High temperature lightweight thermal insulating cement and silica based materials

• US 10,196,309 B2
• Filed: 10/16/2014
• Issued: 02/05/2019
• Est. Priority Date: 10/17/2013
• Status: Active Grant

• Current Assignee: The Intellectual Gorilla GmbH
• Original Assignee: The Intellectual Gorilla GmbH
• Inventors: Andersen, Per Just, Daniels, Evan R.
• Primary Examiner(s): Koslow, C Melissa
• Application Number:
  US15/029,416
• Publication Number:
  US 20170152181A1
• Time in Patent Office: 1,573 Days
• CPC Class Codes: C04B 14/06 Quartz; Sand
• CPC Class Codes: C04B 14/42 Glass
• CPC Class Codes: C04B 16/02 Cellulosic materials cellulosic waste materials, e.g. sawdust, rice husks, C04B18/24
• CPC Class Codes: C04B 16/0633 Polypropylene
• CPC Class Codes: C04B 16/0641 Polyvinylalcohols; Polyvinylacetates
• CPC Class Codes: C04B 18/08 Flue dust , i.e. fly ash
• CPC Class Codes: C04B 18/141 Slags
• CPC Class Codes: C04B 18/146 Silica fume
• CPC Class Codes: C04B 18/24 Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper , cork
• CPC Class Codes: C04B 2103/0079 Rheology influencing agents
• CPC Class Codes: C04B 2103/408 Dispersants
• CPC Class Codes: C04B 2103/48 Foam stabilisers
• CPC Class Codes: C04B 2111/00431 Refractory materials
• CPC Class Codes: C04B 2111/28 Fire resistance, i.e. materials resistant to accidental fires or high temperatures
• CPC Class Codes: C04B 2111/40 Porous or lightweight materials
• CPC Class Codes: C04B 22/04 Metals, e.g. aluminium used as blowing agent
• CPC Class Codes: C04B 22/064 of the alkaline-earth metals
• CPC Class Codes: C04B 2201/20 for the density
• CPC Class Codes: C04B 2201/30 for heat transfer properties such as thermal insulation values, e.g. R-values
• CPC Class Codes: C04B 2201/32 for the thermal conductivity, e.g. K-factors
• CPC Class Codes: C04B 24/38 : Polysaccharides or derivatives thereof C04B24/243 takes precedence
• CPC Class Codes: C04B 24/383 : Cellulose or derivatives thereof
• CPC Class Codes: C04B 28/04 : Portland cements
• CPC Class Codes: C04B 28/06 : Aluminous cements monolithic refractories or refractory mortars C04B35/66
• CPC Class Codes: C04B 28/18 : containing mixtures of the silica-lime type
• CPC Class Codes: C04B 38/02 : by adding chemical blowing agents
• CPC Class Codes: C04B 38/10 : by using foaming agents C04B38/02 takes precedenceor by using mechanical means, e.g. adding preformed foam
• CPC Class Codes: Y02W 30/91 : Use of waste materials as fillers for mortars or concrete

Abstract

A high temperature lightweight thermal insulating material is formed from a mixture that includes cement or silica sand, water and a foaming agent. The foaming agent can be an aluminum powder or a surfactant. The insulating material has a maximum use temperature greater than about 600 degrees Celsius.

Claims

1. An insulating material formed from a mixture comprising:

a silica sand in an amount of 25 to 90% of weight wet;

water in an amount of 10 to 70% of weight wet;

a rheology-modifying agent in an amount of about 0.1 to 5.0% of a weight of the silica sand;

a pH increasing material in an amount of about 0.5 to 10% by weight of the water;

a foaming agent comprising an aluminum powder in an amount of 0.5% to 3.0% by weight of the silica sand or a surfactant in an amount of 0.05 to 2.0% by weight of the water; and

the insulating material having a maximum use temperature in a range of about 600 to 1000 degrees Celsius.

2. The insulating material as recited in claim 1, the insulating material having:

a density in a range of about 0.1 to 1.0 g/cm³;

a thermal conductivity in a range of about 0.05 to 0.30 W/(m·

K); and

a compressive strength in a range of about 30 to 3000 PSI (2.068 to 206.8 Bar).

3. The insulating material as recited in claim 1, the mixture having a water to silica sand ratio by weight in the range of about 0.2 to 2.0.

4. The insulating material as recited in claim 1, the mixture having a water to silica sand ratio by weight of about 1.0.

