Wetting agents for aseptic filling

• US 10,091,988 B2
• Filed: 12/07/2017
• Issued: 10/09/2018
• Est. Priority Date: 05/28/2009
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: Man, Victor Fuk-Pong, Kieffer, Janel M., Denoma, Michael C., Killeen, Yvonne M., Magnuson, Joshua P.
• Primary Examiner(s): Richter, Johann R
• Assistant Examiner(s): Alley, Genevieve S
• Application Number:
  US15/834,370
• Publication Number:
  US 20180092351A1
• Time in Patent Office: 306 Days
• CPC Class Codes: A01N 25/02 containing liquids as carriers, diluents or solvents
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 37/02 Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
• CPC Class Codes: A01N 37/16 containing the group; Thio analogues thereof
• CPC Class Codes: A01N 59/00 Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
• CPC Class Codes: B65B 55/10 by liquids or gases
• CPC Class Codes: C11D 1/008 Polymeric surface-active agents
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/8255 containing a combination of compounds differently alcoxylised or with differently alkylated chains
• CPC Class Codes: C11D 3/2068 Ethers
• CPC Class Codes: C11D 3/3707 Polyethers, e.g. polyalkyleneoxides
• CPC Class Codes: C11D 3/48 Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

Abstract

The present invention is directed to wetting agent compositions and methods for making and using the wetting agent compositions. The compositions of the invention include a sheeting agent, a defoaming agent, and an association disruption agent. The wetting agent compositions of the present invention result in a faster draining/drying time on most substrates compared to conventional wetting agents. The wetting agent compositions of the present invention are especially suitable for use on plastic substrates.

Claims

1. A method for aseptic packaging of food, beverages or pharmaceuticals comprising:

(a) contacting a package with a composition consisting essentially of a wetting agent, and an antimicrobial agent, wherein the wetting agent comprises;

(i) a sheeting agent, wherein the sheeting agent comprises at least one compound having the structure represented by formula I;

R—

O—

(CH₂CH₂O)_n—

H

wherein R is a (C₁-C₁₂) alkyl group, and n is an integer in the range of 1 to 100;

(ii) a defoaming agent comprising a polyoxypropylene-polyoxyethylene block copolymer surfactant;

(iii) an association disruption agent of an alcohol alkoxylate EO/BO surfactant and/or a C₁₂-C₁₄ fatty alcohol EO/PO surfactant; and

(iv) an additional ingredient selected from the group consisting of a carrier, a hydrotrope, a chelating/sequestering agent, and combinations thereof;

(b) filling the package with a substance selected from the group consisting of food, beverage, pharmaceutical, and combinations thereof; and

(c) sealing the package.

2. The method of claim 1, wherein n is an integer in the range of 10 to 50.

3. The method of claim 1, wherein n is an integer in the range of 15 to 30.

4. The method of claim 1, wherein n is 21.

5. The method of claim 1, wherein the sheeting agent is present at about 1 wt. % to about 10 wt. %.

6. The method of claim 1, wherein the sheeting agent is present at about 2 wt. % to about 5 wt. %.

7. The method of claim 1, wherein the defoaming agent is present at about 1 wt. % to about 10 wt. %.

8. The method of claim 1, wherein the defoaming agent is present at about 2 wt. % to about 5 wt. %.

9. The method of claim 1, wherein the ratio of sheeting agent to defoaming agent to association disruption agent is about 1.0:

1.5;

30 to about 1;

2;

1.

10. The method of claim 1, wherein the association disruption agent is present in an amount effective to reduce the contact angle of the composition by between about 5°

to about 15°

.

11. The method of claim 1, wherein the additional ingredient comprises at least about 50 wt. % of a carrier.

12. The method of claim 11, wherein the carrier comprises water.

13. A method for aseptic packaging comprising:

(a) forming an aseptic packaging use solution comprising diluting a composition, wherein the composition consists essentially of;

(i) a wetting agent consisting essentially of;

(a) a sheeting agent, wherein the sheeting agent comprises at least one compound having the structure represented by formula I;

R—

O—

(CH₂CH₂O)_n—

H

 

wherein R is a (C₁-C₁₂) alkyl group, and n is an integer in the range of 1 to 100;

(b) a defoaming agent comprising a polyoxypropylene-polyoxyethylene block copolymer surfactant,

(c) an association disruption agent of an alcohol alkoxylate ethylene oxide surfactant, alcohol alkoxylate butylene oxide surfactant, alcohol alkoxylate propylene oxide surfactant, C₁₂-C₁₄ fatty alcohol ethylene oxide surfactant or C₁₂-C₁₄ fatty alcohol propylene oxide surfactant;

(ii) and an antimicrobial agent;

(b) contacting a package with the aseptic packaging use solution;

(c) filling the package with a substance selected from the group consisting of food, beverage, pharmaceutical, and combinations thereof; and

(d) sealing the package.

14. The method of claim 13, wherein the package comprises a hard surface and/or a soft surface.

15. The method of claim 13, wherein the package dries within about 30 seconds to about 4.5 minutes after the aseptic packaging use solution is applied to the package.