Metal-ceramic coating for heat exchanger tubes of a central solar receiver and methods of preparing the same

• US 10,126,021 B2
• Filed: 07/15/2016
• Issued: 11/13/2018
• Est. Priority Date: 07/15/2016
• Status: Expired due to Fees

• Current Assignee: General Electric Technology GmbH (GE Vernova, Inc.)
• Original Assignee: General Electric Technology GmbH (GE Vernova, Inc.)
• Inventors: Bossmann, Hans-Peter, Hasani, Maryam Bahraini
• Primary Examiner(s): Savani, Avinash
• Application Number:
  US15/211,195
• Publication Number:
  US 20180017290A1
• Time in Patent Office: 851 Days
• Field of Search: 126676
• CPC Class Codes: C23C 24/02 by application of pressure only
• CPC Class Codes: C23C 24/04 Impact or kinetic deposition of particles
• CPC Class Codes: C23C 28/027 including at least one metal matrix material comprising a mixture of at least two metals or metal phases or metal matrix composites, e.g. metal matrix with embedded inorganic hard particles, CERMET, MMC.
• CPC Class Codes: C23C 28/04 only coatings of inorganic non-metallic material
• CPC Class Codes: C23C 28/042 including a refractory ceramic layer, e.g. refractory metal oxides, ZrO2, rare earth oxides
• CPC Class Codes: C23C 4/10 Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
• CPC Class Codes: C23C 4/11 Oxides
• CPC Class Codes: C23C 4/129 Flame spraying
• CPC Class Codes: C23C 4/131 Wire arc spraying
• CPC Class Codes: C23C 4/134 Plasma spraying
• CPC Class Codes: F24S 20/20 Solar heat collectors for receiving concentrated solar energy, e.g. receivers for solar power plants
• CPC Class Codes: F24S 70/20 characterised by absorbing coatings; characterised by surface treatment for increasing absorption
• CPC Class Codes: F28F 13/18 by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing
• CPC Class Codes: F28F 2013/001 Particular heat conductive materials, e.g. superconductive elements
• CPC Class Codes: F28F 21/04 of ceramic; of concrete; of natural stone
• CPC Class Codes: F28F 21/081 Heat exchange elements made from metals or metal alloys
• CPC Class Codes: F28F 21/082 from steel or ferrous alloys
• CPC Class Codes: F28F 21/086 from titanium or titanium alloys
• CPC Class Codes: F28F 21/087 from nickel or nickel alloys
• CPC Class Codes: Y02E 10/40 Solar thermal energy, e.g. solar towers

Abstract

Provided are metal-ceramic coatings for heat exchanger tubes of a central solar receiver and methods of preparing the same. The metal-ceramic coatings comprise at least one ceramic phase dispersed in a metal matrix and are disposed along the heat exchanger tubes to improve heat transfer and reduce oxidation of the heat exchanger tubes. Methods of preparing the metal-ceramic coatings and systems for using the same are provided.

Claims

1. A central solar receiver heat exchanger tube, comprising:

a heat exchanger tube defining a surface, wherein the heat exchanger tube comprises a base material; and

a metal-ceramic coating disposed along the surface of the heat exchanger tube, wherein the metal-ceramic coating comprises a metal matrix with at least one ceramic phase dispersed in the metal matrix, and wherein the metal-ceramic coating is configured on the heat exchanger tube base material to reduce oxidation of the heat exchanger tube base material.

2. The central solar receiver heat exchanger tube according to claim 1, wherein the at least one ceramic phase comprises a non-oxide ceramic material, and wherein the non-oxide ceramic material comprises SiC, Si₃N₄, Ti₃SiC₂, Ti₄SiC₃, Ti₂AlC, Ti₃AlC₂, Cr₂AlC, or combinations thereof.

3. The central solar receiver heat exchanger tube according to claim 1, wherein the at least one ceramic phase comprises an oxide ceramic material, and wherein the oxide ceramic material comprises Co₃O₄, TiO₂, SiO₂, Fe₂O₃, Fe₃O₄, Mn₂O₃, or combinations thereof.

