Color display device

• US 10,162,242 B2
• Filed: 10/02/2014
• Issued: 12/25/2018
• Est. Priority Date: 10/11/2013
• Status: Active Grant

• Current Assignee: E Ink Holdings Incorporated
• Original Assignee: E Ink California, LLC (E Ink Corporation)
• Inventors: Wang, Ming, Du, Hui, Zang, HongMei, Laxton, Peter
• Primary Examiner(s): Mack, Ricky
• Assistant Examiner(s): O'Neill, Gary
• Application Number:
  US14/505,441
• Publication Number:
  US 20150103394A1
• Time in Patent Office: 1,545 Days
• Field of Search: None
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: G02F 1/1685 Operation of cells; Circuit arrangements affecting the entire cell
• CPC Class Codes: G02F 2001/1678 characterised by the composition or particle type
• CPC Class Codes: G02F 2202/022 polymeric
• CPC Class Codes: G02F 2202/04 dye
• CPC Class Codes: G02F 2202/36 Micro- or nanomaterials

Abstract

The present invention provides a solution for a highlight or multicolor display device, in which each display cell can display high quality color states. More specifically, an electrophoretic fluid is provided which comprises three types of charged particles and a fourth type of particles which is substantially uncharged neutral buoyancy particles, all of which are dispersed in a solvent or solvent mixture.

Claims

1. A display layer comprising an electrophoretic fluid sandwiched between a common electrode and a layer of pixel electrodes and having first and second surfaces on opposed sides thereof, the electrophoretic fluid comprising a first type of particles, a second type of particles, a third type of particles and a fourth type of particles which is substantially uncharged neutral buoyancy particles, all dispersed in a solvent or solvent mixture, the first, second and third types of particles having respectively first, second and third optical characteristics differing from one another, one of the first and second types of particles being white and the other black and the third type of particles being non-white and non-black, the first type of particles having a charge of one polarity and the second and third types of particles having charges of the opposite polarity from the first type of particles, and the second type of particles having an electric field threshold, such that:

(a) application of an electric field between the common electrode and a pixel electrode, which electric field is greater than the electric field threshold and has the same polarity as the second type of particles, causes an area corresponding to the pixel electrode to display the second optical characteristic at the first surface;

(b) application of an electric field between the common electrode and a pixel electrode, which electric field is greater than the electric field threshold and has the same polarity as the first type of particles causes an area corresponding to the pixel electrode to display the first optical characteristic at the first surface;

or

(c) once the first optical characteristic is displayed at the first surface, application of an electric field between the common electrode and a pixel electrode, which electric field is the same as, or lower than, the electric field threshold and having the same polarity as the third type of particles causes an area corresponding to the pixel electrode to display the third optical characteristic at the first surface,

wherein, when the first, second or third optical characteristic is displayed at the first surface, the fourth type of particles remain dispersed in the solvent or solvent mixture, separate from the first, second and third types of particles,

wherein the concentration of the substantially uncharged neutral buoyancy particles in the electrophoretic fluid is in a range of 0.1 to 10% by volume.

2. The layer of claim 1, wherein the substantially uncharged neutral buoyancy particles are formed from a material selected from the group consisting of polyacrylate, polymethacrylate, polystyrene, polyaniline, polypyrrole, polyphenol and polysiloxane.

3. The layer of claim 1, wherein the substantially uncharged neutral buoyancy particles are formed from a material selected from the group consisting of poly(pentabromophenyl methacrylate), poly(2-vinylnapthalene), poly(naphthyl methacrylate), poly(alpha-methylstyrene), poly(N-benzyl methacrylamide) and poly(benzyl methacrylate).

4. The layer of claim 1, wherein the substantially uncharged neutral buoyancy particles are core-shell particles.

5. The layer of claim 1, wherein the concentration of the substantially uncharged neutral buoyancy particles in the electrophoretic fluid is in a range of 0.1 to 5% by volume.

