Organic electroluminescent element and lighting device

• US 10,084,146 B2
• Filed: 02/29/2016
• Issued: 09/25/2018
• Est. Priority Date: 03/02/2015
• Status: Active Grant

• Current Assignee: Xianyang CHVT New Display Technology Co., Ltd.
• Original Assignee: Lumiotec Inc. (V Technology Co., Ltd.)
• Inventors: Tanaka, Junichi, Morimoto, Mitsuru
• Primary Examiner(s): Nguyen, Cuong B
• Assistant Examiner(s): Park, Samuel
• Application Number:
  US15/554,528
• Publication Number:
  US 20180047926A1
• Time in Patent Office: 939 Days
• CPC Class Codes: H05B 33/26 characterised by the composition or arrangement of the conductive material used as an electrode
• CPC Class Codes: H10K 2101/20 Delayed fluorescence emission
• CPC Class Codes: H10K 2101/27 Combination of fluorescent and phosphorescent emission
• CPC Class Codes: H10K 2102/302 of OLED structures
• CPC Class Codes: H10K 2102/351 Thickness
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/131 with spacer layers between the electroluminescent layers
• CPC Class Codes: H10K 50/15 Hole transporting layers
• CPC Class Codes: H10K 50/16 Electron transporting layers
• CPC Class Codes: H10K 50/171 Electron injection layers
• CPC Class Codes: H10K 50/19 Tandem OLEDs
• CPC Class Codes: H10K 50/81 Anodes
• CPC Class Codes: H10K 50/82 Cathodes
• CPC Class Codes: H10K 50/824 combined with auxiliary electrodes
• CPC Class Codes: H10K 59/131 Interconnections, e.g. wiring lines or terminals
• CPC Class Codes: H10K 59/32 Stacked devices having two or more layers, each emitting at different wavelengths
• CPC Class Codes: H10K 85/341 Transition metal complexes, e.g. Ru(II)polypyridine complexes H10K85/331 takes precedence
• CPC Class Codes: H10K 85/6572 comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole

Abstract

The present invention provides an organic electroluminescent element which includes a first light emitting unit (23) that is positioned on the side of a cathode (21) and includes a first light emitting layer (28A), a second light emitting unit (24) that is adjacent to the first light emitting unit (23) with sandwiching a first charge generating layer (26A) and includes a second light emitting layer (28B), and a third light emitting unit (25) that is adjacent to the second light emitting unit (24) with sandwiching a second charge generating layer (26B) and includes a third light emitting layer (28C), and in which differences of the total thickness of the first light emitting unit (23) and the total thickness of the third light emitting unit (25) with the total thickness of the second light emitting unit (24) are 30 nm to 70 nm.

Claims

1. An organic electroluminescent element which has a structure in which a plurality of light emitting units including at least a light emitting layer made of an organic compound are laminated between a cathode and an anode with a charge generating layer between the light emitting units and in which white light is obtained when the plurality of light emitting units emit light, the organic electroluminescent element comprising:

a first light emitting unit that is positioned closest to the side of the cathode among the plurality of light emitting units;

a second light emitting unit that is adjacent to the first light emitting unit with sandwiching a first charge generating layer; and

a third light emitting unit that is adjacent to the second light emitting unit with sandwiching a second charge generating layer,

wherein the first light emitting unit includes a first light emitting layer, a first functional layer including an electron transporting layer between the first light emitting layer and the cathode, and a second functional layer including a hole transporting layer between the first light emitting layer and the first charge generating layer,

wherein the second light emitting unit includes a second light emitting layer, a third functional layer including an electron transporting layer between the second light emitting layer and the first charge generating layer, and a fourth functional layer including a hole transporting layer between the second light emitting layer and the second charge generating layer,

wherein the third light emitting unit includes a third light emitting layer, a fifth functional layer including an electron transporting layer between the third light emitting layer and the second charge generating layer, and a sixth functional layer including a hole transporting layer between the third light emitting layer and the anode,

wherein the thickness of the third functional layer and the thickness of the fifth functional layer are smaller than the thickness of the first functional layer,

wherein the first light emitting unit and the third light emitting unit include a phosphorescent light emitting layer capable of emitting light from triplet excitons,

wherein the second light emitting unit includes a blue fluorescent light emitting layer capable of emitting light from singlet excitons, and

wherein differences of the total thickness of the first light emitting unit and the total thickness of the third light emitting unit with the total thickness of the second light emitting unit are 30 nm to 70 nm.

