Apparatus and method for ionic liquid electroplating

• US 10,138,567 B2
• Filed: 09/14/2016
• Issued: 11/27/2018
• Est. Priority Date: 10/14/2013
• Status: Active Grant

• Current Assignee: Rtx Corporation
• Original Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Inventors: Chen, Lei
• Primary Examiner(s): Rufo, Louis J
• Application Number:
  US15/265,693
• Publication Number:
  US 20170002478A1
• Time in Patent Office: 804 Days
• CPC Class Codes: C23C 18/54 Contact plating, i.e. electroless electrochemical plating
• CPC Class Codes: C25D 17/002 Cell separation, e.g. membranes, diaphragms
• CPC Class Codes: C25D 17/10 Electrodes , e.g. composition, counter electrode
• CPC Class Codes: C25D 21/06 Filtering particles other than ions filtering ions C25D21/22
• CPC Class Codes: C25D 21/10 Agitating of electrolytes; Moving of racks
• CPC Class Codes: C25D 3/42 of light metals
• CPC Class Codes: C25D 3/44 Aluminium
• CPC Class Codes: C25D 3/665 from ionic liquids
• CPC Class Codes: C25D 5/36 of iron or steel
• CPC Class Codes: C25D 5/40 Nickel; Chromium
• CPC Class Codes: C25D 5/42 of light metals
• CPC Class Codes: C25D 5/44 Aluminium
• CPC Class Codes: C25F 3/04 of light metals
• CPC Class Codes: C25F 3/06 of iron or steel
• CPC Class Codes: C25F 3/08 of refractory metals

Abstract

An electroplating apparatus includes a container containing plural portions and an ionic liquid plating solution that is capable of flowing therebetween. The plural portions include at least a first portion containing a counter electrode that includes coating donor material and a second portion that includes a workpiece. A porous scrubber separating the first and second portions has a plurality of metallic outer surfaces in contact with the ionic liquid plating solution. Coating, repair, and regeneration methods using an ionic liquid plating solution are also described.

Claims

1. A method for coating at least a first surface of a workpiece with a metallic coating, the method comprising:

electrolytically etching a first portion of the workpiece in a container holding an ionic liquid plating solution, the etching step comprising subjecting the workpiece to an anodic potential and subjecting a counter electrode to a cathodic potential to remove at least a portion of an applied displacement layer, thereby (i) accumulating ionic byproducts of the removed portion of the displacement layer in the ionic liquid plating solution in the container and (ii) exposing and activating the first surface;

electrodepositing the metallic coating onto the exposed and activated portion of the first surface without removing the workpiece from the container or the ionic liquid plating solution, the electrodepositing step comprising subjecting the counter electrode to an anodic potential and subjecting the workpiece to a cathodic potential to deposit coating donor material from the counter electrode onto the surface to be coated; and

during at least one of the etching step and the electrodepositing step, fluidly communicating a portion of the ionic liquid plating solution through a porous scrubber disposed in the ionic liquid plating solution in the container between the workpiece and the counter electrode, the scrubber having a plurality of metallic outer surfaces in contact with the ionic liquid plating solution to capture at least some of the accumulated ionic byproducts of the removed portion of the displacement layer from the ionic liquid plating solution;

wherein a portion of the ionic byproducts adhere to the metallic outer surfaces of the scrubber during at least the etching mode, thereby regenerating the ionic liquid plating solution in situ by removing at least a portion of the ionic byproducts therefrom without removing the ionic liquid plating solution from the container.

2. The method of claim 1, further comprising:

pretreating a first portion of the workpiece that includes the first surface;

prior to the electrolytically etching step, depositing the displacement layer onto at least the pretreated first portion of the workpiece.

3. The method of claim 1, wherein the workpiece comprises a metallic component substrate selected from the group consisting of:

aluminum, magnesium, chromium, nickel, molybdenum, iron, and alloys thereof.

4. The method of claim 2, wherein the pretreating step comprises:

one or more of grit blasting, acid etching, desmutting, rinsing, and drying.

5. The method of claim 2, wherein the displacement layer comprises a metal selected from a group consisting of:

zinc, tin, copper, zirconium, cerium, and alloys thereof.

6. The method of claim 5, wherein the depositing step comprises:

an immersion process including a zincating process.

7. The method of claim 1, wherein the metallic coating comprises a substantially pure metal selected from the group consisting of:

aluminum and magnesium.

8. The method of claim 3, wherein the metallic component substrate comprises an aluminum alloy selected from the group consisting of:

AA 6061 alloy, AA 7075 alloy, and AA 2024 alloy.

9. The method of claim 1, wherein the workpiece comprises a turbine engine component.

10. The method of claim 1, wherein the ionic liquid plating solution comprises an ionic liquid selected from:

1-ethyl-3-methylimidazolium chloride [EMIM][Cl]-AlCl₃, 1-butyl-3-methylimidizolium chloride [BMIM][Cl]-AlCl₃, and combinations thereof.

11. The method of claim 1, further comprising:

electrically biasing the porous scrubber at least during the etching step.

12. The method of claim 1, further comprising:

electrically biasing the porous scrubber at least during the electroplating step.

13. The method of claim 1, further comprising:

operating at least one agitator in the container, the agitator adapted to circulate the ionic liquid plating solution through the porous scrubber.

14. The method of claim 1, wherein a configuration of the porous scrubber is selected from a group consisting of:

a mesh, foam, a honeycomb, a powder bed, and a fluidized bed, and combinations thereof.