Method for curing and surface-functionalizing molded parts

• US 10,113,042 B2
• Filed: 02/04/2010
• Issued: 10/30/2018
• Est. Priority Date: 02/25/2009
• Status: Active Grant

• Current Assignee: Leibniz-Institut für Polymerforschung Dresden
• Original Assignee: Leibniz-Institut für Polymerforschung Dresden
• Inventors: Gedan-Smolka, Michaela, Gohs, Uwe, Mueller, Anett
• Primary Examiner(s): Padgett, Marianne L
• Application Number:
  US13/203,092
• Publication Number:
  US 20110311733A1
• Time in Patent Office: 3,190 Days
• Field of Search: 264 136, 264 27, 264402, 264446, 264470, 264471, 264473, 264477, 264485, 264488, 264496, 264405, 264424, 264425, 264494, 264239, 427491, 427492, 427493, 427496, 427500, 427501, 427508, 427513, 427514, 427133
• CPC Class Codes: C08J 7/04 Coating
• CPC Class Codes: C08J 7/08 Heat treatment
• CPC Class Codes: C08J 7/123 Treatment by wave energy or particle radiation C08J7/18 takes precedence
• CPC Class Codes: C08J 7/18 using wave energy or particle radiation

Abstract

A method for curing and surface functionalization of molded parts, including processing materials that contain at least one unsaturated radically or cationically curable reactive resin system and further substances to form a molded part and cross-linking the materials up to dimensional stability during or after the processing. The method additionally includes subjecting the molded part to energetic radiation or energetic particles at least one of during the cross-linking and subsequent to the cross-linking to essentially complete curing at least of a surface region of the molded part to produce an essentially completely coatable molded part surface.

Claims

1. A method for curing and surface functionalization to produce surface-functionalized molded parts, comprising:

processing at least one material of

a fiber reinforced polymer material,

a sheet molding compound (SMC),

a bulk molding compound (BMC), and

a fiber-polymer-matrix part to form a molded part;

wherein the material is an unsaturated radically curable reactive resin system and further substances; and

during or after the processing of the at least one material to form the molded part,

partially curing the material of the molded part to dimensional stability by cross-linking, which is thermally initiated, to form a partially-cured molded part; and

then

subjecting the partially-cured molded part to energetic electrons in an oxygen-containing atmosphere and with a dose application in at least two treatments to essentially completely cure at least a surface region of the partially-cured molded part, to generate oxygen-containing functional groups from the atmosphere on the surface and/or in regions close to the surface of the partially-cured molded part, and to increase hydrophilicity of the surface of the partially-cured molded part, thereby producing a surface-functionalized molded part;

wherein,

after subjecting the partially-cured molded part to the energetic electrons in the oxygen-containing atmosphere to form the surface-functionalized molded part, gas emission from the surface of the surface-functionalized molded part, of any residual monomers, residual oligomers, or residual reactive thinning agents that remain, is virtually completely prevented, and

no residual reactivity is detectable in the surface-functionalized molded part surface via differential scanning calorimetry (DSC) measurements.

2. The method of claim 1, further comprising coating the molded part such that the molded part has a coating layer during the cross-linking.

3. The method of claim 1, wherein the molded part does not include a coating layer during the cross-linking.

4. The method of claim 1, wherein the fiber reinforced polymer material is processed to form the molded part.

5. The method of claim 4, wherein the fiber reinforced polymer material comprises one of:

unsaturated polyester resins;

acrylic resins; and

epoxy resins with a cationic initiator.

6. The method of claim 5, wherein the fiber reinforced polymer material comprises an acrylic resin, which comprises at least one of acrylates and methacrylates.

7. The method of claim 1, wherein the further substances comprise at least one of additives, fillers, reinforcing elements, further polymers, and reactive thinning agents.

8. The method of claim 1, wherein the sheet molding compound (SMC) or the bulk molding compound (BMC) is processed to form the molded part.

9. The method of claim 1, wherein processing at least one of the fiber reinforced polymer material, the sheet molding compound (SMC), the bulk molding compound (BMC), and the fiber polymer matrix part to form the molded part comprises a hot pressing.

10. The method of claim 1, wherein the oxygen-containing atmosphere is air.

11. The method of claim 1, wherein the subjecting the partially-cured molded part to the energetic electrons is carried out in combination with a plasma treatment.

12. The method of claim 1, wherein the subjecting the partially-cured molded part to the energetic electrons is carried out with doses in the range of 10 kGy to 250 kGy.

13. The method of claim 1, wherein the dose application is carried out with the same dose per treatment step.

14. The method of claim 1, wherein the dose application is carried out with a different dose per treatment step.

15. The method of claim 1, wherein the fiber-polymer-matrix part is processed to form the molded part.

16. The method of claim 1, further comprising applying a coating of paint to the surface-functionalized molded part.

17. The method of claim 1, further comprising applying a coating to the molded part at least one of prior to or subsequent to subjecting the partially-cured molded part to the energetic electrons.

18. The method of claim 17, wherein the coating is applied prior to subjecting the partially-cured molded part to the energetic electrons.

19. The method of claim 17, wherein the coating is applied subsequent to subjecting the partially-cured molded part to the energetic electrons.