Polymer and asphalt composition

• US 10,138,319 B2
• Filed: 01/16/2015
• Issued: 11/27/2018
• Est. Priority Date: 01/17/2014
• Status: Active Grant

• Current Assignee: Asahi Kasei Kabushiki Kaisha (Asahi Kasei Corporation)
• Original Assignee: Asahi Kasei Kabushiki Kaisha (Asahi Kasei Corporation)
• Inventors: Shiromoto, Takayuki, Nakajima, Shigeo, Araki, Yoshifumi, Kubo, Nobuaki, Suzuki, Takuya
• Primary Examiner(s): Rodd, Christopher M
• Application Number:
  US15/111,891
• Publication Number:
  US 20160333132A1
• Time in Patent Office: 1,411 Days
• CPC Class Codes: C08F 297/04 polymerising vinyl aromatic monomers and conjugated dienes
• CPC Class Codes: C08F 6/12 Separation of polymers from solutions
• CPC Class Codes: C08L 2555/80 Macromolecular constituents
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 95/00 Compositions of bituminous materials, e.g. asphalt, tar, pitch

Abstract

The polymer according to the present invention is a polymer containing a conjugated diene monomer unit and a vinyl aromatic monomer unit, wherein the polymer has a polymer block (A) containing the vinyl aromatic monomer unit as a main component and a polymer block (B) containing the conjugated diene monomer unit and the vinyl aromatic monomer unit, a content of the polymer block (A) is 10% by mass or more and 40% by mass or less, a bulk density of the polymer is 0.05 g/mL or more and 0.45 g/mL or less, and a specific surface area of the polymer is 0.10 m²/g or more and 0.60 m²/g or less.

Claims

1. A polymer comprising a conjugated diene monomer unit and a vinyl aromatic monomer unit,

wherein the polymer has a polymer block (A) comprising the vinyl aromatic monomer unit as a main component and a polymer block (B) comprising the conjugated diene monomer unit and the vinyl aromatic monomer unit,

a content of the polymer block (A) is 10% by mass or more and 40% by mass or less,

a bulk density of the polymer is 0.05 g/mL or more and 0.45 g/mL or less, and

a specific surface area of the polymer is 0.10 m²/g or more and 0.60 m²/g or less,

in the polymer block (B), a content of a short-chain vinyl aromatic monomer-polymerized moiety comprising 2 to 6 vinyl aromatic monomer units is 50% by mass or more based on the content of the vinyl aromatic monomer unit being 100% by mass.

2. The polymer according to claim 1, wherein a hydrogenation rate of double bonds in the conjugated diene monomer unit is 95 mol % or more.

3. The polymer according to claim 1, wherein a hydrogenation rate of double bonds in the conjugated diene monomer unit is 0 mol % or more and less than 50 mol %.

4. The polymer according to claim 1, wherein a hydrogenation rate of double bonds in the conjugated diene monomer unit is 50 mol % or more and less than 95 mol %.

5. The polymer according to claim 1, wherein the specific surface area is 0.30 m²/g or more and 0.60 m²/g or less.

6. The polymer according to claim 1, wherein the specific surface area is 0.10 m²/g or more and less than 0.30 m²/g.

7. The polymer according to claim 1, wherein a proportion of components that pass through a sieve having a mesh size of 3.35 mm and do not pass through a sieve having a mesh size of 0.425 mm is less than 80% by mass based on a total amount of crumbs.

8. The polymer according to claim 1, wherein the polymer has a peak molecular weight of less than 200,000.

9. The polymer according to claim 1, wherein a content of the vinyl aromatic monomer unit is 20% by mass or more and 60% by mass or less.

10. The polymer according to claim 1, wherein the content of the short-chain vinyl aromatic monomer-polymerized moiety is 70% by mass or more.

11. The polymer according to claim 1, wherein the polymer has a functional group.

12. An asphalt composition comprising 0.5 parts by mass or more and 50 parts by mass or less of the polymer according to claim 1 and 100 parts by mass of an asphalt.

13. An asphalt composition comprising:

a mixture comprising the polymer according to claim 1 and a block copolymer (a); and

an asphalt,

wherein the block copolymer (a) has a polymer block (A′

) comprising at least one vinyl aromatic monomer unit as a main component and a polymer block (C) comprising at least one conjugated diene monomer unit as a main component,

a content of the mixture is 0.5 parts by mass or more and 50 parts by mass or less based on 100 parts by mass of the asphalt, and

a content of the block copolymer (a) in the mixture is 15 to 85% by mass.

14. The asphalt composition according to claim 12, further comprising 0.03 parts by mass or more and 3 parts by mass or less of sulfur or a sulfur compound.

15. The asphalt composition according to claim 13, further comprising 0.03 parts by mass or more and 3 parts by mass or less of sulfur or a sulfur compound.

16. An asphalt composition comprising:

a mixture comprising the polymer according to claim 11 and a block copolymer (a); and

an asphalt,

wherein the block copolymer (a) has a polymer block (A′

) comprising at least one vinyl aromatic monomer unit as a main component and a polymer block (C) comprising at least one conjugated diene monomer unit as a main component,

a content of the mixture is 0.5 parts by mass or more and 50 parts by mass or less based on 100 parts by mass of the asphalt, and

a content of the block copolymer (a) in the mixture is 15 to 85% by mass.

17. An asphalt composition comprising 0.5 parts by mass or more and 50 parts by mass or less of the polymer according to claim 11 and 100 parts by mass of an asphalt.