Method for producing dialkylaminosilane

• US 10,150,785 B2
• Filed: 01/22/2016
• Issued: 12/11/2018
• Est. Priority Date: 03/24/2015
• Status: Active Grant

• Current Assignee: JNC Corporation (Chisso Corporation)
• Original Assignee: JNC Corporation (Chisso Corporation)
• Inventors: Tanaka, Toru
• Primary Examiner(s): Brooks, Clinton A
• Assistant Examiner(s): Adzamli, Kofi
• Application Number:
  US15/552,804
• Publication Number:
  US 20180044358A1
• Time in Patent Office: 1,054 Days
• Field of Search: None
• CPC Class Codes: C07F 7/025 without C-silicon linkages
• CPC Class Codes: C07F 7/10 containing nitrogen having a Si-N linkage

Abstract

In a method for synthesizing dialkylaminosilane from a reaction of dialkylamine with chlorosilane as the method for producing dialkylaminosilane, a large amount of dialkylamine hydrochloride is produced as a by-product, in addition to objective dialkylaminosilane. Therefore, upon obtaining objective dialkylaminosilane, reduction of volumetric efficiency caused by a large amount of a solvent is prevented, and dialkylaminosilane is produced at a low cost and in a large amount. Dialkylaminosilane having a small halogen content is produced with high volumetric efficiency by using, as a solvent upon allowing dialkylamine to react with chlorosilane, an aprotic polar solvent having high solubility in dialkylamine hydrochloride and metal chloride each produced as a by-product by the reaction, and straight-chain or branched hydrocarbon having high solubility in dialkylaminosilane and hard to dissolve a halogen compound therein.

Claims

1. A method for producing dialkylaminosilane, by allowing dialkylamine to react with chlorosilane in a mixed solvent of an aprotic polar solvent and a solvent of straight-chain or branched hydrocarbon,

wherein the aprotic polar solvent is at least one selected from acetonitrile, dimethylformamide, acetone, dichloromethane, dimethyl sulfoxide, dimethylacetamide and hexamethylphosphoramide.

2. The method for producing dialkylaminosilane according to claim 1, wherein metal is added thereto in a reaction of dialkylamine with chlorosilane.

3. The method for producing dialkylaminosilane according to claim 1, wherein the solvent of straight-chain or branched hydrocarbon is used in an amount of 0.2 to 10 times in weight based on chlorosilane.

4. The method for producing dialkylaminosilane according to claim 1, wherein the aprotic polar solvent is used in an amount of 0.2 to 10 times in weight based on chlorosilane.

5. The method for producing dialkylaminosilane according to claim 1, wherein the dialkylamine is a compound of the following formula:

6. The method for producing dialkylaminosilane according to claim 1, wherein the chlorosilane is a compound of the following formula:

R3_n—

Si-Cl_(4-n)

wherein, R3 is hydrogen, a straight-chain alkyl group having 1 to 6 carbons, a branched alkyl group having 3 to 6 carbons or a phenyl group, and n is an integer from 0 to 3.

7. The method for producing dialkylaminosilane according to claim 1, wherein the aprotic polar solvent is acetonitrile.

8. The method for producing dialkylaminosilane according to claim 1, wherein the solvent of straight-chain or branched hydrocarbon is straight-chain hydrocarbon having 5 to 40 carbons or branched hydrocarbon having 5 to 40 carbons.

9. The method for producing dialkylaminosilane according to claim 2, wherein the metal to be added is at least one selected from magnesium, calcium and zinc.