Solid state lighting devices including quantum confined semiconductor nanoparticles, an optical component for a solid state lighting device, and methods

• US 10,145,539 B2
• Filed: 10/19/2015
• Issued: 12/04/2018
• Est. Priority Date: 05/06/2008
• Status: Active Grant

• Current Assignee: Samsung Electronics Co. Ltd.
• Original Assignee: Samsung Electronics Co. Ltd.
• Inventors: Coe-Sullivan, Seth, Linton, John R., Sadasivan, Sridhar, Squires, Emily M., Bawendi, Moungi G.
• Primary Examiner(s): CARIASO, ALAN B
• Application Number:
  US14/886,867
• Publication Number:
  US 20160209002A1
• Time in Patent Office: 1,142 Days
• CPC Class Codes: F21V 13/14 the elements being filters or photoluminescent elements, reflectors and refractors
• CPC Class Codes: F21V 3/0625 the material diffusing light, e.g. translucent plastics
• CPC Class Codes: F21V 3/08 the material comprising photoluminescent substances
• CPC Class Codes: F21V 3/12 the coatings comprising photoluminescent substances
• CPC Class Codes: F21V 9/32 characterised by the arrangement of the photoluminescent material
• CPC Class Codes: F21V 9/38 Combination of two or more photoluminescent elements of different materials
• CPC Class Codes: F21Y 2115/10 Light-emitting diodes [LED]
• CPC Class Codes: H01L 2933/0091 Scattering means in or on the semiconductor body or semiconductor body package H01L33/22 takes precedence
• CPC Class Codes: H01L 33/502 Wavelength conversion materials
• CPC Class Codes: H05B 33/145 Arrangements of the electroluminescent material

Abstract

A solid state lighting device including a light source capable of emitting white light including a blue spectral component and having a deficiency in a spectral region, and an optical component that is positioned to receive at least a portion of the light generated by the light source, the optical component comprising an optical material for converting at least a portion of the blue spectral component of the light to one or more predetermined wavelengths such that light emitted by the solid state lighting device includes light emission from the light source supplemented with light emission at one or more predetermined wavelengths, wherein the optical material comprises quantum confined semiconductor nanoparticles. Also disclosed is lighting fixture, a cover plate for a lighting fixture and a method.

Claims

1. An endoscopy light source comprising a solid state lighting device comprising a phosphor converted LED light source that emits white light including a blue spectral component and having a deficiency in at least one spectral region, and an optical component that is positioned to receive at least a portion of the light generated by the phosphor-converted LED light source and supplement the spectrum of the white light passing through the optical component, the optical component comprising an optical material for converting at least a portion of the blue spectral component of the white light to one or more predetermined wavelengths such that light emitted by the solid state lighting device includes white light emission from the phosphor-converted LED light source supplemented with light emission at the one or more predetermined wavelengths in the at least one deficient spectral region of the phosphor-converted LED light source, wherein the optical material comprises quantum confined semiconductor nanocrystals distributed in a light-transmissive solid host material, wherein the optical material is fully encapsulated by one or more barrier materials, wherein the optical component is not in direct contact with the phosphor-converted LED light source, wherein the at least one predetermined wavelength comprises a wavelength in a range from about 575 nm to about 650 nm,

wherein the quantum confined semiconductor nanocrystal comprises a Group II-VI compound, a Group II-V compound, a Group III-VI compound, a Group III-V compound, a Group IV-VI compound, a Group I-III-VI compound, a Group II-IV-VI compound, or a Group II-IV-V compound, and wherein the light emitted by the sold state lighting device has a General Color Rendering Index (Ra) greater than 80.

2. An endoscopy light source in accordance with claim 1 wherein at least one predetermined wavelength further comprises a wavelength in a range from about 450 nm to about 500 nm.

3. An endoscopy light source in accordance with claim 1 wherein the light emitted by the solid state lighting device has a General Color Rendering Index (Ra) greater than 90.

4. An endoscopy light source in accordance with claim 1 wherein the light emitted by the solid state lighting device has a General Color Rendering Index (Ra) greater than 95.

5. An endoscopy light source in accordance with claim 1 wherein the General Color Rendering Index (Ra) of the light emitted by the solid state lighting device is at least 10% higher than the General Color Rendering Index (Ra) of the light emitted by the phosphor-converted LED light source.

