Method for separating carbon dioxide from a gas flow, in particular from a flue gas flow, and separating device for separating carbon dioxide from a gas flow, in particular from a flue gas flow

• US 10,213,728 B2
• Filed: 06/12/2014
• Issued: 02/26/2019
• Est. Priority Date: 06/21/2013
• Status: Active Grant

• Current Assignee: Siemens Energy Global GmbH & Co. KG (Siemens AG)
• Original Assignee: Siemens AG
• Inventors: Hafner, Benjamin, Kursawe, Ansgar, Reichl, Albert, Schneider, Rudiger, Schramm, Henning
• Primary Examiner(s): Holecek, Carbrena
• Application Number:
  US14/898,136
• Publication Number:
  US 20160206991A1
• Time in Patent Office: 1,720 Days
• CPC Class Codes: B01D 15/36 involving ionic interaction
• CPC Class Codes: B01D 15/361 Ion-exchange
• CPC Class Codes: B01D 2252/20494 Amino acids, their salts or derivatives
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 2311/04 Specific process operations in the feed stream; Feed pretreatment
• CPC Class Codes: B01D 2311/2626 Absorption or adsorption
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/96 Regeneration, reactivation or recycling of reactants
• CPC Class Codes: B01D 61/025 Reverse osmosis; Hyperfiltration
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A method for separating carbon dioxide from a gas flow, in particular from a flue gas flow, where a gas flow is brought in contact with a scrubbing medium in an absorber of a separating device and carbon dioxide contained in the gas flow is separated, the loaded scrubbing medium is fed to a desorber of the separating device in order to release the carbon dioxide, a vapor flow is drawn from the desorber and is fed to a cooling device in order to form condensate, and the condensate formed in the cooling device is at least partially fed to a purifying device, in which degradation products contained in the condensate are removed by reverse osmosis and/or by an ion exchanger. A separating device is adapted for separating carbon dioxide from a gas flow.

Claims

1. A method for separating off carbon dioxide from a gas stream, the method comprising:

bringing a gas stream into contact with a scrubbing medium in an absorber of a separating device, with carbon dioxide present in the gas stream being separated off,

feeding the loaded scrubbing medium to a desorber of the separating device to liberate the carbon dioxide,

withdrawing a vapor stream from the desorber and feeding the vapor stream to a cooling device for formation of condensate,

feeding the condensate formed in the cooling device, at least in part, to a purification device, comprising a reverse osmosis plant

removing degradation products present in the condensate by reverse osmosis, and recirculating the condensate that was purified in the purification device by removal of degradation products to the desorber.

2. The method as claimed in claim 1, wherein the purification device further comprises an ion exchanger, and

wherein additional degradation products present in the condensate are removed by the ion exchanger.

3. The method as claimed in claim 1,

wherein the vapor stream is withdrawn at the top of the desorber.

4. The method as claimed in claim 1, further comprising:

feeding the degradation products separated off in the purification device to a utilization appliance.

5. The method as claimed in claim 1,

wherein the cooling device used is a heat exchanger.

6. The method as claimed in claim 1,

wherein the cooling device used is a scrubbing column, supplied with acidified water.

7. The method as claimed in claim 1, further comprising:

recirculating the scrubbing medium draining off from the desorber to the absorber.

8. The method as claimed in claim 1,

wherein the scrubbing medium used is an amino acid salt or the aqueous solution thereof.

9. A separating device for separating off carbon dioxide from a gas stream, comprising

an absorber for separating off carbon dioxide from the gas stream by a scrubbing medium, and

a desorber that is flow-coupled to the absorber for liberating carbon dioxide that is absorbed in the scrubbing medium,

a cooling device flow-connected to the desorber to form a condensate,

a purification device, comprising a reverse osmosis plant, wherein the purification device is flow-connected to the cooling device,

wherein the purification device is equipped and constructed to remove degradation products from the condensate formed in the cooling device by reverse osmosis, and

a recirculation line and a feed line, wherein the reverse osmosis purification device for recirculating purified condensate is flow-coupled via the recirculation line to the feed line of the desorber.

10. The separating device as claimed in claim 9, wherein the purification device further comprises

an ion exchanger, and

wherein the purification device is equipped and constructed to remove additional degradation products from the condensate formed in the cooling device by the ion exchanger.

11. The separating device as claimed in claim 9, further comprising:

a discharge line for a withdrawable vapor stream connected at the top of the desorber.

12. The separating device as claimed in claim 9, further comprising:

a utilization appliance, and

a discharge line connected to the purification device, wherein the discharge line opens out into the utilization appliance.

13. The separating device as claimed in claim 9,

wherein the cooling device used is a heat exchanger.

14. The separating device as claimed in claim 9,

wherein the cooling device used is a scrubbing column, supplied with acidified water.

15. The separating device as claimed in claim 9, further comprising:

a recirculation line and a feed line,

wherein the desorber is flow-coupled via the recirculation line to the feed line of the absorber.

16. The separating device as claimed in claim 9,

wherein the scrubbing medium used is an amino acid salt.