5. The insulating material as recited in claim 1, further comprising a high range water reducer (HRWR) in an amount of about 0.25 to 4.0% of a weight of the silica sand.

6. The insulating material as recited in claim 1, the mixture further comprising an additive material selected from the group consisting of cement, gypsum, silica fume, fumed silica, plaster of Paris, fly ash, slag, rock and fiber.

7. The insulating material as recited in claim 6, the fiber comprising glass fibers, cellulose fibers, polyvinyl alcohol fibers, polypropylene fibers, or a combination thereof.

8. A method for manufacturing an insulating material comprising the steps of:

mixing a silica sand in an amount of about 25 to 90% of weight wet with water in an amount of about 10 to 70% of weight wet;

mixing a pH increasing material in an amount of about 0.5 to 10% by weight of the water with the sand-water mixture;

foaming the sand-water mixture using a foaming agent comprising an aluminum powder in an amount of about 0.5 to 3.0% by weight of the silica sand, or a surfactant in an amount of about 0.05 to 2.0% by weight of the water;

pouring the foamed sand-water mixture into a mold and allowing the foamed sand-water mixture to rise to form the insulating material;

removing the insulating material from the mold;

heat treating the insulating material; and

the insulating material having a maximum use temperature of about 600 to 1000 degrees Celsius.

9. The method as recited in claim 8, further comprising the step of grinding the silica sand-water mixture to a fineless less than 100 microns using a ball mill prior to mixing the pH increasing material.

10. The method as recited in claim 8, wherein:

the mixing step is performed for about 1 to 5 minutes;

the foaming step is performed for about 5 seconds to 1 minute; and

the foamed sand-water mixture is allowed to rise for about 0.5 to 2.0 hours.

11. The method as recited in claim 8, the heat treating step comprises the step of autoclaving the insulating material for about 15-48 hours at a temperature of about 150 to 200 degrees Celsius and a pressure of about 10 to 20 Bars.

12. The method as recited in claim 8, further comprising the step of drying the insulating material.

13. The method as recited in claim 8, further comprising the step of cutting, trimming, sanding or routing the insulating material into a specified shape comprising a pipe, a half-pipe, a block or a panel.

14. The method as recited in claim 8, further comprising the step of spraying the insulating material with a water repellent comprising a water or solvent based silane.

15. The method as recited in claim 8, the insulating material having:

a density in the range of about 0.1 to 1.0 g/cm³;

a thermal conductivity in the range of about 0.05 to 0.30 W/(m·

K); and

a compressive strength in the range of about 30 to 3000 PSI (2.068 to 206.8 Bar).

16. The method as recited in claim 8, the mixture having a water to sand ratio by weight in the range of about 0.2 to 2.0.

17. The method as recited in claim 8, the mixture having a water to sand ratio by weight of about 1.0.

18. The method as recited in claim 8, further comprising a dispersion agent in an amount of about 0.25 to 4.0% of a weight of the sand.

19. The method as recited in claim 8, the mixture further comprising an additive material selected from the group consisting of cement, gypsum, silica fume, fumed silica, plaster of Paris, fly ash, slag, rock and fiber.

20. The method as recited in claim 19, the fiber comprising glass fibers, cellulose fibers, polyvinyl alcohol fibers, polypropylene fibers, or a combination thereof.

21. The method as recited in claim 8, the mixture further comprising a rheology-modifying agent in an amount of about 0.1 to 5.0% of a weight of the sand.

22. A method for manufacturing an insulating material comprising the steps of:

mixing a silica sand in an amount of about 25 to 90% of weight wet with water in an amount of about 10 to 70% of weight wet for about 1 to 5 minutes;

mixing a pH increasing material in an amount of about 0.5 to 10% by weight of the water with the sand-water mixture for about 1 to 5 minutes;

foaming the sand-water mixture using a foaming agent comprising an aluminum powder in an amount of about 0.5 to 3.0% by weight of the sand for about 5 seconds to a minute, or a surfactant in an amount of about 0.05 to 2.0% by weight of the water for about 1 to 10 minutes;

pouring the foamed sand-water mixture into a mold and allowing the foamed sand-water mixture to rise to form the insulating material;

removing the insulating material from the mold;

heat treating the insulating material; and

the insulating material having a maximum use temperature of about 600 to 1000 degrees Celsius, a density in the range of about 0.1 to 1.0 g/cm³, a thermal conductivity in the range of about 0.05 to 0.30 W/(m·

K), and a compressive strength in the range of about 30 to 3000 PSI (2.068 to 206.8 Bar).