Method, apparatus and chemical products for treating petroleum equipment

• US 10,106,752 B2
• Filed: 04/29/2016
• Issued: 10/23/2018
• Est. Priority Date: 04/16/2012
• Status: Active Grant

• Current Assignee: Marcello Ferrara
• Original Assignee: Marcello Ferrara
• Inventors: Ferrara, Marcello
• Primary Examiner(s): McCaig, Brian A
• Application Number:
  US15/141,871
• Publication Number:
  US 20170037327A1
• Time in Patent Office: 907 Days
• CPC Class Codes: C10G 2300/4075 Limiting deterioration of equipment
• CPC Class Codes: C10G 45/02 to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
• CPC Class Codes: C10G 7/00 Distillation of hydrocarbon oils
• CPC Class Codes: C10G 75/04 by addition of antifouling agents
• CPC Class Codes: C10G 9/005 Coking (in order to produce liquid products mainly)
• CPC Class Codes: C10G 9/007 Visbreaking
• CPC Class Codes: C10G 9/16 Preventing or removing incrustation
• CPC Class Codes: F24D 17/0021 with accumulation of the heated water
• CPC Class Codes: F24D 17/0031 with accumulation of the heated water
• CPC Class Codes: F24D 17/02 using heat pumps
• CPC Class Codes: Y10T 29/49 Method of mechanical manufacture

Abstract

The present invention provides a method, an apparatus and chemical products for treating petroleum equipment wherein a fluid is flowing, preferably of the hydrocarbon type, and wherein treating is performed by establishing a closed or semi-closed flow circulation loop, during the normal production operations of the equipment. The treatment can refer to the cleaning of equipment, to yield improvement as compared to normal run conditions and/or to a reduction of coke formation and/or to coke removal on catalysts.

Claims

1. A method for treating a petroleum plant or equipment of the petroleum plant during a running of the petroleum plant, comprising:

maintaining, during a treatment period, the petroleum plant under a production operating condition, typical of the petroleum plant itself, which includes providing fresh feed to the petroleum plant;

while maintaining the petroleum plant under the production operating condition, there is carried out one or both of a) and b);

a) introducing in the petroleum plant, during the treatment period, a hydrocarbon-based treatment fluid;

b) varying an established feed rate, present at initiation of the treatment of the petroleum plant or equipment of the petroleum plant, which established feed rate ranges from a maximum operation rate for the petroleum plant, which is at or above a design feed rate for the petroleum plant, to a minimum operation rate which is set at a level for satisfying a minimum production operating state in the petroleum plant;

wherein said introduction of a hydrocarbon-based treatment fluid and/or said variation to the established feed rate generates an additional source or sources for distillation with respect to the amount provided by the established feed rate;

distilling said additional source or sources for distillation for the purpose of plant treatment; and

introducing a distillate into at least one of the fresh feed and a residue, the introduced distillate being an output of the petroleum plant that is pre-established as resulting during a non-treatment, normal operation state of the petroleum plant.

2. The method of claim 1 wherein the additional source or sources of distillate generated by the variation to the established feed rate is fed into the current fresh feed of the petroleum plant as the hydrocarbon-based treatment fluid in “

a)”

or as a supplement to an alternate hydrocarbon-based treatment fluid “

a)”

.

3. The method of claim 1 wherein varying the established feed rate includes an adjustment of the established feed rate in association with an introduction of the hydrocarbon-based treatment fluid at least partly derived from an external source and wherein said externally derived hydrocarbon-based treatment fluid is introduced into a closed or semi-closed loop at least partly formed by said petroleum plant.

4. The method of claim 1 wherein varying the established feed rate includes an increase adjustment from said established feed rate to a level above the established feed rate as to generate an additional quantity of distillates relative to a quantity generated at the established feed rate, and drawing off at least some of an overall quantity of distillate generated from the increased feed rate and introducing the drawn off distillate into a treatment region of said petroleum plant.

