Process for production of acrylic acid

• US 10,099,988 B2
• Filed: 02/12/2016
• Issued: 10/16/2018
• Est. Priority Date: 02/13/2015
• Status: Active Grant

• Current Assignee: Novomer, Inc (Danimer Scientific, Inc.)
• Original Assignee: Novomer, Inc (Danimer Scientific, Inc.)
• Inventors: Farmer, Jay J., Galebach, Peter, Sherry, Kyle, Sookraj, Sadesh H.
• Primary Examiner(s): Valenrod, Yevgeny
• Assistant Examiner(s): Doletski, Blaine G
• Application Number:
  US15/550,193
• Publication Number:
  US 20180016219A1
• Time in Patent Office: 977 Days
• CPC Class Codes: C07C 51/09 from carboxylic acid esters or lactones
• CPC Class Codes: C07C 57/04 Acrylic acid; Methacrylic acid
• CPC Class Codes: Y02P 20/10 Process efficiency

Abstract

Provided are integrated processes for the conversion of beta propiolactone to acrylic acid. Systems for the production of acrylic acid are also provided.

Claims

1. A method for producing acrylic acid, comprising:

(a) providing a feedstock stream comprising beta propiolactone;

(b) directing the feedstock stream to a reaction zone;

(c) contacting the feedstock stream with a polymerization catalyst in the reaction zone;

(d) polymerizing at least a portion of the beta propiolactone to poly(propiolactone) in the reaction zone, wherein the temperature of the reaction zone is at or above the pyrolysis temperature of poly(propiolactone);

(e) thermally decomposing the poly(propiolactone) in the reaction zone to produce acrylic acid; and

(f) withdrawing an acrylic acid product stream comprising the acrylic acid from the reaction zone;

wherein steps (b) and (e) occur in the same reaction zone.

2. The method of claim 1, further comprising directing a return loop comprising a portion of the acrylic acid product stream to the reaction zone.

3. The method of claim 2, wherein the return loop of acrylic acid is combined with the feedstock stream.

4. The method of claim 1, wherein the polymerization catalyst is a salt of a compound of formula:

5. The method of claim 1, wherein the polymerization catalyst is a salt of a compound of formula:

6. The method of claim 1, wherein the polymerization catalyst is heterogeneous.

7. The method of claim 1, wherein after removal of all acrylic acid product stream, the polymerization catalyst remains as a salt or melt.

8. The method of claim 7, further comprising recycling the salt or melt to the reaction zone.

9. The method of claim 1, wherein the feedstock stream contains or is combined with a high boiling solvent.

10. The method of claim 9, further comprising withdrawing a recycling stream of the polymerization catalyst from the reaction zone.

11. The method of claim 1, further comprising directing a return loop of a portion of the acrylic acid product stream to the reaction zone.

12. The method of claim 1, wherein the feedstock stream is neat.