Apparatus and method for sampling of confined spaces

• US 10,090,142 B2
• Filed: 04/24/2017
• Issued: 10/02/2018
• Est. Priority Date: 05/08/2009
• Status: Active Grant

• Current Assignee: Bruker Scientific LLC (Bruker Corporation)
• Original Assignee: IonSense, Inc. (Bruker Corporation)
• Inventors: Musselman, Brian D
• Primary Examiner(s): Souw, Bernard
• Application Number:
  US15/495,246
• Publication Number:
  US 20170229299A1
• Time in Patent Office: 526 Days
• Field of Search: 250281, 250282, 250288, 250423 R, 250423, 250429, 25044211, 73 232, 73 2322, 73 2325, 73 2337, 422244, 422280, 422906, 324459, 324464, 324465
• CPC Class Codes: G01N 1/2214 by sorption
• CPC Class Codes: G01N 1/2226 Sampling from a closed space, e.g. food package, head space
• CPC Class Codes: G01N 1/2273 Atmospheric sampling
• CPC Class Codes: G01N 2001/022 sampling for security purposes, e.g. contraband, warfare agents
• CPC Class Codes: G01N 27/62 by investigating the ionisation of gases, e.g. aerosols; by investigating electric discharges, e.g. emission of cathode
• CPC Class Codes: H01J 49/0027 Methods for using particle spectrometers
• CPC Class Codes: H01J 49/0409 Sample holders or containers containers for retaining a material to be analyzed, B01L3/50, for DNA, C12Q1/6834, for biological materials, G01N33/543
• CPC Class Codes: H01J 49/10 Ion sources; Ion guns

Abstract

In various embodiments of the invention, a cargo container can be monitored at appropriate time intervals to determine that no controlled substances have been shipped with the cargo in the container. The monitoring utilizes reactive species produced from an atmospheric analyzer to ionize analyte molecules present in the container which are then analyzed by an appropriate spectroscopy system. In an embodiment of the invention, a sorbent surface can be used to absorb, adsorb or condense analyte molecules within the container whereafter the sorbent surface can be interrogated with the reactive species to generate analyte species characteristic of the contents of the container.

Claims

1. A cargo monitoring system comprising:

(a) receiving a container with an atmosphere, where the container is adapted to detachably attach an atmospheric ionization sorbent module (AISM) including a sorbent material;

(b) attaching the AISM to the container;

(c) directing a flow of the atmosphere onto the AISM to transfer one or more analyte molecules in the atmosphere to the sorbent material;

(d) directing ionizing species from an atmospheric ionizer at the sorbent material to generate one or more analyte ions; and

(e) analyzing the one or more analyte ions with a spectrometer.

2. The cargo monitoring system of claim 1, where the one or more analyte molecules can be absorbed, adsorbed or condensed on the sorbent material.

3. The cargo monitoring system of claim 1, where movement of the atmosphere within the container to the sorbent material is facilitated.

4. The cargo monitoring system of claim 1, where the atmosphere is directed to the sorbent material over an interval of time.

5. The cargo monitoring system of claim 1, where the sorbent material is subjected to analysis in situ.

6. The cargo monitoring system of claim 1, where the sorbent material is subjected to analysis after detaching the AISM from the container.

7. The cargo monitoring system of claim 1, further comprising detaching the AISM from the container prior to step (d).

8. The cargo monitoring system of claim 1, further comprising transferring the one or more analyte ions to the spectrometer for analysis in step (e).

9. The cargo monitoring system of claim 1, where the ionizing species are directed towards a surface of the sorbent material to generate the one or more analyte ions.

10. The cargo monitoring system of claim 9, where the one or more analyte ions are transferred from the surface to the spectrometer for analysis.

11. A method of identifying one or more controlled substances in a shipping container, comprising:

(a) receiving a shipping container with an atmosphere;

(b) attaching an atmospheric ionization sorbent module (AISM) with a sorbent surface to the shipping container;

(c) directing a flow of the atmosphere onto the AISM to transfer one or more analyte molecules in the atmosphere to the sorbent surface;

(d) detaching the AISM from the shipping container;

(e) directing ionizing species from an atmospheric ionizer at the sorbent surface to generate one or more analyte ions; and

(f) analyzing the one or more analyte ions with a spectrometer to determine if one or more controlled substances are present in the shipping container.

12. The method of claim 11, where the one or more analyte molecules can be absorbed, adsorbed or condensed on the sorbent surface.

13. The method of claim 11, where movement of the atmosphere within the shipping container to the sorbent surface is facilitated.

14. The method of claim 11, where the atmosphere is directed to the sorbent surface over an interval of time.

15. An atmospheric ionization sorbent module (AISM) comprising:

(a) a housing with a proximal end and a distal end;

(b) a tube with an inlet and an outlet positioned at the distal end;

(c) a connector for attaching the inlet to a connecting pathway on a cargo container;

(d) a sorbent material positioned in proximity to the outlet at the distal end;

(e) a fan for recirculating air from one or more regions within the cargo container through the connecting pathway to the inlet to transfer one or more analyte molecules through the outlet to the sorbent material; and

(f) means for releasing the connector to detach the AISM from the cargo container for analysis of the one or more analyte molecules transferred to the sorbent material.

16. The AISM of claim 15, where the sorbent material is segmented into distinct regions.

17. The AISM of claim 15, further comprising a chemical code impregnated onto the sorbent material.

18. The AISM of claim 15, further comprising a temperature controller to control the temperature of the sorbent material.

19. The AISM of claim 15, further comprising:

an entry port for a carrier gas, a power supply that supplies a potential difference between an electrode and a counter electrode to produce an electrical discharge which creates reactive species which subsequently pass and traverse through the length of the housing directed onto the sorbent material.

20. The AISM of claim 19, further comprising a gas ion separator to analyze species formed by the reactive species directed onto the sorbent material.