5. The method of claim 4 further comprising passing said drawn off distillate through a closed or semi-closed loop forming at least a portion of said petroleum plant and extending through the treatment region.

6. The method of claim 4 further comprising introducing the drawn off distillate to one or more fresh feed passageways of the petroleum plant and a coordinated lowering of a then current fresh feed rate to the petroleum plant such that the lowered fresh feed rate plus the additional drawn off distillate is summed together to a desired treatment feed rate and wherein a controller is configured as to monitor and adjust the fresh feed rate to the petroleum plant, based on an input level of the drawn off distillate being received in said one or more fresh feed passageways, a current fresh feed to the petroleum plant, and a set desired treatment feed rate in the petroleum plant.

7. The method of claim 4 wherein the drawn off distillate is introduced into a fresh feed passageway of the petroleum plant and wherein introduction of the hydrocarbon-based treatment fluid includes introduction of a first and/or second hydrocarbon-based treatment fluid, and varying the established feed rate is carried out by an introduction of the first and/or second hydrocarbon-based treatment fluids, with the introduction of first and/or second hydrocarbon-based treatment fluids including both the drawn off distillate plus an external source of said first and/or second hydrocarbon-based treatment fluids placed into combination with the drawn off distillate so as to establish a desired treatment feed rate.

8. The method of claim 4 further comprising introducing steam as a medium for passage with the hydrocarbon-based treatment fluid being directed at the petroleum plant or equipment of said petroleum plant to be treated.

9. The method of claim 1 further comprising passing one or more distillates and/or products of the petroleum plant from a non-treatment, normal plant operation mode passage route to a treatment mode passage route by feeding at least a portion of the one or more distillates and/or products into a closed or semi-closed circulation loop at least partially passing inside the petroleum plant and that passes the one or more distillates and/or products to a different location in the petroleum plant than when directed in the non-treatment mode.

10. The method of claim 9 wherein there is circulated in the closed or semi-closed loop one or both of a first hydrocarbon-based fluid and a second hydrocarbon-based fluid inside equipment to be treated as part of the introduction of hydrocarbon-based treatment fluid in the petroleum plant, such that a portion of distillate products during said circulation are re-introduced in said closed or semi-closed loop, whereas another portion of distillate products during said circulation makes up the petroleum plant production and/or the normal distillate flow stream.

11. The method of claim 1 wherein varying the established feed rate includes, a reduction in the established feed rate of the petroleum plant to a value greater than or equal to 40% and below 100% with respect to the design feed rate, followed by the introduction of the hydrocarbon-based treatment fluid which comprises an introduction of first and/or the second hydrocarbon-based treatment fluid(s) in an amount as to compensate up to the difference between the rate at which the petroleum plant is running and the design feed rate, while also not exceeding the maximum allowable plant distillate flow rate, such as to run the petroleum plant at a resulting flow rate that is equal to the sum:

[flow rate of reduced fresh feed]+[flow rate of the first and/or the second hydrocarbon-based treatment fluid(s)], and wherein said, resulting flow rate is equal to or higher to the flow rate prior to the reduction of the established feed rate.

12. The method of claim 1 wherein the introduction of the hydrocarbon-based treatment fluid includes the introduction of one or both of a first hydrocarbon-based treatment fluid and a second hydrocarbon-based treatment fluid that is or are capable of solubilizing the deposits in said petroleum plant or equipment of said petroleum plant to be treated essentially under near critical or supercritical operating conditions of the petroleum plant.

