Packaging method for high gamut white light quantum dot LED

• US 10,153,407 B2
• Filed: 12/20/2016
• Issued: 12/11/2018
• Est. Priority Date: 03/30/2016
• Status: Active Grant

• Current Assignee: Shenzhen Jufei Optoelectronics Co., Ltd.
• Original Assignee: Shenzhen Jufei Optoelectronics Co., Ltd.
• Inventors: Zhang, Zhikuan, Xing, Qibin, Gao, Danpeng, Zhang, Ni
• Primary Examiner(s): Maruf, Sheikh
• Application Number:
  US15/578,518
• Publication Number:
  US 20180158996A1
• Time in Patent Office: 721 Days
• Field of Search: 438 27- 29, 257 98, 257 99
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: C09K 11/08 containing inorganic luminescent materials
• CPC Class Codes: H01L 2933/0041 relating to wavelength conversion elements
• CPC Class Codes: H01L 2933/0083 Periodic patterns for optical field-shaping in or on the semiconductor body or semiconductor body package, e.g. photonic bandgap structures
• CPC Class Codes: H01L 33/50 Wavelength conversion elements
• CPC Class Codes: H01L 33/502 Wavelength conversion materials
• CPC Class Codes: H01L 33/504 Elements with two or more wavelength conversion materials
• CPC Class Codes: H01L 33/52 Encapsulations
• CPC Class Codes: Y02B 20/00 Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
• CPC Class Codes: Y10S 977/774 Exhibiting three-dimensional carrier confinement, e.g. quantum dots
• CPC Class Codes: Y10S 977/95 Electromagnetic energy

Abstract

A packaging method of high color gamut white light quantum dot (QD) light emitting diodes (LEDs). The method includes: a. add an organic solvent to red light QD phosphor powder and blue light QD phosphor powder, respectively; b. perform ultrasonic processing for the solutions; c. prepare a mixed QD solution; d. add mixed packaging glue to the mixed QD solution; e. remove the organic solvent; f. add green light rare earth phosphor powder; g. drip the mixed phosphor glue into an LED stent fixed with ultraviolet chips, and bake and solidify the LED stent to obtain LED beads. The method produces high gamut white light LEDs and greatly improves the color gamut value of LED backlight beads, which reaches above NTSC 92%. With an organic solvent as a connecting bridge, QDs and the packaging glue are mixed uniformly, QD phosphor powder failure resulted from agglomeration is avoided, and quality of high color gamut white light LED beads is significantly improved.

Claims

1. A packaging method of high color gamut white light QD LEDs, the method comprising the following steps:

a. add 50 to 2000 parts by weight of an organic solvent to 1 part by weight of red light QD phosphor powder to obtain a red light QD solution, and add 50 to 1500 parts by weight of an organic solvent to 1 part by weight of blue light QD phosphor powder to obtain a blue light QD solution;

b. perform ultrasonic processing respectively for said red light QD solution and blue light QD solution to obtain clear QD solutions;

c. add 1 to 50 parts by weight of the blue light QD solution to 1 part by weight of the red light QD solution to obtain a mixed QD solution;

d. add 3 to 800 parts by weight of mixed packaging glue to 1 part by weight of the mixed QD solution and mix them well;

e. mix the mixture obtained in step d in vacuum for deaeration to remove the organic solvent from the mixed solution obtained in step d and obtain a uniformly mixed red light and blue light QD phosphor glue;

f. add green light rare earth phosphor powder to said mixed QD phosphor glue according to a mass ratio of 1-50;

1 between the green light rare earth phosphor powder and red light QD phosphor powder, and mix them;

g. drip the mixed phosphor glue obtained in step f into an LED stent fixed with ultraviolet chips, and bake and solidify the LED stent to obtain LED beads.

2. The packaging method of high color gamut white light QD LEDs according to claim 1, wherein said organic solvent is at least one of n-hexane, cyclohexane, n-octane, methylbenzene, dichlorotoluene, dichloromethane, trichlormethane, and pyridine.

3. The packaging method of high color gamut white light QD LEDs according to claim 1, wherein said red light QD phosphor powder and blue light QD phosphor powder are both selected from at least one of BaS, AgInS₂, NaCl, Fe₂O₃, In₂O₃, InAs, InN, InP, CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, GaAs, GaN, GaS, GaSe, InGaAs, MgS, MgSe, MgTe, PbS, PbSe, PbTe, Cd (S_xSe_1-x), BaTiO₃, PbZrO₃, CsPbCl₃, CsPbBr₃, and CsPM₃.

4. The packaging method of high color gamut white light QD LEDs according to claim 3, wherein the grain size of said red light QD phosphor powder and said blue light QD phosphor powder is 1 nm to 10 nm;

the peak wavelength of the light emitted from said red light QD phosphor powder is 600 nm to 660 nm, and the peak wavelength of the light emitted from said blue light QD phosphor powder is 430 nm to 480 nm.

5. The packaging method of high color gamut white light QD LEDs according to claim 4, wherein said mixed packaging glue consists of packaging glue A and packaging glue B at a mass ratio of 1:

1-20, and said packaging glue A and packaging glue B are both one of epoxy packaging glue, organic silicon packaging glue, and polyurethane packaging glue.

6. The packaging method of high color gamut white light QD LEDs according to claim 5, wherein said green light rare earth phosphor powder is selected from one of rare earth element doped silicate, aluminate, phosphate, nitride, and fluoride phosphor powders, the peak wavelength of the light emitted from said green light rare earth phosphor powder is 520 nm to 550 nm, and the peak wavelength of the light emitted from said ultraviolet chips is 230 nm to 395 nm.

7. The packaging method of high color gamut white light QD LEDs according to claim 6, wherein the frequency of the ultrasonic wave is 15 KHz to 120 KHz, the ultrasonic duration is 10 min to 90 min, and the water bath temperature during ultrasonic processing is 25°

C. to 45°

C. in step b;

the baking temperature is 120°

C. to 180°

C., and the baking duration is 0.5 h to 6 h in step g.

8. The packaging method of high color gamut white light QD LEDs according to claim 7, wherein the mixing speed is 120 rpm to 350 rpm and the mixing duration is 5 min to 30 min in step d.

9. The packaging method of high color gamut white light QD LEDs according to claim 8, wherein the pressure in the deaerator during vacuum deaeration mixing is 0 KPa to 0.15 KPa, the mixing speed is 300 rpm to 1200 rpm, the deaeration temperature is 40°

C. to 55°

C., the deaeration duration is 30 min to 150 min in step e.

10. The packaging method of high color gamut white light QD LEDs according to claim 9, wherein the mixture is put into the deaerator and is mixed uniformly after a green light rare earth phosphor powder is added, the pressure in said deaerator is 0 KPa to 1.5 KPa, the mixing speed is 1100 rpm to 2000 rpm, the mixing duration is 3 min to 10 min, and the mixing temperature is 25°

C. to 55°

C. in step f.