6. An endoscopy light source in accordance with claim 1 wherein the solid state lighting device maintains greater than 70% of the phosphor-converted LED light source lumens per watt efficiency.

7. An endoscopy light source in accordance with claim 1 wherein lumens per watt efficiency of the solid state lighting device does not substantially vary as a function of the color temperature of the solid state lighting device.

8. An endoscopy light source in accordance with claim 1 wherein quantum confined semiconductor nanocrystals are included in the optical material in an amount in a range from about 0.001 to about 5 weight percent of the weight of the host material.

9. An endoscopy light source in accordance with claim 1 wherein the optical material further comprises light scatterers.

10. An endoscopy light source in accordance with claim 9 wherein light scattering particles are included in the optical material in an amount in a range from about 0.001 to about 5 weight percent of the weight of the host material.

11. An endoscopy light source in accordance with claim 1 wherein the optical material comprising quantum confined semiconductor nanocrystals are disposed over a surface of a support element.

12. An endoscopy light source in accordance with claim 1 wherein the temperature at the location of the nanocrystals during operation of the solid state lighting device is less than 90°

C.

13. An endoscopy light source in accordance with claim 1 wherein optical material comprises quantum confined semiconductor nanocrystals capable of emitting red light.

14. An endoscopy light source in accordance with claim 1 wherein the solid host material comprises at least one of polymers, monomers, resins, binders, glasses, metal oxides, nonpolymeric materials, and silica gels.

15. An endoscopy light source in accordance with claim 1 wherein the semiconductor nanocrystal includes a core comprising a first semiconductor material and a shell comprising a second semiconductor material on at least a portion of a surface of the core, the first semiconductor material is different from the second semiconductor material.

16. A method for improving lumens per watt efficiency of a white light emitting solid state semiconductor light emitting device having a spectral output including emissions in the blue and yellow spectral regions, the method comprising:

passing at least a portion of the blue emission into an optical material to convert at least a portion of the blue spectral emission into one or more emissions in an orange to red spectral region, the optical material comprising quantum confined semiconductor nanocrystals distributed in a light transmissive solid host material, wherein the orange to red spectral region is in a range from about 575 nm to about 650 nm,

wherein the quantum confined semiconductor nanocrystal comprises a Group II-VI compound, a Group II-V compound, a Group III-VI compound, a Group III-V compound, a Group IV-VI compound, a Group I-III-VI compound, a Group II-IV-VI compound, or a Group II-IV-V compound, and

wherein the light emitted by the solid state lighting device has a General Color Rendering Index (Ra) greater than 80.

17. A solid state lighting device, comprising:

a phosphor converted LED light source that emits white light including a blue spectral component and having a deficiency in at least one spectral region and

an optical component that is positioned to receive at least a portion of the white light generated by the light source and supplement the spectrum of the white light passing through the optical component, the optical component comprising an optical material for converting at least a portion of the blue spectral component of the white light to one or more predetermined wavelengths such that light emitted by the solid state lighting device includes white light emission from the light source supplemented with light emission at the one or more predetermined wavelengths in the at least one deficient spectral region of the light source, wherein the optical material comprises quantum confined semiconductor nanocrystals distributed in a light transmissive solid host material and wherein the optical component comprises the optical material sandwiched between two barrier films or coatings,

wherein at least one predetermined wavelength is in a range from about 575 nm to about 650 nm,

wherein the quantum confined semiconductor nanocrystal comprises a Group II-VI compound, Group II-V compound, at Group III-VI compound, a Group III-V compound, a Group IV-VI compound, a Group I-III-VI compound, a Group II-IV-VI compound, or a Group II-IV-V compound, and wherein the light emitted by the solid state lighting device has a General Color Rendering Index (Ra) greater than 80.

18. A solid state lighting device in accordance with claim 17 wherein quantum confined semiconductor nanocrystals are included in the optical material in an amount in a range from about 0.001 to about 5 weight percent of the weight of the host material.

19. A solid state lighting device in accordance with claim 17 wherein the optical material further comprises light scatterers.

20. A solid state lighting device in accordance with claim 19 wherein light scattering particles are included in the optical material in an amount in a range from about 0.001 to about 5 weight percent of the weight of the host material.