13. A method for treating a petroleum plant or equipment of the petroleum plant during a running of the petroleum plant, comprising:

maintaining, during a treatment period, the petroleum plant under a production operating condition, typical of the petroleum plant itself, which includes providing fresh feed to the petroleum plant;

while maintaining the petroleum plant under the production operating condition, there is carried out one or both of a) and b);

a) introducing in the petroleum plant, during the treatment period, a hydrocarbon-based treatment fluid;

b) varying an established feed rate, present at initiation of the treatment of the petroleum plant or equipment of the petroleum plant, which established feed rate ranges from a maximum operation rate for the petroleum plant, which is at or above a design feed rate for the petroleum plant, to a minimum operation rate which is set at a level for satisfying a minimum production operating state in the petroleum plant;

wherein said introduction of a hydrocarbon-based treatment fluid and/or said variation to the established feed rate generates an additional source or sources for distillation with respect to the amount provided by the established feed rate

distilling said additional source or sources for distillation for the purpose of plant treatment; and

running the petroleum plant so as to increase an amount of distillates produce, circulating the increased amount of distillates in parts of the petroleum plant or equipment of the petroleum plant to be treated, and progressively reducing a pre-existing fresh feed rate.

14. A method for treating a petroleum plant or equipment of the petroleum plant during a running of the petroleum plant, comprising:

maintaining, during a treatment period, the petroleum plant under a production operating condition, typical of petroleum plant itself, which includes providing fresh feed to the petroleum plant;

implementing a closed or semi-closed circulation loop inside said petroleum plant or equipment of the petroleum plant, wherein one or more distillates and/or products exiting the petroleum plant are withdrawn and re-introduced inside the petroleum plant or equipment of the petroleum plant to be treated upstream of the withdrawal point;

while maintaining the petroleum plant under the production operating condition, there is carried out one or both of a) and b);

a) introducing in the petroleum plant, during the treatment period, a hydrocarbon-based treatment fluid;

b) varying an established feed rate, present at initiation of the treatment of the petroleum plant or equipment of the petroleum plant, which established feed rate ranges from a maximum operation rate for the petroleum plant, which is at or above a design feed rate for the petroleum plant, to a minimum operation rate which is set at a level for satisfying a minimum production operating state in the petroleum plant;

wherein said introduction of a hydrocarbon-based treatment fluid and/or said variation to the established feed rate generates an additional source or sources for distillation with respect to the amount provided by the established feed rate;

distilling said additional source or sources for distillation and re-introducing in said closed or semi-closed loop a portion of the distillates for treating the petroleum plant or equipment of the petroleum plant; and

introducing a distillate into a least one of the fresh feed and a residue, the introduced distillate being an output of the petroleum plant that is pre-established as resulting during a non-treatment, normal operation state of the petroleum plant.

15. The method of claim 14 wherein introduction of the hydrocarbon-based treatment fluid includes introduction of a first and/or second hydrocarbon-based treatment fluid, and varying the established feed rate is carried out by an introduction of the first and/or second hydrocarbon-based treatment fluids, with the introduction of first and/or second hydrocarbon-based treatment fluids including both the withdrawn distillate plus an external source of said first and/or second hydrocarbon-based treatment fluids placed into combination with the withdrawn distillate so as to establish a desired treatment feed rate.

16. A method for treating a petroleum plant or equipment of the petroleum plant during a running of the petroleum plant, comprising:

maintaining, during a treatment period, the petroleum plant under a production operating condition, typical of the petroleum plant itself, which includes providing fresh feed to the petroleum plant;

while maintaining the petroleum plant under the production operating condition, there is carried out one or both of a) and b);

a) introducing in the petroleum plant, during the treatment period, a hydrocarbon-based treatment fluid;

b) varying an established feed rate, present at initiation of the treatment of the petroleum plant or equipment of the petroleum plant, which established feed rate ranges from a maximum operation rate for the petroleum plant, which is at or above a design feed rate for the petroleum plant, to a minimum operation rate which is set at a level for satisfying a minimum production operating state in the petroleum plant;

wherein said introduction of a hydrocarbon-based treatment fluid and/or said variation to the established feed rate generates an additional source or sources for distillation with respect to the amount provided by the established feed rate;

distilling said additional sources or sources for distillation for the purpose of plant treatment; and

returning distillate, represented by the distillated additional source or sources for distillation, to a plant treatment area together with residue flowing together with the distillate, and with the combined residue and distillate coming into initial contact with fresh feed used in the production operating condition of the petroleum plant.