Submerged combustion melting processes for producing glass and similar materials, and systems for carrying out such processes

• US 10,087,097 B2
• Filed: 06/26/2015
• Issued: 10/02/2018
• Est. Priority Date: 06/11/2012
• Status: Active Grant

• Current Assignee: Johns Manville Corporation (Berkshire Hathaway Incorporated)
• Original Assignee: Johns Manville Corporation (Berkshire Hathaway Incorporated)
• Inventors: Charbonneau, Mark William
• Primary Examiner(s): Lazorcik, Jason L
• Application Number:
  US14/752,556
• Publication Number:
  US 20160002084A1
• Time in Patent Office: 1,194 Days
• Field of Search: 65 2919, 65 29, 65 21, 65162
• CPC Class Codes: C03B 2211/22 by direct combustion in the melt
• CPC Class Codes: C03B 2211/70 Skull melting, i.e. melting or refining in cooled wall crucibles or within solidified glass crust, e.g. in continuous walled vessels
• CPC Class Codes: C03B 3/023 Preheating
• CPC Class Codes: C03B 5/04 in tank furnaces C03B5/02 takes precedence
• CPC Class Codes: C03B 5/167 Means for preventing damage to equipment, e.g. by molten glass, hot gases, batches C03B5/20, C03B5/42 take precedence
• CPC Class Codes: C03B 5/205 Mechanical means for skimming or scraping the melt surface
• CPC Class Codes: C03B 5/2356 Submerged heating, e.g. by using heat pipes, hot gas or submerged combustion burners bubblers C03B5/193
• CPC Class Codes: C03B 5/24 Automatically regulating the melting process
• CPC Class Codes: C03B 5/44 Cooling arrangements for furnace walls
• CPC Class Codes: C03B 7/06 Means for thermal conditioning or controlling the temperature of the glass
• CPC Class Codes: Y02P 40/50 Glass production, e.g. reusing waste heat during processing or shaping

Abstract

Processes of controlling submerged combustion melters, and systems for carrying out the methods. One process includes feeding vitrifiable material into a melter vessel, the melter vessel including a fluid-cooled refractory panel in its floor, ceiling, and/or sidewall, and heating the vitrifiable material with a burner directing combustion products into the melting zone under a level of the molten material in the zone. Burners impart turbulence to the molten material in the melting zone. The fluid-cooled refractory panel is cooled, forming a modified panel having a frozen or highly viscous material layer on a surface of the panel facing the molten material, and a sensor senses temperature of the modified panel using a protected thermocouple positioned in the modified panel shielded from direct contact with turbulent molten material. Processes include controlling the melter using the temperature of the modified panel. Other processes and systems are presented.

Claims

1. A system comprising:

melter vessel comprising a floor, a ceiling, and a wall connecting the floor and ceiling at a perimeter of the floor and ceiling, the floor, ceiling, and wall defining a melting zone, the wall comprising a feed end wall, a first portion of an exit end wall, and a second portion of the exit end wall, the feed end wall and the first portion of the exit end wall forming angles “

α

” and

“

β

”

, respectively, with respect to the floor, angles α and

β

may be the same or different and each ranges from about 45 degrees to about 75 degrees, the melter vessel comprising a feed opening in the feed end wall or ceiling and the first and second portions of the exit end wall comprising a melter exit structure for discharging molten material formed in the melting zone, the melter vessel comprising at least one fluid-cooled refractory panel in its floor, ceiling, and the feed end wall, and one or more submerged combustion burners positioned to direct combustion products substantially perpendicularly into the melting zone under a level of molten material in the melting zone and form a turbulent molten material having a turbulent molten material surface facing the ceiling, the at least one fluid-cooled refractory panel configured to be modified during operation of the melter vessel to have a frozen or highly viscous material layer, or combination thereof, formed on at least a portion of a surface of the panel facing the molten material,

the melter vessel further comprising a one or more thermocouples in the refractory of the at least one fluid-cooled refractory panel or in the frozen or highly viscous material layer of the modified panel for sensing a temperature of the modified panel; and

a controller configured to control the melter vessel using the temperature of the modified panel to achieve a desired melt temperature of at least a portion of the turbulent molten material in the melting zone.

2. The system of claim 1 wherein the one or more thermocouple has a distal end buried in the refractory of the modified panel.

