Liquid toner containing a low symmetry electrically conducting material for printing conductive traces

• US 10,114,305 B2
• Filed: 09/26/2014
• Issued: 10/30/2018
• Est. Priority Date: 09/26/2014
• Status: Active Grant

• Current Assignee: HP Indigo B.V. (HP Inc.)
• Original Assignee: HP Indigo B.V. (HP Inc.)
• Inventors: Grinwald, Yaron, Avigdor, Reut, Katz, Gregory, Reznick, Yana, Shitrit, Mirit, Vinegrad, Adi
• Primary Examiner(s): Chea, Thorl
• Application Number:
  US15/502,909
• Publication Number:
  US 20170235245A1
• Time in Patent Office: 1,495 Days
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium
• CPC Class Codes: G03G 9/122 characterised by the colouring agents
• CPC Class Codes: G03G 9/125 characterised by the liquid
• CPC Class Codes: G03G 9/131 obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: G03G 9/135 characterised by stabiliser or charge-controlling agents
• CPC Class Codes: G03G 9/1355 Ionic, organic compounds

Abstract

A liquid toner for printing conductive traces is provided. The liquid toner includes a carrier liquid and toner particles dispersed in the carrier liquid. The toner particles include a low symmetry electrically conducting material dispersed in a pigment.

Claims

1. A liquid toner for printing conductive traces, including:

a carrier liquid; and

toner particles dispersed in the carrier liquid, the toner particles including an electrically conducting material and a dispersant embedded in a resin, the electrically conducting material having a shape of a flake, a fiber, or a tube.

2. The liquid toner of claim 1, wherein the electrically conducting material comprises a carbon-based material or a metal.

3. The liquid toner of claim 2, wherein the electrically conducting material is selected from the group consisting of carbon nanotubes, graphene, and the metal in the form of metallic flakes or nano-fibers.

4. The liquid toner of claim 3, wherein the electrically conducting material is the metal, and the metal is selected from the group consisting of aluminum, tin, a transition metal selected from the group consisting of zinc, copper, silver, gold, nickel, palladium, platinum, chromium, and iron, and an alloy selected from the group consisting of brass, bronze, and steel.

5. The liquid toner of claim 2, wherein the resin is selected from the group consisting of ethylene acid copolymers and ethylene vinyl acetate copolymers.

6. The liquid toner of claim 5, wherein the resin is selected from the group consisting of ethylene acrylic acid copolymers;

ethylene methacrylic acid copolymers;

ethylene vinyl acetate copolymers;

copolymers of ethylene and C₁ to C₅ alkyl esters of methacrylic or acrylic acid;

copolymers of ethylene, acrylic or methacrylic acid, and C₁ to C₅ alkyl esters of methacrylic or acrylic acid;

polyethylene;

polystyrene;

isotactic polypropylene;

ethylene ethyl acrylate;

polyesters;

polyvinyl toluene;

polyamides;

styrene/butadiene copolymers;

epoxy resins;

acrylic resins, including copolymers of acrylic or methacrylic acid and at least one C₁ to C₂₀ alkyl esters of acrylic or methacrylic acid;

ethylene-acrylate terpolymers;

ethylene-acrylic esters-maleic anhydride or glycidyl methacrylate (GMA) terpolymers;

ethylene-acrylic acid ionomers, and combinations thereof.

7. The liquid toner of claim 1, wherein the carrier liquid is a non-polar liquid selected from the group consisting of paraffinic liquids, mineral spirits, petroleum distillates, and aromatic solvents.

8. The liquid toner of claim 1, further including an other dispersant, a charge director, or both.

9. The liquid toner of claim 8, wherein the other dispersant is selected from the group consisting of anionic surfactants, cationic surfactants, amphoteric surfactants, non-ionic surfactants, polymeric surfactants, oligomeric surfactants, crosslinking surfactants, and combinations thereof and wherein the charge director is a sulfosuccinate salt of a general formula MAn, wherein M is a metal, n is a valence of M, and A is an ion of the general formula (IV):

[R¹—

O—

C(O)CH₂CH(SO₃)C(O)—

O—

R²]⁻

 

 

Formula (IV)

wherein each of R¹ and R² is an alkyl group.

10. The liquid toner of claim 1, wherein the dispersant is a surfactant of formula (I):

11. The liquid toner of claim 10, wherein the hydrocarbon tail group is of formula (II):

P-L- 

 

Formula (II)

wherein P is polyisobutylene and L is O, NH, or (CH₂)_n, wherein n is from 1 to 5.

12. The liquid toner of claim 10, wherein the amine-containing head group is of formula (III):

(CH₂)_m[(CH₂)_oNH(CH₂)_p]_q(CH₂)_r—

NH₂ 

 

Formula (III)

wherein m is from 1 to 5, o is 0, 1 or 2, p is 1 or 2, q is from 0 to 10, and r is from 0 to 10.

13. The liquid toner of claim 1, wherein the dispersant is a polyisobutylene succinamide.

14. The liquid toner of claim 1, wherein the electrically conducting material forms a conducting line in the resin.

15. A method of making a liquid toner for printing conductive traces, the method comprising:

coating a dispersant on an electrically conducting material, the electrically conducting material having a shape of a flake, a fiber, or a tube;

dispersing the dispersant coated electrically conducting material into a resin to form a mixture;

grinding the mixture to embed the dispersant coated electrically conducting material in the resin using mechanical force; and

adding the mixture to a carrier liquid to form the liquid toner.

16. The method of claim 15, wherein the electrically conducting material is selected from the group consisting of carbon nanotubes, graphene, and a metal in the form of metallic flakes or nano-fibers, wherein the metal is selected from the group consisting of aluminum, tin, a transition metal selected from the group consisting of zinc, copper, silver, gold, nickel, palladium, platinum, chromium, and iron, and an alloy selected from the group consisting of brass, bronze, and steel.

17. The method of claim 16, wherein the carbon nanotubes have a pigment loading of 30% or more in the liquid toner.

18. A method for printing conductive traces, the method comprising:

providing a liquid toner, the liquid toner including;

a carrier liquid, and

toner particles dispersed in the carrier liquid, the toner particles comprising an electrically conducting material and a dispersant embedded in a resin, the electrically conducting material having a shape of a flake, a fiber, or a tube; and

printing the liquid toner on a substrate one or more times to form the conductive traces.

19. The method of claim 18, wherein the electrically conducting material is selected from the group consisting of carbon nanotubes, graphene, and a metal in the form of metallic flakes or nano-fibers, wherein the metal is selected from the group consisting of aluminum, tin, a transition metal selected from the group consisting of zinc, copper, silver, gold, nickel, palladium, platinum, chromium, and iron, and an alloy selected from the group consisting of brass, bronze, and steel, and wherein the carrier liquid is a non-polar liquid selected from the group consisting of paraffinic liquids, mineral spirits, petroleum distillates, and aromatic solvents.