Methods and compositions for stimulating the production of hydrocarbons from subterranean formations

• US 10,196,557 B2
• Filed: 03/16/2016
• Issued: 02/05/2019
• Est. Priority Date: 06/14/2013
• Status: Active Grant

• Current Assignee: Flotek Industries Incorporated
• Original Assignee: Flotek Industries Incorporated
• Inventors: Hill, Randal M., Champagne, Lakia M., Lett, Nathan L., Dismuke, Keith Ingram, Germack, David, Mast, Nicole, Soeung, Melinda
• Primary Examiner(s): Bates, Zakiya W
• Application Number:
  US15/071,332
• Publication Number:
  US 20160194550A1
• Time in Patent Office: 1,056 Days
• CPC Class Codes: C09K 8/26 Oil-in-water emulsions
• CPC Class Codes: C09K 8/40 Spacer compositions, e.g. compositions used to separate well-drilling from cementing masses
• CPC Class Codes: C09K 8/602 containing surfactants
• CPC Class Codes: C09K 8/68 containing organic compounds
• CPC Class Codes: C09K 8/70 characterised by their form or by the form of their components, e.g. foams
• CPC Class Codes: C09K 8/72 Eroding chemicals, e.g. acids
• CPC Class Codes: C09K 8/86 containing organic compounds
• CPC Class Codes: C09K 8/90 of natural origin, e.g. polysaccharides, cellulose
• CPC Class Codes: E21B 43/27 by use of eroding chemicals, e.g. acids

Abstract

Methods for treating an oil well having a wellbore. The methods involve injecting a microemulsion into the wellbore to increase formation crude oil production by the well. The microemulsion comprises water, a first type of solvent and a first type of surfactant. The microemulsion includes a continuous water phase.

Claims

1. A method of treating an oil well having a wellbore, comprising:

injecting a microemulsion into the wellbore to increase formation crude oil production by the well, wherein the microemulsion comprises water, a first type of solvent, and a first type of surfactant, wherein the microemulsion includes a continuous water phase,

wherein the first type of solvent is selected from the group consisting of unsubstituted cyclic or acyclic, branched or unbranched alkanes having 6-12 carbon atoms, unsubstituted acyclic branched or unbranched alkenes having one or two double bonds and 6-12 carbon atoms, cyclic or acyclic, branched or unbranched alkanes having 9-12 carbon atoms and substituted with only an —

OH group, branched or unbranched dialkylether compounds having the formula C_nH_2n+1OC_mH_2m+1, wherein n+m is between 6 and 16, and aromatic solvents having a boiling point between about 300-400°

F.

2. The method of claim 1, wherein the ratio of water to solvent is between about 15:

1 and 1;

10.

3. The method of claim 1, wherein the microemulsion further comprises a second type of solvent.

4. The method of claim 1, wherein the microemulsion is diluted with an aqueous fluid prior to injection to the wellbore.

5. The method of claim 4, wherein the microemulsion is diluted to between about 0.1 wt % and about 2 wt %.

6. The method of claim 4, wherein the microemulsion is diluted with an aqueous fluid selected from the group consisting of water, brine and a well-treatment fluid.

7. The method of claim 6, wherein the well-treatment fluid is selected from the group consisting of an acid, a fracturing fluid and slickwater.

8. The method of claim 1, wherein the microemulsion further comprises a freezing point depression agent.

9. The method of claim 8, wherein the microemulsion comprises a first type of freezing point depression agent and a second type of freezing point depression agent.

10. The method of claim 8, wherein the freezing point depression agent is selected from the group consisting of an alkylene glycol, an alcohol, a combination of choline chloride and urea, and a salt.

11. The method of claim 8, wherein the freezing point depression agent is present in an amount between about 5 wt % and about 40 wt %.

12. The method of claim 1, wherein the surfactant is an alkyl polyglycol or alkyl polyglucoside nonionic surfactant.

13. The method of claim 1, wherein the microemulsion further comprises a second type of surfactant.

14. The method of claim 13, wherein the first type of surfactant is an alkyl polyglycol or alkyl polyglucoside nonionic surfactant and the second type of surfactant is an anionic, cationic, or zwitterionic surfactant.

15. The method of claim 1, wherein the first type of surfactant is present in an amount between about 15 wt % and 55 wt %.