Processing of alpha/beta titanium alloys

• US 10,144,999 B2
• Filed: 07/19/2017
• Issued: 12/04/2018
• Est. Priority Date: 07/19/2010
• Status: Active Grant

• Current Assignee: ATI Properties LLC
• Original Assignee: ATI Properties LLC
• Inventors: Bryan, David J.
• Primary Examiner(s): Hoban, Matthew E.
• Application Number:
  US15/653,985
• Publication Number:
  US 20180016670A1
• Time in Patent Office: 503 Days
• CPC Class Codes: C21D 1/26 Methods of annealing
• CPC Class Codes: C22C 14/00 Alloys based on titanium
• CPC Class Codes: C22F 1/18 High-melting or refractory metals or alloys based thereon
• CPC Class Codes: C22F 1/183 of titanium or alloys based thereon

Abstract

Processes for forming an article from an α+β titanium alloy are disclosed. The α+β titanium alloy includes, in weight percentages, from 2.90 to 5.00 aluminum, from 2.00 to 3.00 vanadium, from 0.40 to 2.00 iron, and from 0.10 to 0.30 oxygen. The α+β titanium alloy is cold worked at a temperature in the range of ambient temperature to 500° F., and then aged at a temperature in the range of 700° F. to 1200° F.

Claims

1. A process comprising:

cold working an α

+β

titanium alloy workpiece at a temperature in the range of ambient temperature to 500°

F.; and

direct aging the cold-worked α

+β

titanium alloy workpiece at a temperature in the range of 700°

F. to 1200°

F. without any quenching intermediate cold working the α

+β

titanium alloy workpiece and direct aging the cold-worked α

+β

titanium alloy workpiece;

the α

+β

titanium alloy comprising, in weight percentages, from 2.90 to 5.00 aluminum, from 2.00 to 3.00 vanadium, from 0.40 to 2.00 iron, from 0.10 to 0.30 oxygen, titanium, and incidental impurities, wherein the cold working and direct aging forms an α

+β

titanium alloy article having an ultimate tensile strength (UTS) and an elongation that satisfy the equation;

5×

(Elongation in %)+(UTS in ksi)≥

230.

2. The process of claim 1 comprising cold working the α

+β

titanium alloy workpiece to a 20% to 60% reduction in area.

3. The process of claim 1, wherein the cold working of the α

+β

titanium alloy comprises at least two deformation cycles, wherein each deformation cycle comprises cold working the α

+β

titanium alloy workpiece to an at least 10% reduction in area.

4. The process of claim 1 comprising cold working the α

+β

titanium alloy workpiece at ambient temperature.

5. The process of claim 1 comprising direct aging the α

+β

titanium alloy workpiece at a temperature in the range of 800°

F. to 1100°

F.

6. The process of claim 1 comprising direct aging the α

+β

titanium alloy workpiece for 0.5 to 10 hours at temperature.

7. The process of claim 1 comprising hot working the α

+β

titanium alloy workpiece at a temperature in the range of 300°

F. to 25°

F. below the β

-transus temperature of the α

+β

titanium alloy, wherein the hot working is performed before the cold working.

8. The process of claim 1 comprising hot working the α

+β

titanium alloy workpiece at a temperature in the range of 1500°

F. to 1775°

F., wherein the hot working is performed before the cold working.

9. The process of claim 7 comprising annealing the α

+β

titanium alloy at a temperature in the range of 1200°

F. to 1500°

F., wherein the annealing is performed between the hot working and the cold working.

10. The process of claim 1, wherein the cold working and direct aging forms an α

+β

titanium alloy article having an ultimate tensile strength in the range of 155 ksi to 200 ksi and an elongation in the range of 8% to 20%, at ambient temperature.

11. The process of claim 10, wherein the α

+β

titanium alloy article is selected from the group consisting of a billet, a bar, a rod, a tube, a slab, a plate, and a fastener.

12. The process of claim 10, wherein the α

+β

titanium alloy article has a diameter or thickness greater than 0.5 inches, an ultimate tensile strength greater than 165 ksi, a yield strength greater than 155 ksi, and an elongation greater than 12%.

13. The process of claim 1, wherein cold working the α

+β

titanium alloy workpiece comprises cold working by at least one operation selected from the group consisting of rolling, forging, extruding, pilgering, and drawing.

14. A process comprising:

hot working an α

+β

titanium alloy workpiece at a temperature in the range of 1500°

F. to 1775°

F.;

annealing the α

+β

titanium alloy at a temperature in the range of 1200°

F. to 1500°

F.;

cold working the α

+β

titanium alloy workpiece at ambient temperature to a 20% to 60% reduction in area; and

direct aging the cold worked α

+β

titanium alloy workpiece at a temperature in the range of 800°

F. to 1100°

F. without any quenching intermediate cold working the α

+β

titanium alloy workpiece and direct aging the cold worked α

+β

titanium alloy workpiece;

the α

+β

titanium alloy comprising, in weight percentages, from 2.90 to 5.00 aluminum, from 2.00 to 3.00 vanadium, from 0.40 to 2.00 iron, from 0.10 to 0.30 oxygen, titanium, and incidental impurities, wherein the cold working and direct aging forms an α

+β

titanium alloy article having an ultimate tensile strength (UTS) and an elongation that satisfy the equation;

5×

(Elongation in %)+(UTS in ksi)≥

230.

15. The process of claim 14, wherein the cold working of the α

+β

titanium alloy comprises at least two deformation cycles, wherein each deformation cycle comprises cold working the α

+β

titanium alloy workpiece to an at least 10% reduction in area.

16. The process of claim 14 comprising direct aging the α

+β

titanium alloy workpiece for 0.5 to 10 hours at temperature.

17. The process of claim 14 hot working the α

+β

titanium alloy workpiece at a temperature in the range of 300°

F. to 25°

F. below the β

-transus temperature of the α

+β

titanium alloy, wherein the hot working is performed before the cold working.

18. The process of claim 14, wherein the cold working and direct aging forms an α

+β

titanium alloy article having an ultimate tensile strength in the range of 155 ksi to 200 ksi and an elongation in the range of 8% to 20%, at ambient temperature.

19. The process of claim 18, wherein the α

+β

titanium alloy article is selected from the group consisting of a billet, a bar, a rod, a tube, a slab, a plate, and a fastener.

20. The process of claim 18, wherein the α

+β

titanium alloy article has a diameter or thickness greater than 0.5 inches, an ultimate tensile strength greater than 165 ksi, a yield strength greater than 155 ksi, and an elongation greater than 12%.

21. The process of claim 14, wherein cold working the α

+β

titanium alloy workpiece comprises cold working by at least one operation selected from the group consisting of rolling, forging, extruding, pilgering, and drawing.