Complex stress-engineered frangible structures

• US 10,202,990 B2
• Filed: 07/02/2018
• Issued: 02/12/2019
• Est. Priority Date: 04/06/2016
• Status: Active Grant

• Current Assignee: SRI International, Inc.
• Original Assignee: Palo Alto Research Center, Inc. (Xerox Holdings Corp.)
• Inventors: Limb, Scott J. H., Whiting, Gregory L.
• Primary Examiner(s): Wiley, Daniel J
• Application Number:
  US16/025,573
• Publication Number:
  US 20180306218A1
• Time in Patent Office: 225 Days
• CPC Class Codes: B32B 17/00 Layered products essentially comprising sheet glass, or glass, slag, or like fibres
• CPC Class Codes: B32B 17/10137 Chemical strengthening
• CPC Class Codes: C03B 23/20 Uniting glass pieces by fusing without substantial reshaping
• CPC Class Codes: C03B 23/203 Uniting glass sheets C03B23/24 takes precedence
• CPC Class Codes: C03B 27/00 Tempering or quenching glass products
• CPC Class Codes: C03C 15/00 Surface treatment of glass, not in the form of fibres or filaments, by etching etching or surface-brightening compositions, in general C09K13/00
• CPC Class Codes: C03C 21/00 Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
• CPC Class Codes: C03C 21/001 in liquid phase, e.g. molten salts, solutions
• CPC Class Codes: C03C 21/002 to perform ion-exchange between alkali ions C03C21/005 takes precedence
• CPC Class Codes: C03C 27/044 of glass, glass-ceramic or ceramic material only
• CPC Class Codes: C03C 27/06 Joining glass to glass by processes other than fusing fusing C03B23/20; units for use as elements for closing wall or like openings and comprising two or more parallel glass panes in spaced relationship, the panes being permanently secured together E06B3/66
• CPC Class Codes: C03C 27/10 with the aid of adhesive specially adapted for that purpose
• CPC Class Codes: F16B 1/00 Devices for securing together, or preventing relative movement between, constructional elements or machine parts

Abstract

A stress-engineered frangible structure includes multiple discrete glass members interconnected by inter-structure bonds to form a complex structural shape. Each glass member includes strengthened (i.e., by way of stress-engineering) glass material portions that are configured to transmit propagating fracture forces throughout the glass member. Each inter-structure bond includes a bonding member (e.g., glass-frit or adhesive) connected to weaker (e.g., untreated, unstrengthened, etched, or thinner) glass member region(s) disposed on one or both interconnected glass members that function to reliably transfer propagating fracture forces from one glass member to other glass member. An optional trigger mechanism generates an initial fracture force in a first (most-upstream) glass member, and the resulting propagating fracture forces are transferred by way of inter-structure bonds to all downstream glass members. One-way crack propagation is achieved by providing a weaker member region only on the downstream side of each inter-structure bond.

Claims

1. A stress-engineered frangible structure, comprising:

a plurality of interconnected discrete glass members including a first glass member and a second glass member, at least one of the first and second glass members having a curved shape, each of the glass members including at least one strengthened glass portion comprising a stress-engineered glass material; and

an inter-structure bond connected between the first glass member and the second glass member, the inter-structure bond comprising a bonding member connected between first surface regions of the first and second glass members such that the bonding member is connected to at least one weaker member region disposed in at least one of the first and second glass members, the at least one weaker member region comprising a structurally weaker glass material than the stress-engineered glass material of the at least one strengthened glass portions;

wherein the bonding member and the at least one weaker member region are configured to generate a transfer fracture force in response to a first propagating fracture force, the transfer fracture force being directed from the first glass member to the second glass member and having sufficient energy such that secondary propagating fracture forces are generated in the at least one strengthened glass portion of the second glass member.

2. The stress-engineered frangible structure of claim 1, wherein the first and second glass members have the curved shape.

3. The stress-engineered frangible structure of claim 1, wherein the at least one of the first and second glass members has a rod shape.