4. The central solar receiver heat exchanger tube according to claim 1, wherein the metal-ceramic coating comprises a first ceramic phase and a second ceramic phase dispersed in the metal matrix, and wherein the first ceramic phase comprises a non-oxide ceramic material and the second ceramic phase comprises an oxide ceramic material.

5. The central solar receiver heat exchanger tube according to claim 1, wherein the metal-ceramic coating comprises a first metal-ceramic layer and a second metal-ceramic layer, wherein the first metal-ceramic layer comprises a first metal matrix and a non-oxide ceramic material dispersed in the first metal matrix, and wherein the second metal-ceramic layer comprises a second metal matrix and an oxide ceramic material dispersed in the second metal matrix.

6. The central solar receiver heat exchanger tube according to claim 1, wherein the metal matrix comprises a nickel-based super alloy or steel.

7. The central solar receiver heat exchanger tube according to claim 1, wherein the base material of the heat exchanger tube comprises a nickel-based super alloy or steel.

8. The central solar receiver heat exchanger tube according to claim 1, wherein the thermal conductivity of the metal-ceramic coating is greater than or equal to about 25 W/mK.

9. The central solar receiver heat exchanger tube according to claim 1, wherein the absorption coefficient for solar radiation of the metal-ceramic coating is at least 90%.

10. The central solar receiver heat exchanger tube according to claim 1, wherein the metal-ceramic coating is disposed along the radiation portion of the heat exchanger tube base material.

11. The central solar receiver heat exchanger tube according to claim 1, wherein the ceramic phase comprises a volume fraction of about 0.2 to about 0.8 of the metal-ceramic coating.

12. The central solar receiver heat exchanger tube according to claim 5, wherein the first metal-ceramic layer has a volume fraction of ceramic material of about 0.2 to about 0.8 of the first metal-ceramic layer.

13. The central solar receiver heat exchanger tube according to claim 5, wherein the second metal-ceramic layer has a volume fraction of ceramic material of about 0.2 to about 0.8 of the second metal-ceramic layer.

14. A method of preparing a metal-ceramic coated central solar receiver heat exchanger, the method comprising:

applying a metal-ceramic coating onto a surface of a heat exchanger tube, wherein the heat exchanger tube comprises a base material, wherein the metal-ceramic coating comprises a metal matrix with at least one ceramic phase dispersed in the metal matrix, and wherein the metal-ceramic coating is configured on the heat exchanger tube base material to reduce oxidation of the heat exchanger tube base material.

15. The method of preparing a metal-ceramic coated central solar receiver heat exchanger according to claim 14, wherein applying the metal-ceramic coating comprises applying a first metal-ceramic layer and applying a second metal-ceramic layer, wherein the first metal-ceramic layer comprises a non-oxide ceramic material and the second metal-ceramic layer comprises an oxide ceramic material.

16. The method of preparing a metal-ceramic coated central solar receiver heat exchanger according to claim 15, wherein the non-oxide ceramic material comprises SiC, Si₃N₄, Ti₃SiC₂, Ti₄SiC₃, Ti₂AlC, Ti₃AlC₂, Cr₂AlC, or combinations thereof.

17. The method of preparing a metal-ceramic coated central solar receiver heat exchanger according to claim 15, wherein the oxide ceramic material comprises Co₃O₄, TiO₂, SiO₂, Fe₂O₃, Fe₃O₄, Mn₂O₃, or combinations thereof.

18. The method of preparing a metal-ceramic coated central solar receiver heat exchanger according to claim 14, wherein the metal matrix comprises a nickel-based super alloy or steel.

19. A system for solar heat transfer, comprising:

a central solar receiver comprising one or more heat exchanger tubes, wherein the one or more heat exchanger tubes comprises a material and a metal-ceramic coating disposed along a surface of the heat exchanger tube, wherein the metal-ceramic coating comprises a metal matrix with at least one ceramic phase dispersed in the metal matrix, and wherein the metal-ceramic coating is configured on the heat exchanger tube base material to reduce oxidation of the heat exchanger tube base material.