Electrically operated propellants with elevated self-sustaining threshold pressures

• US 10,220,809 B2
• Filed: 07/20/2016
• Issued: 03/05/2019
• Est. Priority Date: 05/28/2014
• Status: Active Grant

• Current Assignee: Raytheon Company (Rtx Corporation)
• Original Assignee: Raytheon Company (Rtx Corporation)
• Inventors: Loehr, Richard D., Villarreal, James K.
• Primary Examiner(s): Gooden, Jr., Barry
• Application Number:
  US15/214,996
• Publication Number:
  US 20160325708A1
• Time in Patent Office: 958 Days
• CPC Class Codes: B60R 21/00 Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks safety belts or body harnesses in vehicles B60R22/00; devices, apparatus or methods for life-saving in general A62B; safety devices for propulsion unit control specially adapted for, or arranged in, vehicles B60K28/00; seats constructed to protect the occupant from the effect of abnormal g-forces, e.g. crash or safety seats, B60N2/42; energy-absorbing arrangements for hand wheels for steering vehicles B62D1/11; energy-absorbing arrangements for vehicle steering columns B62D1/19; harnessing in aircraft B64D25/00
• CPC Class Codes: B60R 21/264 using instantaneous generation of gas, e.g. pyrotechnic B60R21/268 takes precedence
• CPC Class Codes: B60R 21/2644 using only solid reacting substances, e.g. pellets, powder
• CPC Class Codes: C06B 33/06 the material being an inorganic oxygen-halogen salt
• CPC Class Codes: C06C 9/00 Chemical contact igniters; Chemical lighters
• CPC Class Codes: C06D 5/06 by reaction of two or more solids
• CPC Class Codes: F42B 3/04 for producing gas under pressure generators of inflation fluid especially adapted for vehicle air bags B60R21/26
• CPC Class Codes: F42B 3/128 characterised by the composition of the pyrotechnic material
• CPC Class Codes: F42B 3/14 Spark initiators F42B3/195 takes precedence
• CPC Class Codes: F42C 19/0823 Primers or igniters for the initiation or the propellant charge in a cartridged ammunition primers for caseless ammunition F42C19/085
• CPC Class Codes: F42C 19/12 electric

Abstract

The rate of combustion of an electrically operated propellant having a self-sustaining threshold of at least 1,000 psi is controlled to produce chamber pressures that are sufficient to produce a desired pressure profile in the airbag to accommodate a range of human factors and crash conditions yet never exceeding the self-sustaining threshold. The combustion of the propellant is extinguished to control the total pressure impulse delivered to the airbag. Propellants formed with an ionic perchlorate-based oxidizer have demonstrated thresholds in excess of 1,500 psi and higher.

Claims

1. A gas generation system with an electrically operated propellant comprising:

a combustion chamber;

at least two electrodes configured for coupling with an electrical power source;

an electrically operated propellant within the combustion chamber and electrically coupled to each of the at least two electrodes, said electrically operated propellant having a self-sustaining threshold pressure of at least 1,000 psi at which the propellant once ignited cannot be extinguished and below which the propellant can be extinguished by interruption of an electrical input; and

wherein the electrically operated propellant is configured to ignite at an ignition condition and generate gas, and to extinguish under an extinguishing condition,

in the ignition condition, the electrical input is applied across the at least two electrodes to ignite the electrically operated propellant, and

in the extinguishing condition, the electrical input is interrupted, the pressure within the combustion chamber is less than the self-sustaining threshold pressure, and the electrically operated propellant transitions from ignited to extinguished.

2. The gas generation system of claim 1, wherein, in the ignition condition, pressure in the combustion chamber reaches more than 500 psi.

3. The gas generation system of claim 1, wherein, in the extinguishing condition, the electrical input is interrupted, pressure within the combustion chamber is greater than 500 psi and less than the self-sustaining threshold, and the electrically operated propellant transitions from ignited to extinguished.

4. The gas generation system of claim 1, wherein the self-sustaining threshold is at least 1,500 psi and wherein, in the ignition condition, pressure in the combustion chamber reaches more than 1,000 psi.

