss-control additives, gas, nitrogen, carbon dioxide, surface-modifying agents, tackifying agents, foamers, corrosion inhibitors, scale inhibitors, catalysts, clay-control agents, biocides, friction reducers, antifoam agents, bridging agents, dispersants, flocculants, H₂S scavengers, CO₂ scavengers, oxygen scavengers, lubricants, viscosifiers, breakers, weighting agents, relative-permeability modifiers, resins, particulate materials, wetting agents, coating-enhancement agents, and the like.

4. The method of claim 1 wherein the well bore equipment comprises equipment selected from the group consisting of:

drill pipe, drill collars, drills bits, directional drills, casings, liners, and any combination thereof.

5. A method of treating bituminous materials, comprising:

using a drill bit to enlarge a well bore in a subterranean formation, wherein bituminous materials from the subterranean formation enters the well bore and adheres to well bore equipment in the well bore;

providing a treatment fluid comprising solid nanoparticles that are functionalized, wherein the solid nanoparticles comprise nano-silica or nano-alumina wherein the solid nanoparticles are functionalized with trichlorosilane, wherein the solid nanoparticles have an average particle size of about 5 nm to about 50 nm, wherein the solid nanoparticles have a roundness of greater than 0.7 measured on the Krumbein scale, and wherein the solid nanoparticles have a sphericity of greater than 0.7 measured on the Krumbein scale;

circulating the treatment fluid past the drill bit;

forming a solid nanoparticle film at the surface of the well bore equipment wherein the solid nanoparticle film exerts a disjointing force on the drilling fluid residue that forms a wedge driving separation of the drilling fluid residue from the surfaces of the well equipment; and

filtering the bituminous materials from the treatment fluid.

6. The method of claim 5 of the well bore equipment wherein the concentration of solid nanoparticles in the treatment fluid is between about 0.1% and about 5% by volume of the treatment fluid.

7. The method of claim 5 wherein the treatment fluid further comprise a polymer selected from the group consisting of styrene polymers and any derivative thereof, acrylate polymers and any derivative thereof, styrene-acrylate polymers and any derivative thereof, acrylonitrile-butadiene polymers and any derivative thereof, and any combination thereof.

8. The method of claim 5 wherein the treatment fluid further comprises an additive selected from the group consisting of:

salts, surfactants, fluid-loss-control additives, gas, nitrogen, carbon dioxide, surface-modifying agents, tackifying agents, foamers, corrosion inhibitors, scale inhibitors, catalysts, clay-control agents, biocides, friction reducers, antifoam agents, bridging agents, dispersants, flocculants, H₂S scavengers, CO₂ scavengers, oxygen scavengers, lubricants, viscosifiers, breakers, weighting agents, relative-permeability modifiers, resins, particulate materials, wetting agents, coating-enhancement agents, and combinations thereof.

9. The method of claim 5 wherein the well bore equipment comprises equipment selected from the group consisting of:

drill pipe, drill collars, drills bits, directional drills, casings, liners, and any combination thereof.