Electrospun aligned nanofiber adhesives with mechanical interlocks

• US 10,081,891 B2
• Filed: 05/22/2015
• Issued: 09/25/2018
• Est. Priority Date: 08/06/2012
• Status: Active Grant

• Current Assignee: University of Akron
• Original Assignee: University of Akron
• Inventors: Wong, Shing-Chung Josh
• Primary Examiner(s): Tatesure, Vincent
• Application Number:
  US14/720,117
• Publication Number:
  US 20150252223A1
• Time in Patent Office: 1,222 Days
• Field of Search: 428114, 442149
• CPC Class Codes: C09J 2301/31 the adhesive effect being based on a Gecko structure
• CPC Class Codes: C09J 2400/263 in the substrate
• CPC Class Codes: C09J 5/00 Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
• CPC Class Codes: D04H 1/74 the fibres being orientated, e.g. in parallel (anisotropic fleeces)
• CPC Class Codes: Y10T 29/49801 Shaping fiber or fibered material
• CPC Class Codes: Y10T 29/53526 Running-length work
• CPC Class Codes: Y10T 428/24132 including grain, strips, or filamentary elements in different layers or components parallel

Abstract

A dry adhesive includes a first plurality of fiber segments mechanically interlocked with a second plurality of fiber segments. A dry adhesive can include a first plurality of fibers mechanically interlocked with a second plurality of fibers or a single plurality of fibers having a first end region mechanically interlocked with a second end region. The fiber segments and fibers can be aligned, electrospun nanofibers. One or more continuous and scalable methods of making aligned fibers are also provided. One or more apparatuses are also provided.

Claims

1. A dry adhesive comprising a first fiber mat on a first face stock, said first fiber mat made from a first plurality of substantially aligned electrospun fiber segments having void spaces therebetween, a second fiber mat on a second face stock, said second fiber mat made from a second plurality of substantially aligned electrospun fiber segments having void spaces therebetween, said first plurality of substantially aligned electrospun fiber segments being intimately positioned in said void spaces between said second plurality of substantially aligned electrospun fiber segments, said second plurality of substantially aligned electrospun fiber segments being intimately positioned in said void spaces between said first plurality of substantially aligned electrospun fiber segments, such that said first plurality of substantially aligned electrospun fiber segments and said second plurality of substantially aligned electrospun fiber segments are mechanically interlocked, where the dry adhesive has a shear adhesion strength of at least 40 N/cm², wherein the direction of substantial alignment of said first plurality of substantially aligned fiber segments is parallel with said first face stock and the direction of substantial alignment of said second plurality of substantially aligned fiber segments is parallel with said second face stock.

2. A method for securing two substrates with the dry adhesive of claim 1 comprising the steps of:

providing the first fiber mat on the first face stock;

providing the second fiber mat on the first face stock;

positioning the first plurality of substantially aligned electrospun fiber segments in the void spaces of the second plurality of substantially aligned electrospun fiber segments; and

positioning the second plurality of substantially aligned electrospun fiber segments in the void spaces of the first plurality of substantially aligned electrospun fiber segments;

where the positioning steps form a mechanical interlock region utilizing the first plurality of electrospun fiber segments and the second plurality of electrospun fiber segments of the second substrate.

3. The method of claim 2, further comprising the step of removing air from the mechanical interlock region.

4. The dry adhesive of claim 1, where the dry adhesive has a shear adhesion strength of at least 45 N/cm².

5. The dry adhesive of claim 1, where the dry adhesive has a shear adhesion strength of at least 50 N/cm².

6. The dry adhesive of claim 1, wherein the average diameter of the nanofibers is from 50 nanometers to 1000 nanometers.

7. The dry adhesive of claim 1, wherein the dry adhesive has a shear adhesion strength that is higher than the normal adhesion strength.

8. The dry adhesive of claim 1, wherein the dry adhesive has a shear adhesion strength that is at least 3000% higher than the normal adhesion strength.

9. A dry adhesive comprising a first face stock carrying a first electrospun fiber mat made from electrospun fibers having void spaces therebetween, and a second face stock carrying a second electrospun fiber mat made from electrospun fibers having void spaces therebetween, said electrospun fibers of said first electrospun fiber mat being intimately positioned in said void spaces between said electrospun fibers of said second electrospun fiber mat, said electrospun fibers of said second electrospun fiber mat being intimately positioned in said void spaces between said electrospun fibers of said first electrospun fiber mat, such that said electrospun fibers of said first electrospun fiber mat and said electrospun fibers of said second electrospun fiber mat are mechanically interlocked, said first electrospun fiber mat extending in an in-plane direction with said first face stock and said second electrospun fiber mat extending in an in-plane direction with said second face stock.

10. The dry adhesive of claim 9, said first face stock having a surface area and said second face stock having a surface area, wherein the surface area coverage of said first face stock by said first electrospun fiber mat is at least 85 percent and the surface area coverage of said second face stock by said second electrospun fiber mat is at least 85 percent.

11. The dry adhesive of claim 9, said first face stock having a surface area and said second face stock having a surface area, wherein the surface area coverage of said first face stock by said first electrospun fiber mat is at least 95 percent and the surface area coverage of said second face stock by said second electrospun fiber mat is at least 95 percent.

12. A dry adhesive comprising a first face stock extending in a planar direction and carrying a first fiber mat made from a first plurality of electrospun fibers having void spaces therebetween, and a second face stock extending in a planar direction and carrying a second fiber mat made from a second plurality of electrospun fibers having void spaces therebetween, said first plurality of electrospun fibers being intimately positioned in said void spaces between said second plurality of electrospun fibers, said second plurality of electrospun fibers being intimately positioned in said void spaces between said first plurality of electrospun fibers, such that said first plurality of electrospun fibers and said second plurality of electrospun fibers are mechanically interlocked, wherein the entirety of said first plurality of electrospun fibers extend in said planar direction of said first face stock, and wherein the entirety of said second plurality of electrospun fibers extend in said planar direction of said second face stock.