Methods for strengthening the edge of laminated glass articles and laminated glass articles formed therefrom

• US 10,195,825 B2
• Filed: 10/29/2015
• Issued: 02/05/2019
• Est. Priority Date: 10/30/2014
• Status: Active Grant

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Chaparala, Satish Chandra
• Primary Examiner(s): Mulvaney, Elizabeth E
• Application Number:
  US15/521,662
• Publication Number:
  US 20170246841A1
• Time in Patent Office: 1,195 Days
• CPC Class Codes: B24C 1/04 for treating only selected parts of a surface, e.g. for carving stone or glass
• CPC Class Codes: B32B 17/06 comprising glass as the main or only constituent of a layer, next to another layer of a specific material
• CPC Class Codes: B32B 2250/03 3 layers
• CPC Class Codes: B32B 2307/558 Impact strength, toughness
• CPC Class Codes: B32B 2419/00 Buildings or parts thereof walls, panels B32B2607/00
• CPC Class Codes: B32B 2457/12 Photovoltaic modules
• CPC Class Codes: B32B 2457/208 Touch screens
• CPC Class Codes: B32B 2509/00 Household appliances
• CPC Class Codes: B32B 2605/00 Vehicles
• CPC Class Codes: B32B 3/02 characterised by features of form at particular places, e.g. in edge regions non-uniform thickness B32B3/263
• CPC Class Codes: C03B 17/02 Forming molten glass coated with coloured layers; Forming molten glass of different compositions or layers; Forming molten glass comprising reinforcements or inserts
• CPC Class Codes: C03B 17/064 by the overflow downdraw fusion process; Isopipes therefor
• CPC Class Codes: C03B 23/203 Uniting glass sheets C03B23/24 takes precedence
• CPC Class Codes: C03C 13/00 Fibre or filament compositions manufacture of fibres or filaments C03B37/00
• CPC Class Codes: C03C 15/00 Surface treatment of glass, not in the form of fibres or filaments, by etching etching or surface-brightening compositions, in general C09K13/00
• CPC Class Codes: C03C 19/00 Surface treatment of glass, not in the form of fibres or filaments, by mechanical means sand-blasting, grinding, or polishing glass B24
• CPC Class Codes: C03C 2207/00 Compositions specially applicable for the manufacture of vitreous enamels
• CPC Class Codes: C03C 2213/00 Glass fibres or filaments
• CPC Class Codes: C03C 23/0025 by a laser beam
• CPC Class Codes: C03C 23/005 by atoms
• CPC Class Codes: C03C 3/085 : containing an oxide of a divalent metal
• CPC Class Codes: C03C 3/087 : containing calcium oxide, e.g. common sheet or container glass
• CPC Class Codes: C03C 3/091 : containing aluminium
• CPC Class Codes: C03C 3/093 : containing zinc or zirconium
• CPC Class Codes: C03C 8/02 : Frit compositions, i.e. in a powdered or comminuted form

Abstract

A method for strengthening an edge of a glass laminate including a glass core layer positioned between a first glass clad layer and a second glass clad layer may include forming a channel in the edge of the glass laminate. Sidewalls of the channel may be formed from the first glass clad layer and the second glass clad layer. Glass filler material having a filler coefficient of thermal expansion greater than a core coefficient of thermal expansion may be positioned in the channel. The glass filler material and the sidewalls of the channel may be fused to the second glass clad layer thereby forming an edge cap over the channel. The edge of the glass laminate is under compressive stress after the glass filler material is enclosed in the channel.

Claims

1. A method for strengthening an edge of a glass laminate, the method comprising:

positioning a glass filler material in a channel in the edge of the glass laminate, the glass laminate comprising a glass core layer positioned between a first glass clad layer and a second glass clad layer, sidewalls of the channel being formed from at least a portion of the first glass clad layer and at least a portion of the second glass clad layer, the glass filler material having a filler coefficient of thermal expansion CTE_F that is greater than a core coefficient of thermal expansion CTE_C of the glass core layer;

heating the glass filler material and the sidewalls of the channel to a temperature greater than or equal to a softening temperature of the glass filler material and greater than or equal to a softening temperature of the sidewalls; and

enclosing the glass filler material in the channel by joining the sidewalls and fusing at least a portion of the first glass clad layer to at least a portion of the second glass clad layer thereby forming an edge cap over the channel, wherein the edge cap is under compressive stress.

2. The method of claim 1, further comprising forming the channel in the edge of the glass laminate prior to positioning the glass filler material in the channel.

3. The method of claim 1, wherein the glass filler material is enclosed in the channel by overlapping at least a portion of the first glass clad layer with at least a portion of the second glass clad layer.

4. The method of claim 1, wherein a maximum thickness of the edge cap is greater than a maximum thickness of either the first glass clad layer or the second glass clad layer.

5. The method of claim 1, wherein the glass filler material comprises a glass fiber.

6. The method of claim 1, wherein the glass filler material comprises a glass frit.

7. The method of claim 1, wherein the first glass clad layer and the second glass clad layer have a clad coefficient of thermal expansion CTE_CL and CTE_F>

CTE_C>

CTE_CL.

8. The method of claim 1, wherein heating the glass filler material and the sidewalls of the channel comprises directing a laser beam onto the glass filler material positioned in the channel.

9. The method of claim 1, wherein heating the glass filler material and the sidewalls of the channel comprises directing a first laser beam onto a surface of the first glass clad layer adjacent to the channel and directing a second laser beam onto a surface of the second glass clad layer adjacent to the channel.

10. A laminated glass article comprising:

a glass core layer having a core coefficient of thermal expansion CTE_C;

a first glass clad layer fused directly to a first surface of the glass core layer;

a second glass clad layer fused directly to a second surface of the glass core layer opposite the first surface, the first glass clad layer and the second glass clad layer fused to one another adjacent an edge of the glass core layer forming an edge cap that encloses at least a portion of the edge of the glass core layer; and

a glass filler material having a filler coefficient of thermal expansion CTE_F and positioned between the edge of the glass core layer and the edge cap, the glass filler material fused to the glass core layer and the edge cap, wherein CTE_F>

CTE_C.

11. The laminated glass article of claim 10, wherein the first glass clad layer and the second glass clad layer have a clad coefficient of thermal expansion CTE_CL and CTE_F>

CTE_C>

CTE_CL.

12. The laminated glass article of claim 10, wherein the edge cap is formed by an overlap of the first glass clad layer and the second glass clad layer.

13. The laminated glass article of claim 10, wherein a maximum thickness of the edge cap is greater than a maximum thickness of either the first glass clad layer or the second glass clad layer.

14. The laminated glass article of claim 10, wherein the glass filler material comprises a glass fiber.

15. The laminated glass article of claim 10, wherein the glass filler material comprises a glass frit.

16. The laminated glass article of claim 10, wherein the glass core layer has a region of compressive stress extending from an interface of the glass core layer with the glass filler material into a bulk of the glass core layer.

17. The laminated glass article of claim 10, wherein the edge cap has a region of compressive stress extending through a thickness of the edge cap.

18. Use of the laminated glass article of claim 10 for cover glass or glass backplane applications in consumer or commercial electronic devices, touch screen or touch sensor applications, integrated circuit applications, photovoltaic applications, architectural glass applications, automotive or vehicular glass applications, commercial or household appliance applications, lighting or signage applications, or transportation applications.