5. The gas generation system of claim 1, wherein the electrically operated propellant comprises an ionic perchlorate-based oxidizer.

6. The gas generation system of claim 1, wherein the electrically operated propellant includes:

a liquid perchlorate based oxidizer,

a binder, and

a fuel.

7. The gas generation system of claim 6, wherein the electrically operated propellant includes the liquid perchlorate-based oxidizer in a ratio of 50 to 90 percent of a mass of the electrically operated propellant, the binder of approximately 10 to 30 percent of the mass of the electrically operated propellant and the fuel includes a metal-based fuel of approximately 5 to 30 percent of the mass of the electrically operated propellant.

8. The gas generation system of claim 1, comprising a controller coupled with the electrical power source coupled with the at least two electrodes, the controller is configured to control ignition, extinguishing and throttling of the electrically operated propellant, and the controller includes:

an ignition module configured to control an application of the electrical input to the at least two electrodes at the ignition condition,

an extinguishing module configured to interrupt the application of the electrical input to the at least two electrodes at the extinguishing condition, and

a throttling module configured to adjust the application of the electrical input to change a burn rate of the electrically operated propellant.

9. The gas generation system of claim 8, wherein the controller includes a pressure monitoring module, and one or more of the ignition, extinguishing and throttling modules communicate with the pressure monitoring module to control one or more of the ignition, extinguishing and throttling of the electrically operated propellant according to a monitored pressure.

10. An electrically operated propellant comprising:

a perchlorate based oxidizer of approximately 50 to 90 percent of a mass of the electrically operated propellant;

a binder of approximately 10 to 30 percent of the mass of the electrically operated propellant;

a metal based fuel of approximately 5 to 30 percent of the mass of the electrically operated propellant; and

wherein the electrically operated propellant is configured to ignite and extinguish according to a respective application and interruption of an electrical input to the electrically operated propellant;

wherein said electrically operated propellant has a self-sustaining threshold pressure of at least 1,000 psi at which pressure the propellant once ignited cannot be extinguished and below which the propellant can be extinguished by interruption of the electrical input.

11. The electrically operated propellant of claim 10, wherein the self-sustaining threshold pressure is at least 1,500 psi.

12. The electrically operated propellant of claim 10, wherein the perchlorate based oxidizer comprises a liquid perchlorate based oxidizer.

13. The electrically operated propellant of claim 10, wherein the metal based fuel in cooperation with the liquid perchlorate based oxidizer provides the electrically operated propellant with a specific energy of around 600 to 1100 joules per gram at ambient pressure.

14. The electrically operated propellant of claim 10, wherein the electrically operated propellant has an initial total impulse value at an initial time, and a mature impulse value at a second time after storage for at least 30 days at a temperature of around 140 degrees Fahrenheit, and the mature total impulse value is substantially the same as the initial impulse value.

15. A method of using an electrically operated propellant located within a combustion chamber comprising:

igniting an electrically operated propellant by applying an electrical input to the electrically operated propellant, said electrically operated propellant having a self-sustaining threshold pressure of at least 1,000 psi at which the propellant once ignited cannot be extinguished and below which the propellant can be extinguished by interruption of the electrical input;

generating pressurized gas within the combustion chamber from the combustion of the ignited electrically operated propellant; and

extinguishing the electrically operated propellant with the interruption of the electrical input while the electrically operated propellant is subject to a pressure less than the self-sustaining threshold pressure.

16. The method of claim 15, wherein the self-sustaining threshold pressure is at least 1,500 psi.

17. The method of claim 15, wherein generating the pressurized gas produces pressures in the combustion chamber reaching more than 500 psi.

18. The method of claim 17, wherein the electrical input is interrupted to extinguish the electrically operated propellant while subject to more than 500 psi.

19. The method of claim 15, wherein the electrically operated propellant comprises an ionic perchlorate-based oxidizer.

20. The method of claim 19, wherein the ionic perchlorate-based oxidizer is a liquid perchlorate-based oxidizer.