6. The layer of claim 1, which displays the color of the first type of particles, the color of the second type of particles and the color of the third type of particles, but not the color of the fourth type of particles.

7. An electrophoretic fluid comprising a first type of particles, a second type of particles, a third type of particles and a fourth type of particles, all of which are dispersed in a solvent or solvent mixture, wherein

(a) the first type of particles and the second type of particles carry opposite charge polarities, one of the first and second types of particles being black and the other white;

(b) the third type of particles has the same charge polarity as the second type of particles, but at a lower intensity;

(c) the second type of particles has a threshold voltage; and

(d) the fourth type of particles is substantially uncharged neutral buoyancy particles which remain dispersed in the solvent or solvent mixture, separate from the first, second and third types of particles,

wherein the concentration of the substantially uncharged neutral buoyancy particles in the electrophoretic fluid is in a range of 0.1 to 10% by volume.

8. The fluid of claim 7, wherein the substantially uncharged neutral buoyancy particles are formed from a material selected from the group consisting of polyacrylate, polymethacrylate, polystyrene, polyaniline, polypyrrole, polyphenol and polysiloxane.

9. The fluid of claim 7, wherein the substantially uncharged neutral buoyancy particles are formed from a material selected from the group consisting of poly(pentabromophenyl methacrylate), poly(2-vinylnapthalene), poly(naphthyl methacrylate), poly(alpha-methylstyrene), poly(N-benzyl methacrylamide) and poly(benzyl methacrylate).

10. The fluid of claim 7, wherein the substantially uncharged neutral buoyancy particles are core-shell particles.

11. The fluid of claim 7, wherein the concentration of the substantially uncharged neutral buoyancy particles in the electrophoretic fluid is in a range of 0.1 to 5% by volume.

12. A display layer comprising an electrophoretic fluid having first and second surfaces on opposed sides thereof, the electrophoretic fluid comprising a first type of particles, a second type of particles, a third type of particles and a fourth type of particles which is substantially uncharged neutral buoyancy particles, all dispersed in a solvent or solvent mixture, the first, second and third types of particles having respectively first, second and third optical characteristics differing from one another, the first type of particles having a charge of one polarity and the second and third types of particles having charges of the opposite polarity from the first type of particles, and the second type of particles having an electric field threshold, such that:

(a) application of an electric field across the electrophoretic fluid, which electric field is greater than the electric field threshold and has a polarity driving the second type of particles towards the first surface, causes the second optical characteristic to be displayed at the first surface;

(b) application of an electric field across the electrophoretic fluid, which electric field is greater than the electric field threshold and has a polarity driving the first type of particles towards the first surface, causes the first optical characteristic to be displayed at the first surface;

or

(c) once the first optical characteristic is displayed at the first surface, application of an electric field across the electrophoretic fluid, which electric field is the same as, or lower than, the electric field threshold and has a polarity driving the third type of particles towards the first surface, causes the third optical characteristic to be displayed at the first surface, wherein, when the first, second or third optical characteristic is displayed at the first surface, the fourth type of particles remain dispersed in the solvent or solvent mixture, separate from the first, second and third types of particles,

wherein the concentration of the substantially uncharged neutral buoyancy particles in the electrophoretic fluid is in a range of 0.1 to 10% by volume.

13. An electrophoretic fluid comprising a first type of particles, a second type of particles, a third type of particles and a fourth type of particles, all of which are dispersed in a solvent or solvent mixture, the first, second and third types of particles having respectively first, second and third optical characteristics differing from one another, wherein

(a) the first type of particles and the second type of particles carry opposite charge polarities;

(b) the third type of particles has the same charge polarity as the second type of particles, but at a lower intensity;

(c) the second type of particles has a threshold voltage; and

(d) the fourth type of particles is substantially uncharged neutral buoyancy particles which remain dispersed in the solvent or solvent mixture, separate from the first, second and third types of particles,

wherein the concentration of the substantially uncharged neutral buoyancy particles in the electrophoretic fluid is in a range of 0.1 to 10% by volume.