2. The organic electroluminescent element according to claim 1,

wherein the first light emitting layer is a red phosphorescent light emitting layer that emits red light having a peak wavelength in a red wavelength range,

wherein the second light emitting layer is a blue fluorescent light emitting layer that emits blue light having a peak wavelength in a blue wavelength range, and

wherein the third light emitting layer is a green phosphorescent light emitting layer that emits green light having a peak wavelength in a green wavelength range.

3. The organic electroluminescent element according to claim 1,

wherein the thickness of the first functional layer is 30 nm to 70 nm.

4. The organic electroluminescent element according to claim 1,

wherein the thickness of the third functional layer and the thickness of the fifth functional layer are 1 nm to 20 nm.

5. The organic electroluminescent element according to claim 1,

wherein light emitted from the light emitting unit including the blue fluorescent light emitting layer includes a delayed fluorescent component.

6. The organic electroluminescent element according to claim 1,

wherein the total thickness of the second light emitting unit is smaller than both the total thickness of the first light emitting unit and the total thickness of the third light emitting unit.

7. The organic electroluminescent element according to claim 1,

wherein the charge generating layer is an electrically insulating layer made of an electron accepting substance and an electron donating substance, and the resistivity of the electrically insulating layer is 1.0×

10² Ω

·

cm or more.

8. The organic electroluminescent element according to claim 7,

wherein the resistivity of the electrically insulating layer is 1.0×

10⁵ Ω

·

cm or more.

9. The organic electroluminescent element according to claim 1,

wherein the charge generating layer is a layer in which different substances are mixed, one component of the substances is a metal oxide, and the metal oxide forms a charge transfer complex due to a redox reaction, and

wherein, when a voltage is applied between the cathode and the anode, charges in the charge transfer complex move toward the cathode and the anode, holes are injected into one light emitting unit positioned on the side of the cathode with sandwiching the charge generating layer, and electrons are injected into the other light emitting unit positioned on the side of the anode with sandwiching the charge generating layer.

10. The organic electroluminescent element according to claim 1,

wherein the charge generating layer is made of a laminate of an electron accepting substance and an electron donating substance, and

wherein, when a voltage is applied between the cathode and the anode, charges generated due to a reaction according to electron movement between the electron accepting substance and the electron donating substance move toward the cathode and the anode at the interface between the electron accepting substance and the electron donating substance, and thus holes are injected into one light emitting unit positioned on the side of the cathode with sandwiching the charge generating layer, and electrons are injected into the other light emitting unit positioned on the side of the anode with sandwiching the charge generating layer.

11. The organic electroluminescent element according to claim 1,

wherein the charge generating layer is formed of a laminate or a mixture of a material according to the following Structural Formula (1) and another organic material

12. The organic electroluminescent element according to claim 1, wherein a luminescent color of the white light is classified into a light bulb color (L) or a warm white color (WW) in a chromaticity range and an average color rendering index (Ra) of the white light is 70 or more.

13. A lighting device comprising the organic electroluminescent element according to claim 1.

14. The organic electroluminescent element according to claim 2,

wherein the thickness of the first functional layer is 30 nm to 70 nm.

15. The organic electroluminescent element according to claim 2,

wherein the thickness of the third functional layer and the thickness of the fifth functional layer are 1 nm to 20 nm.

16. The organic electroluminescent element according to claim 2,

wherein light emitted from the light emitting unit including the blue fluorescent light emitting layer includes a delayed fluorescent component.

17. The organic electroluminescent element according to claim 2,

wherein the charge generating layer is an electrically insulating layer made of an electron accepting substance and an electron donating substance, and the resistivity of the electrically insulating layer is 1.0×

10² Ω

·

cm or more.

18. The organic electroluminescent element according to claim 2,

wherein the charge generating layer is a layer in which different substances are mixed, one component of the substances is a metal oxide, and the metal oxide forms a charge transfer complex due to a redox reaction, and

wherein, when a voltage is applied between the cathode and the anode, charges in the charge transfer complex move toward the cathode and the anode, holes are injected into one light emitting unit positioned on the side of the cathode with sandwiching the charge generating layer, and electrons are injected into the other light emitting unit positioned on the side of the anode with sandwiching the charge generating layer.

19. The organic electroluminescent element according to claim 2,

wherein the charge generating layer is made of a laminate of an electron accepting substance and an electron donating substance, and

wherein, when a voltage is applied between the cathode and the anode, charges generated due to a reaction according to electron movement between the electron accepting substance and the electron donating substance move toward the cathode and the anode at the interface between the electron accepting substance and the electron donating substance, and thus holes are injected into one light emitting unit positioned on the side of the cathode with sandwiching the charge generating layer, and electrons are injected into the other light emitting unit positioned on the side of the anode with sandwiching the charge generating layer.

20. A lighting device comprising the organic electroluminescent element according to claim 2.