Device for optically determining the concentration of alcohol and carbohydrates in a liquid sample

• US 10,132,787 B2
• Filed: 09/04/2014
• Issued: 11/20/2018
• Est. Priority Date: 09/05/2013
• Status: Active Grant

• Current Assignee: Haffmans B.V. (Pentair Plc (Ireland))
• Original Assignee: Haffmans B.V. (Pentair Plc (Ireland))
• Inventors: Levels, Geert Hubert Willem, Martynowicz, Emile Thomas Martinus Johannes
• Primary Examiner(s): Porta, David
• Assistant Examiner(s): Faye, Mamadou
• Application Number:
  US14/476,990
• Publication Number:
  US 20150060674A1
• Time in Patent Office: 1,538 Days
• Field of Search: 25033907, 25033908, 25033912, 250343, 356322
• CPC Class Codes: G01J 2003/4275 Polarised dual wavelength spectrometry
• CPC Class Codes: G01N 21/031 Multipass arrangements
• CPC Class Codes: G01N 21/0332 with temperature control control of temperature G05D23/00; cryostats F17C3/08
• CPC Class Codes: G01N 21/21 Polarisation-affecting properties G01N21/19 takes precedence
• CPC Class Codes: G01N 21/3151 using two sources of radiation of different wavelengths G01N21/33 - G01N21/39 take precedence
• CPC Class Codes: G01N 21/3577 for analysing liquids, e.g. polluted water
• CPC Class Codes: G01N 21/359 using near infrared light
• CPC Class Codes: G01N 21/85 Investigating moving fluids or granular solids
• CPC Class Codes: G01N 2201/0624 Compensating variation in output of LED source
• CPC Class Codes: G01N 33/14 Beverages
• CPC Class Codes: G01N 33/146 containing alcohol

Abstract

Disclosed is a device for optically determining a concentration of alcohol and carbohydrates in a liquid sample. The device includes at least a first and a second light source arranged for exposing the liquid sample in a wavelength range between 750 nm and 1000 nm, a spectrometer arranged to determine a first and a second light intensity by measuring the light from the first and the second light source, a processing unit which is connected to the spectrometer and which is arranged to determine an absorption value of the liquid sample from a comparison of the first and the second light intensity with a reference value. In certain aspects, the device may further include a processing unit that calculates concentrations of alcohol and/or carbohydrates and at least two polarization filters.

Claims

1. A device installed in a production line for optically determining a concentration of alcohol and carbohydrates in a liquid sample, comprising:

a first and a second light source arranged for exposing and emitting light through the liquid sample having a wavelength ranging between 750 nm and 1000 nm from the first and second light source as the liquid sample is passing through a measuring chamber in the production line;

a spectrometer arranged to determine a first and a second light intensity by measuring the light from the first and the second light source emitted through the liquid sample;

a temperature sensor for measuring a temperature of said liquid sample in the production line;

a processing unit connected to the spectrometer and arranged to determine an absorption value of the liquid sample from a comparison of the first and the second light intensity with a reference value and

two polarization filters for filtering the light from the first light source, wherein;

the processing unit is further arranged to calculate and present the concentration of alcohol from the proportion of the absorption at a wavelength of less than 900 nm and the wavelength range between 900 nm and 920 nm, and to calculate and present the concentration of carbohydrates from the proportion of the absorption in the wavelength range between 750 nm and 900 nm and at a wavelength of 900 nm, wherein the processing unit is arranged to determine if the measured temperature in the production line is outside of a predetermined range, and wherein an outcome thereof defines reliability of the calculated concentrations; and

the first polarization filter is positioned between the first light source and the liquid sample and the second polarization is positioned between the liquid sample and the spectrometer, and wherein the liquid sample is selected from the group consisting of beer, wine, liquors, low-alcohol beer, non-alcoholic beer, and soft drinks.

2. The device of claim 1, wherein the first and second polarization filters are positioned at an angle relative to each other, the angle ranging from 10 to 170 degrees.

3. The device of claim 1, wherein the processing unit is arranged to formulate a linear equation from a plurality of reference measurements and to calculate the concentrations of carbohydrates and alcohol from the linear equation.

4. The device of claim 3, wherein the linear equation is a simple linear regression or multiple linear regression analysis.

5. The device of claim 1, further comprising a reflecting surface for reflecting the light from the first and the second light source to the spectrometer.

6. The device of claim 1, further comprising a first and a second lens element for focusing the light from the first and the second light source to the spectrometer.

7. The device of claim 1, further comprising a window for closing the device to the liquid sample, and

the window is arranged to only transmit light in the wavelength range between 750 nm and 1000 nm.

8. The device of claim 1, further comprising temperature control means for maintaining the liquid sample at a constant, predetermined temperature.

9. The device of claim 1, wherein the spectrometer comprises a monochromator.

10. The device of claim 1, wherein the alcohol comprises ethanol.

11. The device of claim 10, wherein the carbohydrates consist of an extract comprising at least one or more from the group of glucose, maltose, dextrine, fructose, and sucrose.

12. A method for optically determining a concentration of alcohol and carbohydrates in a liquid sample by a device installed in a production line, comprising the steps of:

providing the liquid sample and passing the liquid sample through a measuring chamber of the device installed in the production line;

exposing the liquid sample to a first and a second light source in which the light sources are arranged to alternately expose the liquid sample to a wavelength ranging between 750 nm and 1000 nm by emitting light from the first and second light sources through the liquid sample as the liquid sample is passing through the measuring chamber of the device installed in the production line;

determining a first and a second light intensity by means of a spectrometer by measuring the light emitted through the liquid sample from the first and the second light sources;

measuring temperature of said liquid sample in the production line with a temperature sensor;

determining with a processing unit, an absorption value of the liquid sample by comparing the first and the second light intensity with a reference value;

calculating and presenting with a processing unit, the concentration of alcohol from the proportion of the absorption in the wavelength range of less than the 900 nm and the wavelength range between 900 nm and 920 nm and

the concentration of carbohydrates from the proportion of the absorption between 750 nm and 900 nm and the absorption in excess of 900 nm, wherein;

the liquid sample is selected from the group consisting of beer, wine, liquors, low-alcohol beer, non-alcoholic beer, and soft drinks, wherein;

the processing unit is arranged to determine if the measured temperature in the production line is outside of a predetermined range, and wherein an outcome thereof defines reliability of the calculated concentrations.

13. The method for optically determining a concentration of alcohol and carbohydrates in a liquid sample according to claim 12, further comprising

defining a linear equation from a plurality of reference measurements;

and

calculating the concentration of carbohydrates and alcohol from the linear equation, wherein;

the linear equation is a simple or multiple linear regression analysis.