Process for producing a fuel from lignocellulosic feedstock

• US 10,202,312 B2
• Filed: 03/01/2016
• Issued: 02/12/2019
• Est. Priority Date: 03/05/2012
• Status: Active Grant

• Current Assignee: Iogen Energy Corporation (Iogen Corporation)
• Original Assignee: Iogen Energy Corporation (Iogen Corporation)
• Inventors: Foody, Patrick J., Glenns, Robert
• Primary Examiner(s): Langel, Wayne A
• Application Number:
  US15/057,644
• Publication Number:
  US 20160176767A1
• Time in Patent Office: 1,078 Days
• CPC Class Codes: C05C 11/00 Other nitrogenous fertilisers
• CPC Class Codes: C05C 3/00 Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
• CPC Class Codes: C05D 9/00 Other inorganic fertilisers
• CPC Class Codes: C05D 9/02 containing trace elements
• CPC Class Codes: C05F 5/008 Waste from biochemical processing of material, e.g. fermentation, breweries
• CPC Class Codes: C05G 1/00 Mixtures of fertilisers belonging individually to different subclasses of C05
• CPC Class Codes: C05G 3/80 Soil conditioners
• CPC Class Codes: C09K 17/40 containing mixtures of inorganic and organic compounds
• CPC Class Codes: C12F 3/10 from distillery slops
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: C13K 13/002 Xylose
• CPC Class Codes: Y02A 40/20 Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02P 20/145 the feedstock being materials of biological origin

Abstract

The present invention relates to a method for producing a composition for use in land application. The method comprises: (a) obtaining a fermentation product by a production process comprising the steps of: (i) treating lignocellulosic feedstock to produce sugar; (ii) fermenting the sugar to produce a fermented mixture comprising the fermentation product; and (iii) recovering the fermentation product from the fermented mixture in one or more stages to produce a concentrated fermentation product and still bottoms; and

(b) recovering the still bottoms, the still bottoms comprising organic and inorganic components; and (c) providing the still bottoms for use in a land application. Also provided is a soil conditioning composition for use in land application. The soil conditioning composition contains still bottoms and optionally other components.

Claims

1. A process for producing a fuel from lignocellulosic feedstock, said fuel comprising ethanol, said process comprising:

(i) treating the lignocellulosic feedstock to produce sugar;

(ii) fermenting the sugar to produce a fermented mixture comprising the ethanol;

(iii) recovering the ethanol from the fermented mixture in one or more stages to produce a concentrated ethanol and still bottoms;

(iv) recovering the still bottoms, said still bottoms comprising an organic component and an inorganic component; and

(v) applying the still bottoms comprising the organic component and the inorganic component to land as a soil conditioner,

wherein applying the still bottoms to the land returns at least one member selected from the group consisting of organic matter and nutrients back to the land.

2. The process of claim 1, wherein the still bottoms applied to land as a soil conditioner comprises 40-80 wt % organic components and 20-60 wt % inorganic components on a dry basis.

3. The process of claim 1, wherein the inorganic components originate from the lignocellulosic feedstock, process chemicals added during said process, or a combination thereof.

4. The process of claim 1, wherein the inorganic components originate from both the lignocellulosic feedstock and process chemicals added during said process.

5. The process of claim 1, wherein the step of recovering the still bottoms comprises concentrating the still bottoms.

6. The process of claim 1, wherein the organic component comprises dissolved lignin, insoluble lignin or a combination thereof.

7. The process of claim 1, wherein the still bottoms has a phosphorus content of less than 2 wt % on a dry basis.

8. The process of claim 1, wherein the still bottoms has a solids content that allows it to be pumped through farming equipment.

9. The process of claim 1, wherein the step of recovering the still bottoms comprises separating solids from the still bottoms, thereby producing a residue stream composed of separated solids and a liquid component and wherein the separated solids and the liquid component are each provided for use in soil conditioning.

10. The process of claim 1, wherein the step of treating comprises pretreating the lignocellulosic feedstock with acid or alkali to produce a composition comprising cellulose and hydrolyzing at least a portion of the cellulose to glucose with enzymes.

11. The process of claim 1, comprising adding insoluble lignin to the still bottoms prior to step (v).

12. The process of claim 1, wherein said ethanol is characterized by a sustainability improvement provided by using less chemical fertilizer to restore nutrient levels to the land, said sustainability improvement being relative to a process wherein nutrients are returned back to the land by chemical fertilizers.

13. The process of claim 1, wherein said ethanol is characterized by a greenhouse gas emissions reduction associated with using less chemical fertilizer to restore nutrient levels to the land.

14. The process of claim 1, wherein said ethanol is characterized by a greenhouse gas emissions reduction associated with applying the still bottoms to the land.

15. A process for producing a fuel from lignocellulosic feedstock, said fuel comprising ethanol, said process comprising:

(i) treating the lignocellulosic feedstock to produce sugar;

(ii) fermenting the sugar to produce a fermented mixture comprising the ethanol;

(iii) recovering the ethanol from the fermented mixture in one or more stages to produce concentrated ethanol and still bottoms;

(iv) recovering the still bottoms, said recovered still bottoms comprising 40-80 wt % organic component and 20-60 wt % inorganic component, said organic component comprising at least soluble lignin, said inorganic component comprising at least nitrogen and sulfur; and

(v) applying the still bottoms comprising the organic component and the inorganic component to land as a soil conditioner,

wherein the life cycle greenhouse gas emissions of the ethanol is reduced relative to life cycle greenhouse gas emissions of ethanol produced by an otherwise identical fuel production process that does not apply the still bottoms to land as a soil conditioner, and

wherein said reduction is at least in part a result of step (v).

16. The process of claim 15, wherein the organic component further comprises sugar, insoluble lignin, or a combination thereof.

17. The process of claim 15, wherein the inorganic component further comprises potassium, chloride, magnesium, calcium or a combination thereof.

18. The process of claim 15, wherein the phosphorus content is less than about 2 wt % on a dry basis.

19. The process of claim 15, wherein the water content is between about 10 and about 90 wt %.

20. The process of claim 15, wherein the water content is between about 20 and about 50 wt %.

21. A process for producing a fuel from lignocellulosic feedstock, said fuel comprising ethanol, said process comprising:

(i) treating the lignocellulosic feedstock to produce sugar;

(ii) fermenting the sugar to produce a fermented mixture comprising ethanol;

(iii) recovering the ethanol from the fermented mixture in one or more stages to produce recovered ethanol and still bottoms;

(iv) recovering the still bottoms, said recovered still bottoms comprising 40-80 wt % organic component and 20-60 wt % inorganic component, said organic component comprising at least soluble lignin, said inorganic component comprising at least nitrogen and sulfur; and

(v) conditioning soil by applying the still bottoms comprising the organic component and the inorganic component to land,

wherein the life cycle greenhouse gas emissions of the ethanol is reduced relative to life cycle greenhouse gas emissions of ethanol produced by an otherwise identical fuel production process that includes disposing of the still bottoms by incineration rather than applying the still bottoms to land.