Method of extracting bitumen from oil sands with a propylene oxide capped glycol

• US 10,138,719 B2
• Filed: 03/20/2015
• Issued: 11/27/2018
• Est. Priority Date: 03/27/2014
• Status: Active Grant

• Current Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Original Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Inventors: Akiya, Naoko, Daugs, Edward D., Donate, Felipe A., Singh, Harpreet
• Primary Examiner(s): Runyan, Silvana C
• Application Number:
  US15/119,149
• Publication Number:
  US 20170051597A1
• Time in Patent Office: 1,348 Days
• Field of Search: 166303
• CPC Class Codes: C09K 8/592 Compositions used in combination with generated heat, e.g. by steam injection
• CPC Class Codes: C10G 1/045 Separation of insoluble materials
• CPC Class Codes: C10G 2300/4037 In-situ processes
• CPC Class Codes: C10G 33/04 with chemical means
• CPC Class Codes: E21B 43/24 using heat, e.g. steam injection

Abstract

Oil sands may be surface mined and transported to a treatment area or may be treated directly by means of an in situ process of oil sand deposits that are located too deep for strip mining. A bitumen recovery process may be used to extract bitumen from oil sands. Specifically, the bitumen recover process involves a step of treating oil sands with a propylene oxide capped glycol ether described by the structure:
RO—(C₂H₄O)_n—CH₂CH(CH₃)OH
wherein R is a linear, branched, or cyclic alkyl, phenyl, alkyl phenyl group and n is 1 to 10.

Claims

1. A bitumen recovery process comprising a step of treating oil sands with a propylene oxide capped glycol ether, wherein:

the oil sands are recovered by surface mining and transported to a treatment area for the step of treating the oil sands with the propylene oxide capped glycol ether or the oil sands are recovered by in situ production and in situ treatment occurs during the step of treating the oil sands with the propylene oxide capped glycol ether, and

the propylene oxide capped glycol ether is described by the following structure;

RO—

(C₂H₄O)_n—

CH₂CH(CH₃)OH

wherein R is a linear, branched, cyclic alkyl, phenyl, or alkyl phenyl group and n is 1 to 10.

2. The bitumen recovery process of claim 1 by surface mining comprising additional steps of:

i) surface mining the oil sands,

ii) preparing an aqueous slurry of the oil sands,

iii) treating the aqueous slurry with the propylene oxide capped glycol ether,

iv) agitating the treated aqueous slurry to form an agitated treated aqueous slurry,

v) transferring the agitated treated aqueous slurry to a separation tank, and

vi) separating the bitumen from an aqueous portion.

3. The bitumen recovery process of claim 2 wherein the propylene oxide capped glycol ether is present in the aqueous slurry in an amount of from 0.01 to 10 weight percent based on the weight of the oil sands.

4. The bitumen recovery process of claim 1 by in situ production comprising additional steps of:

i) treating a subterranean reservoir of oil sands by injecting steam containing the propylene oxide capped glycol ether into a well, and

ii) recovering the bitumen from the well.

5. The bitumen recovery process of claim 4 wherein the concentration of the propylene oxide capped glycol ether in the steam is in an amount of from 100 ppm to 10 weight percent.

6. The bitumen recovery process of claim 1 wherein the propylene oxide capped glycol ether is a propylene oxide capped of:

n-butyl ether of ethylene glycol, n-butyl ether of diethylene glycol, n-pentyl ether of ethylene glycol, n-pentyl ether of diethylene glycol, 2-methyl-1-pentyl ether of ethylene glycol, 2-methyl-1-pentyl ether of diethylene glycol, n-hexyl ether of ethylene glycol, n-hexyl ether of diethylene glycol, n-heptyl ether of ethylene glycol, n-heptyl ether of diethylene glycol, n-octyl ether of ethylene glycol, n-octyl ether of diethylene glycol, 2-ethylhexyl ether of ethylene glycol, 2-ethylhexyl ether of diethylene glycol, 2-propylheptyl ether of ethylene glycol, 2-propylheptyl ether of diethylene glycol, phenyl ether of ethylene glycol, phenyl ether of diethylene glycol, cyclohexyl ether of ethylene glycol, cyclohexyl ether of diethylene glycol, or mixtures thereof.

7. The bitumen recovery process of claim 1 wherein:

when the oil sands are recovered by surfacing mining, an aqueous slurry of the oil sands is prepared and the step of treating the oil sands includes adding the propylene oxide capped glycol ether to the aqueous slurry, and

when the oil sands are recovered by in situ production the step of treating the oil sands includes injecting steam containing the propylene oxide capped glycol ether into a well having a subterranean reservoir that includes the oil sands.