Temperable three layer antireflective coating, coated article including temperable three layer antireflective coating, and/or method of making the same

• US 10,214,446 B2
• Filed: 10/24/2017
• Issued: 02/26/2019
• Est. Priority Date: 09/03/2010
• Status: Active Grant

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Inventors: Broadway, David M., Lu, Yiwei
• Primary Examiner(s): Alexander, William R
• Assistant Examiner(s): Madonna, Jeffrey
• Application Number:
  US15/791,781
• Publication Number:
  US 20180057398A1
• Time in Patent Office: 490 Days
• Field of Search: 359557-590
• CPC Class Codes: C03C 17/3435 comprising a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 2217/73 Anti-reflective coatings with specific characteristics
• CPC Class Codes: C03C 2218/365 Coating different sides of a glass substrate
• CPC Class Codes: G02B 1/115 Multilayers

Abstract

A coated article includes a temperable antireflection (AR) coating that utilizes medium and low index (index of refraction “n”) layers having compressive residual stress in the AR coating. In certain example embodiments, the coating may include the following layers from the glass substrate outwardly: silicon oxynitride (SiO_xN_y) medium index layer/high index layer/low index layer. In certain example embodiments, depending on the chemical and optical properties of the high index layer and the substrate, the medium and low index layers of the AR coating are selected to cause a net compressive residual stress and thus optimize the overall performance of the antireflection coating when the coated article is tempered and/or heat-treated.

Claims

1. A coated article comprising an antireflective coating supported by a first major surface of a substrate, wherein the antireflective coating comprises, in order moving away from the substrate:

a silicon-inclusive medium index layer disposed, directly or indirectly, on the first major surface of the substrate;

a high index layer disposed over and contacting the medium index layer, the high index layer having a thickness of at least 85 nm;

a low index layer disposed over and contacting the high index layer;

wherein the medium index layer comprises silicon oxynitride and has an index of refraction of from about 1.65 to 2.0 at 380 nm, 550 nm, and 780 nm wavelengths, the high index layer has an index of refraction of at least about 2.0 at 380 nm, 550 nm, and 780 nm wavelengths, and the low index layer has an index of refraction of from about 1.4 to 1.6 at 380 nm, 550 nm, and 780 nm wavelengths.

2. The coated article of claim 1, wherein the medium index layer comprising silicon oxynitride has an index of refraction of from about 1.7 to 1.8 at 550 nm.

3. The coated article of claim 2, wherein the high index layer comprises an oxide of titanium, and has a thickness between about 95 to 105 nm.