Recovery of additive manufacturing support materials

• US 10,100,168 B2
• Filed: 01/09/2015
• Issued: 10/16/2018
• Est. Priority Date: 01/16/2014
• Status: Active Grant

• Current Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Original Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Inventors: Bayer, Roland, Matteucci, Scott T., Pyzik, Aleksander J., Allen, Sharon, Leugers, Mary Anne, Dermody, Daniel L., Moglia, Robert S.
• Primary Examiner(s): Slifka, Colin W.
• Application Number:
  US15/108,921
• Publication Number:
  US 20160333165A1
• Time in Patent Office: 1,376 Days
• CPC Class Codes: B29C 64/135 the energy source being concentrated, e.g. scanning lasers or focused light sources
• CPC Class Codes: B29C 64/35 Cleaning
• CPC Class Codes: B29C 64/357 Recycling
• CPC Class Codes: B29C 64/40 Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
• CPC Class Codes: B33Y 40/00 Auxiliary operations or equipment, e.g. for material handling
• CPC Class Codes: B33Y 40/20 Post-treatment, e.g. curing, coating or polishing
• CPC Class Codes: B33Y 70/00 Materials specially adapted for additive manufacturing
• CPC Class Codes: C08J 11/08 using selective solvents for polymer components
• CPC Class Codes: C08J 2301/26 Cellulose ethers
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling

Abstract

The inventions is directed to a method for recovering support materials used in an additive manufacturing process. The method comprises exposing a precursor additive manufactured article comprised of a water soluble support polymer and an insoluble material to water. The water soluble support polymer is dissolved in the water. The remaining article is then removed from the water. The dissolved water soluble polymer is precipitated from the water. The precipitated polymer is separated from the water and any remaining water removed to recover the water soluble support polymer. The recovered water soluble support polymer may then be re-used to make further additive manufactured articles.

Claims

1. A method for recovering support materials used in an additive manufacturing process, the method comprising,

(i) providing a precursor fused filament fabrication additive manufactured article comprised of a water soluble support polymer and an insoluble material,

(ii) exposing the precursor additive manufactured article to water such that the water soluble support polymer is dissolved in the water to form (a) an aqueous solution of the water soluble support polymer and water and (b) a finished additive manufactured article,

(iii) removing the final additive manufactured article from the aqueous solution,

(iv) precipitating the water soluble support polymer from the aqueous solution to form a precipitate of the water soluble support polymer,

(v) separating the precipitate from the water, and

(vi) removing any water remaining from the precipitate of the water soluble support polymer,

wherein the water soluble support polymer is a hydroxypropyl cellulose (HPC), a hydroxypropyl methylcellulose (HPMC), hydroxyethyl methylcellulose (HEMC) or combination thereof.

2. The method of claim 1, wherein the precipitating is carried out by changing the pH, adding a salt, changing the temperature of the aqueous solution or combination thereof.

3. The method of claim 1, wherein the water soluble support polymer is the hydroxypropyl methylcellulose.

4. The method of claim 3, wherein hydroxypropyl methylcellulose has a degree of substitution of methoxyl groups of at least 1.0 and a molar substitution of hydroxypropoxyl groups of at least 0.6.

5. The method of claim 4, the hydroxypropyl methylcellulose has no further constituents.

6. The method of claim 4 wherein the precipitating comprises adding a salt to the aqueous solution.

7. The method of claim 6, wherein at least a portion of the salt is re-used for precipitating without removing it from the aqueous solution.

8. The method of claim 4, wherein the hydroxypropyl methylcellulose is dissolved in water that is at or near a neutral pH.

9. The method of claim 8, wherein the hydroxypropyl methylcellulose is dissolved in water having a temperature at or near ambient temperature.

10. The method of claim 1, wherein the water soluble support polymer has no further constituents.

11. The method of claim 1, wherein the water soluble support polymer is further comprised of a filler.

12. The method of claim 11, wherein said filler and precipitate are simultaneously separated and compounded after drying to reform the water soluble support polymer comprised of the filler.

13. The method of claim 11, wherein said filler and precipitate are separated and any remaining water removed individually and then compounded together to reform the water soluble support polymer comprised of the filler.

14. The method of claim 11, wherein the filler is an insoluble filler.

15. The method of claim 1, wherein the precipitating is carried out by changing the temperature, changing the pH or combination thereof of the aqueous solution.

16. The method of claim 15, wherein the precipitating is carried out by changing the temperature of the aqueous solution.

17. The method of claim 16, wherein the water soluble support polymer is the hydroxypropyl methylcellulose.