3. The system of claim 1 wherein the one or more thermocouple has a distal end positioned flush with the surface of the panel facing the molten material.

4. The system of claim 1 wherein the one or more thermocouple has a distal end buried in the frozen or highly viscous material layer of the modified panel.

5. The system of claim 1, wherein the modified panel comprises a plurality of thermocouples positioned in the modified panel so as to be shielded from direct contact with turbulent molten material in the melting zone.

6. The system of claim 1 wherein the melter vessel comprises a fluid-cooled refractory skimmer configured to form a frozen or highly viscous material layer, or combination thereof, on outer surfaces thereof contacting the molten material, forming a modified skimmer, the modified skimmer extending downward from the ceiling of the melter vessel and positioned upstream of the melter exit structure, the modified skimmer having a lower distal end defining a top of a throat of the melter vessel, the throat controlling the discharge of molten material from the melter vessel, and a second thermocouple positioned in the refractory of the fluid-cooled refractory skimmer or in the frozen or highly viscous material layer of the modified skimmer.

7. The system of claim 1 wherein the melter exit structure comprises a fluid-cooled refractory panel configured to form a frozen or highly viscous material layer, or combination thereof, on an inner surface thereof facing the molten material, forming a modified melter exit structure, and a second thermocouple positioned in the refractory of the fluid-cooled refractory panel or in the frozen or highly viscous material layer of the modified melter exit structure.

8. A system comprising:

melter vessel comprising a floor, a ceiling, and a wall connecting the floor and ceiling at a perimeter of the floor and ceiling, the floor, ceiling, and wall defining a melting zone, the wall comprising a feed end wall and an exit end wall, the melter vessel comprising a fluid-cooled refractory skimmer extending downwardly substantially in line with a downstream wall of a stack, a lower distal end of the skimmer forming a submerged throat with the exit end wall, the feed end wall and the exit end wall forming angles “

α

” and

“

β

”

, respectively, with respect to the floor, angles α and

β

may be the same or different and each ranges from about 45 degrees to about 75 degrees, the melter vessel comprising a feed opening in the feed end wall or ceiling and the exit end wall comprising a melter exit structure for discharging molten material formed in the melting zone, the melter vessel comprising at least one fluid-cooled refractory panel in its floor, ceiling, and/or wall, and one or more submerged combustion burners, at least one of which is positioned to direct combustion products substantially perpendicularly into the melting zone under a level of molten material in the melting zone and form a turbulent molten material having a turbulent molten material surface facing the ceiling, the at least one fluid-cooled refractory panel configured to be modified during operation of the melter vessel to have a frozen or highly viscous material layer, or combination thereof, formed on at least a portion of a surface of the panel facing the molten material,

the melter vessel further comprising two or more sensors for sensing two or more temperatures selected from the group consisting of;

a) temperature of the turbulent molten material surface facing the ceiling,

b) inlet and outlet temperatures of a coolant fluid passing through the modified panel,

c) melter exhaust temperature,

d) temperature of the molten material flowing non-turbulently in a forehearth fluidly connected to the melter exit structure,

e) temperature of the molten material discharging non-turbulently out of the melter exit structure, and

f) combinations or two or more of (a)-(e);

with the proviso that two of the two or more sensors for sensing the two or more temperatures are two or more optical temperature measuring devices configured to sense the temperature (a) at two different locations; and

a controller configured to control the melter vessel using the two or more temperatures to achieve a desired melt temperature of at least a portion of the turbulent molten material in the melting zone.

9. The system of claim 8 wherein the fluid-cooled refractory skimmer is configured to form a frozen or highly viscous material layer, or combination thereof, on outer surfaces thereof contacting the molten material, the fluid-cooled refractory skimmer extending downward from the ceiling of the melter vessel and positioned upstream of the melter exit structure, the fluid-cooled refractory skimmer including at least one thermocouple positioned in the refractory or in the frozen or highly viscous material layer of the skimmer.

10. The system of claim 8 wherein the melter exit structure comprises a fluid-cooled refractory panel configured to form a frozen or highly viscous material layer, or combination thereof, on an inner surface thereof facing the molten material, the melter exit structure including at least one thermocouple positioned in the refractory or in the frozen or highly viscous material layer of the melter exit structure.

11. The system of claim 8 wherein the controller comprises a model predictive control strategy, a fuzzy control strategy, a neural network, and combinations thereof.