4. The stress-engineered frangible structure of claim 1, wherein the at least one of the first and second glass members has a pole shape.

5. The stress-engineered frangible structure of claim 1, wherein the at least one of the first and second glass members has a tub shape.

6. The stress-engineered frangible structure of claim 1, wherein the at least one of the first and second glass members has a spherical shape.

7. The stress-engineered frangible structure of claim 1, further comprising a trigger mechanism operably attached to the first glass member, the trigger mechanism configured to generate an initial fracture force sufficient to cause the first propagating fracture force in the at least one strengthened portion of the first glass member.

8. The stress-engineered frangible structure of claim 7, further comprising a sensor configured to detect a predetermined transmitted signal, and configured to generate a trigger signal in response to detection of the predetermined transmitted signal, wherein the trigger mechanism is configured to generate the initial fracture force in response to the trigger signal.

9. A stress-engineered frangible structure, comprising:

a plurality of interconnected discrete glass members including a first glass member and a second glass member, each of the glass members including at least one strengthened glass portion comprising a stress-engineered glass material, the interconnected glass members collectively forming a curved frangible structure; and

an inter-structure bond connected between the first glass member and the second glass member, the inter-structure bond comprising a bonding member connected between first surface regions of the first and second glass members such that the bonding member is connected to at least one weaker member region disposed in at least one of the first and second glass members, the at least one weaker member region comprising a structurally weaker glass material than the stress-engineered glass material of the at least one strengthened glass portions;

wherein the bonding member and the at least one weaker member region are configured to generate a transfer fracture force in response to a first propagating fracture force, the transfer fracture force being directed from the first glass member to the second glass member and having sufficient energy such that secondary propagating fracture forces are generated in the at least one strengthened glass portion of the second glass member.

10. The stress-engineered frangible structure of claim 9, wherein one of the first and second glass members has a planar shape.

11. The stress-engineered frangible structure of claim 9, wherein the first and second glass members have a planar shape.

12. The stress-engineered frangible structure of claim 9, wherein one of the first and second glass members has a curved shape.

13. The stress-engineered frangible structure of claim 9, wherein the first and second glass members have a curved shape.

14. The stress-engineered frangible structure of claim 9, wherein at least one of the first and second glass members has a rod or pole shape.

15. The stress-engineered frangible structure of claim 9, wherein at least one of the first and second glass members has a tub shape.

16. The stress-engineered frangible structure of claim 9, wherein at least one of the first and second glass members has a spherical shape.

17. The stress-engineered frangible structure of claim 9, further comprising a trigger mechanism operably attached to the first glass member, the trigger mechanism configured to generate an initial fracture force sufficient to cause the first propagating fracture force in the at least one strengthened portion of the first glass member.

18. The stress-engineered frangible structure of claim 17, further comprising a sensor configured to detect a predetermined transmitted signal, and configured to generate a trigger signal in response to detection of the predetermined transmitted signal, wherein the trigger mechanism is configured to generate the initial fracture force in response to the trigger signal.

19. A method for producing a stress-engineered frangible structure, the method comprising:

providing a plurality of discrete glass members configured to collectively form, when operably assembled, a curved structural shape, each discrete glass member including at least one strengthened portion comprising a stress-engineered glass material; and

interconnecting the plurality of discrete glass members such that each discrete glass member is connected by way of an inter-structure bond to an adjacent one of the discrete glass members;

wherein each inter-structure bond is configured to transfer first propagating fracture forces from the at least one strengthened portion of a first glass member to the at least one strengthened portion of an adjacent second glass member such that secondary propagating fracture forces are generated in the adjacent second glass member in response to the transferred first propagating fracture forces.

20. The method of claim 19, further comprising providing a trigger mechanism configured to generate an initial fracture force in the first glass member, wherein the initial fracture force generated in the first glass member by the trigger mechanism is transferred by way of the inter-structure bonds to all of the plurality of interconnected glass members.