Additive infused biochar

• US 10,118,870 B2
• Filed: 12/28/2016
• Issued: 11/06/2018
• Est. Priority Date: 06/06/2011
• Status: Active Grant

• Current Assignee: Carbon Technology Holding LLC
• Original Assignee: Cool Planet Energy Systems, Inc.
• Inventors: Bontchev, Ranko Panayotov, Kim, Han Suk, Jarand, Mark L., Belcher, Richard Wilson, Cheiky, Michael C., Sills, Ronald A.
• Primary Examiner(s): Langel, Wayne A
• Application Number:
  US15/393,176
• Publication Number:
  US 20170210677A1
• Time in Patent Office: 678 Days
• CPC Class Codes: A01N 25/08 containing solids as carriers or diluents
• CPC Class Codes: C01B 32/05 Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
• CPC Class Codes: C05B 17/00 Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
• CPC Class Codes: C05B 17/02 containing manganese
• CPC Class Codes: C05C 1/00 Ammonium nitrate fertilisers
• CPC Class Codes: C05C 11/00 Other nitrogenous fertilisers
• CPC Class Codes: C05C 3/00 Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
• CPC Class Codes: C05C 5/00 Fertilisers containing other nitrates
• CPC Class Codes: C05C 5/04 containing calcium nitrate
• CPC Class Codes: C05C 9/00 Fertilisers containing urea or urea compounds
• CPC Class Codes: C05D 1/00 Fertilisers containing potassium C05D7/00 takes precedence
• CPC Class Codes: C05D 3/00 Calcareous fertilisers C05D7/00 takes precedence
• CPC Class Codes: C05D 9/00 Other inorganic fertilisers
• CPC Class Codes: C05D 9/02 containing trace elements
• CPC Class Codes: C05F 11/00 Other organic fertilisers
• CPC Class Codes: C05F 11/02 from peat, brown coal, and similar vegetable deposits
• CPC Class Codes: C05F 11/08 Organic fertilisers containing added bacterial cultures, mycelia or the like
• CPC Class Codes: C05G 3/00 Mixtures of one or more fertilisers with additives not having a specially fertilising activity
• CPC Class Codes: C05G 3/80 Soil conditioners
• CPC Class Codes: C05G 5/10 Solid or semi-solid fertilisers, e.g. powders layered or coated C05G5/30, incorporated into a matrix C05G5/40
• CPC Class Codes: C05G 5/20 : Liquid fertilisers layered or coated C05G5/30; incorporated into a matrix C05G5/40
• CPC Class Codes: C05G 5/23 : Solutions
• CPC Class Codes: C05G 5/27 : Dispersions, e.g. suspensions or emulsions
• CPC Class Codes: C05G 5/40 : Fertilisers incorporated into a matrix
• CPC Class Codes: C09K 17/02 : containing inorganic compounds only
• CPC Class Codes: C09K 17/04 : applied in a physical form other than a solution or a grout, e.g. as granules or gases
• CPC Class Codes: C10B 53/02 : of cellulose-containing material production of pyroligneous acid C10C5/00
• CPC Class Codes: C10B 57/02 : Multi-step carbonising or coking processes
• CPC Class Codes: Y02E 50/10 : Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02P 20/145 : the feedstock being materials of biological origin
• CPC Class Codes: Y10S 71/903 : Soil conditioner

Abstract

A method for creating treated biochar is provided that includes infusing a liquid additive into the pores of biochar, such as a fertilizer solution or other additive beneficial to plant growth. The method further includes the removal of materials and/or other additives from the pores of biochar. The present invention further provides biochar having pores filled with a liquid solution containing an additive, where the additive may include, but not be limited to, an additive beneficial to plant growth.

Claims

1. A method for creating treated biochar having pores, the method comprising the step of infusing a liquid additive into the pores of the biochar which does not include exclusively submersing the biochar in a liquid solution to infuse the liquid additive into the pores of the biochar and which does not include the exclusive use of steam to infuse the liquid additive into the pores of the biochar.

2. The method of claim 1 where the liquid additive is a fertilizer solution.

3. The method of claim 1 where the liquid additive is infused into the pores of the biochar using positive or negative pressure.

4. The method of claim 1 where the liquid additive is infused into the pores of the biochar using a surfactant.

5. The method of claim 1 where the pores of the biochar are washed prior to infusion with the liquid additive.

6. The method of claim 1 where the moisture content of the pores of the biochar is adjusted prior to infusion with the liquid additive.

7. The method of claim 2 where the liquid additive is 1000 ppm NO3⁻

N fertilizer solution.

8. The method of claim 2 where the liquid additive is solution of water and NPK based fertilizer.

9. The method of claim 4 where the surfactant treatment comprises adding 1% surfactant to the liquid additive.

10. The method of claim 1 where the liquid additive is a water based solution that includes an additive selected from the group consisting of nitrogen, phosphorous, potassium, urea, ammonium nitrate, calcium nitrate, ammonium sulfate, monoammonium phosphate, ammonium polyphosphate, Cal-Mag fertilizers, micronutrient fertilizers, fungicides, insecticides, nematicides, bacteriacides, fumigants, plant hormones, beneficial microbial spores, secondary signal activators, calcium, magnesium, sulfur, boron, zinc, iron, manganese, molybdenum, copper and chloride.

11. Biochar having pores where at least 25% of the pores by volume are filled with a liquid solution or suspension containing an additive, where the liquid is infused into the pores of the biochar.

