Photoelectrolysis system and method

• US 10,202,695 B2
• Filed: 05/21/2015
• Issued: 02/12/2019
• Est. Priority Date: 05/21/2015
• Status: Active Grant

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Palo Alto Research Center, Inc. (Xerox Holdings Corp.)
• Inventors: Schwartz, David E.
• Primary Examiner(s): Smith, Nicholas A
• Assistant Examiner(s): Raphael, Colleen M
• Application Number:
  US14/718,946
• Publication Number:
  US 20160340789A1
• Time in Patent Office: 1,363 Days
• Field of Search: 205340
• CPC Class Codes: C25B 1/04 by electrolysis of water
• CPC Class Codes: C25B 1/55 Photoelectrolysis
• CPC Class Codes: C25B 9/17 Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
• CPC Class Codes: C25B 9/19 with diaphragms
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02P 20/133 Renewable energy sources, e.g. sunlight

Abstract

A photoelectrolysis system includes at least one photoelectrochemical (PEC) cell having at least one photoanode and at least one photocathode. A light concentrator provides concentrated light to PEC cell. The PEC cell electrolyzes the electrolyte into H₂ and O₂ in response to excitons generated by the concentrated light on the PEC cell. An electrolyte flow apparatus moves the electrolyte over surfaces of one or both of the photoanode and the photocathode at a flow rate that is based on one or more characteristics of the photoelectrolysis.

Claims

1. A system capable of photoelectrolysis comprising:

at least one photoelectrochemical (PEC) cell the PEC cell comprising;

a photoanode; and

a photocathode;

a concentrator configured to provide concentrated light to PEC cell;

an electrolyte, the PEC cell configured to electrolyze the electrolyte into H₂ and O₂ in response to excitons generated by the concentrated light on the PEC cell; and

an electrolyte movement apparatus configured to pressurize the electrolyte above an atmospheric pressure, the electrolyte movement apparatus including;

a pump configured to move the electrolyte over surfaces of one or both of the photoanode and the photocathode;

a feedback component configured to measure one or more characteristics of the photoelectrolysis and to generate a feedback signal based on the characteristics, the characteristics including at least a portion of surface area of at least one of the photoanode and the photocathode that is covered by bubbles; and

a controller configured to control a flow rate produced by the pump based on the feedback signal.

2. The system of claim 1, wherein the electrolyte movement apparatus is configured to move the electrolyte at a predetermined flow rate that is based on expected characteristics of the photoelectrolysis.

3. The system of claim 1, wherein the one or more characteristics comprise one or more of, concentration of bubbles in a volume of the electrolyte, electrolyte pressure, heat generated by the PEC cell, light intensity, concentrator power, and gas generation rate.

4. The system of claim 1, wherein at least one of the photoanode and photocathode includes a protective coating.

5. The system of claim 1, wherein at least one of the photoanode and the photocathode includes a catalyst.

6. The device of claim 1, wherein the electrolyte comprises water.

7. The device of claim 1, wherein the electrolyte flow apparatus is further configured to pressurize the electrolyte to at least 30 atm.

8. The device of claim 1, wherein the concentrator power is greater than about 50×

.

9. The device of claim 1, wherein the concentrator power is between about 50×

and about 500×

.

10. The device of claim 1, further comprising an optical filter or coating configured to reduce incidence of some wavelengths of the light on the PEC cell.

11. The device of claim 1, wherein the concentrated light passes through the electrolyte to reach the PEC cell.

12. The device of claim 1, further comprising a tracking apparatus configured to track a position of the sun.

13. The device of claim 1, wherein the pump is configured to move the electrolyte at a flow rate that maintains temperature of the PEC cell below about 320 degrees Kelvin.

14. The device of claim 1, wherein the at least one PEC cell comprises multiple individual PEC cells.

15. The device of claim 14, wherein the multiple individual PEC cells are connected to operate in parallel.

16. The device of claim 1, wherein the flow rate is configured to provide substantially no bubbles in an optical path between the concentrator and the PEC cell.

17. The device of claim 1, wherein the flow rate is configured to provide accessibility of a majority of a surface area of the electrode surface to the electrolyte during operation of the PEC cell.

18. The device of claim 1, further comprising a membrane that separates the photoanode from the photocathode.

19. The apparatus of claim 1, wherein the pump is configured to pressurize the electrolyte above the atmospheric pressure and to move the pressurized electrolyte over the surfaces of one or both of the photoanode and the photocathode.

20. The apparatus of claim 1, further comprising a pressurizing pump configured to pressurize the electrolyte above an atmospheric pressure, wherein the pump is a flow pump and the flow pump is configured to move the pressurized electrolyte over the surfaces of one or both of the photoanode and the photocathode.

21. The apparatus of claim 1, wherein the feedback component includes an optical sensor configured to measure an amount of light reflected from or near a surface of the PEC cell, the amount of light indicative of an amount of bubbles at the photoanode and/or photocathode, the sensor configured to generate the feedback signal based on the measured amount of light.

22. A method providing photoelectrolysis, comprising:

concentrating light onto a photoelectrochemical (PEC) cell comprising a photoanode and a photocathode;

generating excitons in the PEC cell in response to the concentrated light;

pressurizing an electrolyte to a pressure above an atmospheric pressure;

electrolyzing the electrolyte into hydrogen and oxygen at surfaces of one or both of the photoanode and photocathode using the excitons; and

flowing the electrolyte over the surfaces of one or-both of the photoanode and the photocathode at a flow rate;

measuring one or more characteristics of the photoelectrolysis, the characteristics comprising a portion of surface area of at least one of the photoanode and the photocathode that is covered by bubbles;

generating a feedback signal based on the measured characteristics; and

controlling the flow rate using the feedback signal.

23. The method of claim 22, wherein flowing the electrolyte comprises moving the electrolyte at a predetermined flow rate that is based on expected characteristics of the photoelectrolysis.

24. The method of claim 22, wherein the one or more characteristics comprise one or more of concentration of bubbles in a volume of the electrolyte, electrolyte pressure, heat generated by the PEC cell, light intensity, concentrator power, and gas generation rate.

25. The method of claim 22, wherein measuring the portion of the surface area comprises measuring an amount of light reflected from or near a surface of the PEC cell, the amount of reflected light indicative of an amount of bubbles at the photoanode and/or photocathode.