12. The biochar of claim 11, where the liquid is a fertilizer solution.

13. The biochar of claim 12 where the fertilizer solution includes a chemical element selected from the group consisting of nitrogen, phosphorous, potassium, urea, ammonium nitrate, calcium nitrate ammonium sulfate, monoammonium phosphate, ammonium polyphosphate, Cal-Mag fertilizers and micronutrient fertilizers.

14. The biochar of claim 11 where the liquid solution includes a substance selected from the group consisting of fungicides, insecticides, nematicides, bacteriacides, fumigants, plant hormones, larvicides, enzymes, beneficial microbial spores, and secondary signal activators.

15. The biochar of claim 11 where the liquid solution includes a beneficial macro- and micro-nutrient.

16. The biochar of claim 15 where the beneficial macro- and micro-nutrient is selected from the group consisting of calcium, magnesium, sulfur, boron, zinc, iron, manganese, molybdenum, copper and chloride.

17. The biochar of claim 11 where the liquid solution includes 2,1,3-Benzothiadiazole (BTH).

18. The biochar of claim 11 where the liquid solution includes a signaling agent.

19. The biochar of claim 11 where the liquid solution includes a plant pathogen.

20. The biochar of claim 11 where the liquid solution includes a biopesticide.

21. The biochar of claim 11 where the liquid solution includes an herbicide.

22. The biochar of claim 11 where the liquid solution includes a fungicide.

23. The biochar of claim 11 where the liquid solution includes a plant hormone.

24. The biochar of claim 11 where the liquid solution includes one or more microbes.

25. The biochar of claim 11 where the biochar is sterilized before being infused with the liquid solution or suspension containing an additive.

26. The biochar of claim 11 where the additive includes mycorrhizal fungi.

27. A method for creating enhanced biochar having pores, the method comprising the step of infusing a liquid solution or suspension containing nutrients, vitamins, drugs, microbes and/or other supplements into the pores of the biochar which does not include exclusively submersing the biochar in the liquid solution or suspension to infuse the liquid solution or suspension into the pores of the biochar and which does not include the exclusive use of steam to infuse the liquid solution or suspension into the pores of the biochar.

28. The method of claim 27 where the nutrients, vitamins, drugs, microbes, and/or other supplements are infused into the pores of the biochar using positive or negative pressure.

29. The method of claim 27 where the nutrients, vitamins, drugs, microbes and/or other supplements are infused into the pores of the biochar using a surfactant.

30. The method of claim 27 where the liquid solution or suspension includes an additive selected from the group consisting of water, liquid inorganic and organic compounds of different composition and polarity, water solutions of salts, water solutions of acids, water solutions of bases, water solutions of organic compounds, water solutions of inorganic compounds, liquid organic compounds, liquid inorganic compounds, solvents, mineral oils, organic oils, turpentine, olive oil, palm oil, mineral extracts, organic extracts, extracts containing organic compounds, extracts of inorganic compounds, slurries, suspensions, slurries comprising solid phases including inorganic oxides, hydroxides, salts, organometallic complexes, nano-dispersed solids, micro-dispersed solids, carbon-based clusters, and fine particles, and supercritical liquids.

31. A method for integrating a microbial community with a biochar particle the method selected from the group consisting of:

while under vacuum, pulling the microbial solution through a treated biochar bed that is resting on a membrane filter;

spraying a microbial solution on top of a treated biochar bed;

lyophilizing a microbial solution and then blending said freeze dried solution with the treated biochar;

again infusing the treated biochar with a microbial solution;

adding treated biochar to a growth medium, inoculating with the microbe, and incubating to allow the microbe to grow in said biochar containing medium;

infusing, as defined previously, the biochar with a food source and then introducing the substrate infused biochar to a microbe and incubating to allow the microbes to grow;

blending microbial strains in dry form with treated biochar;

adding the treated biochar to a microbial solution and then centrifuging with a density gradient in order to promote the biochar to spin down with the microbes;

densely packing a column with treated biochar and then using gravity to flow a microbial solution through the column and repeating this step until an acceptable combination of treated biochar and microbial solution is reached; and

adding the microbe to a solution based binder to enter the treated biochar pores and then adding said solution to the treated biochar.

32. The method of claim 31 where biochar is sterilized before being infused with the microbial community.

33. The method of claim 31 where the microbial community includes mycorrhizal fungi.

34. A method for treating biochar having pores, the method comprising the step of removing an infiltrant or other materials from the pores of the biochar which does not include exclusively submersing the biochar in a liquid solution to remove the infiltrant or other materials from the pores of the biochar and which does not include the exclusive use of steam to remove the infiltrant or other materials from the pores of the biochar.

35. The method of claim 34 where the infiltrant or other materials are removed from the pores of the biochar using positive or negative pressure.

36. The method of claim 34 where the infiltrant or other materials are removed from the pores of the biochar using a surfactant.

37. The method of claim 34 where the infiltrant or other materials removed from the pores of the biochar includes water.

38. The method of claim 37 where the removal of the water from the pores of the biochar adjusts the moisture content of the pores of the biochar.

39. The method of claim 34 where the infiltrant or other materials removed from the pores of the biochar are deleterious materials selected from the group consisting of heavy metals, transition metals, sodium and phytotoxic organics, polycyclic aromatic hydrocarbons, volatile organic compounds (VOCs) and phytotoxins.

40. The method of claim 34 further including the step of infusing a liquid additive into the pores of the biochar.