Air separation unit heat exchanger with porous boiling surface coatings

• US 10,221,970 B2
• Filed: 06/21/2018
• Issued: 03/05/2019
• Est. Priority Date: 10/15/2015
• Status: Active Grant

• Current Assignee: Praxair Technology Incorporated (Linde Plc)
• Original Assignee: Praxair Technology Incorporated (Linde Plc)
• Inventors: Lu, Zigui, Kwark, Sang Muk, Corpus, Joseph M., Lane, Jonathan A., Potempa, David P., Shelat, Maulik R.
• Primary Examiner(s): Klemanski, Helene
• Application Number:
  US16/014,642
• Publication Number:
  US 20180299035A1
• Time in Patent Office: 257 Days
• Field of Search: None
• CPC Class Codes: C08J 2301/28 Alkyl ethers
• CPC Class Codes: C08J 2331/02 Characterised by the use of omopolymers or copolymers of esters of monocarboxylic acids
• CPC Class Codes: C08J 9/0066 Use of inorganic compounding ingredients
• CPC Class Codes: C08K 2003/0812 Aluminium
• CPC Class Codes: C08K 2201/003 Additives being defined by their diameter
• CPC Class Codes: C08K 2201/014 Additives containing two or more different additives of the same subgroup in C08K
• CPC Class Codes: C08K 3/08 Metals
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C09D 1/00 Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
• CPC Class Codes: C09D 101/284 with hydroxylated hydrocarbon radicals
• CPC Class Codes: C09D 131/02 Homopolymers or copolymers of esters of monocarboxylic acids
• CPC Class Codes: C09D 5/00 Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced electrically insulating plastics, resins or waxes H01B3/30; Filling pastes
• CPC Class Codes: C09D 5/26 Thermosensitive paints
• CPC Class Codes: C23C 24/082 without intermediate formation of a liquid in the layer
• CPC Class Codes: F16L 9/02 of metal F16L9/16 - F16L9/22 take precedence
• CPC Class Codes: F28F 13/187 especially adapted for evaporator surfaces or condenser surfaces, e.g. with nucleation sites
• CPC Class Codes: Y02P 20/10 Process efficiency

Abstract

A porous metallic coating is provided. The coating is characterized by a combination of optimized properties that improve coating performance, as measured by heat transfer efficiency. The porous coating has optimal ranges for properties such as porosity, particle size and thickness, and has particular applicability in boiling heat transfer applications as part of an air separations unit. The porous coatings are derived from slurry-based formulations that include a mixture of metallic particles, a binder and a solvent.

Claims

1. A heat exchange surface in an air separation unit, comprising:

a substrate;

a porous coating applied to a surface of the substrate, the porous coating comprising aluminum, magnesium and tin metallic particles, wherein the aggregate amount of magnesium metallic particles and tin metallic particles is not greater than 15 wt % of the weight of the porous coating, and wherein the aggregate amount of metallic particles that are aluminum or aluminum alloys is greater than 78 wt %;

wherein the porous coating has an average particle size diameter ranging from about 35 μ

m to about 55 μ

m;

wherein the porous coating has a thickness ranging from about 300 μ

m to about 400 μ

m;

wherein the porous coating has a median pore diameter ranging from about 7 μ

m to about 12 μ

m; and

wherein the porous coating has an overall porosity ranging from about 40% to about 60% based on the overall volume of the porous coating.

2. The heat exchange surface of claim 1, characterized by the absence of a fugitive in the porous coating.

3. The heat exchange surface of claim 1, wherein the porous coating optionally includes metallic particles of copper, iron, or silicon, and wherein the aggregate amount of metallic particles that are copper, iron or silicon is less than 7 wt %.

4. The heat exchange surface of claim 1, wherein the porous coating has an average particle diameter ranging from about 38 μ

m to about 43 μ

m, a median pore diameter ranging from about 7 μ

m to about 10 μ

m, and an overall porosity ranging from about 40% to about 55% based on the overall volume of the porous coating.

5. The heat exchange surface of claim 1, wherein the magnesium metallic particles range from about 0.1 wt % to about 10 wt % of the porous coating, and the tin metallic particles range from about 0.1 wt % to about 5 wt % of the porous coating.

6. The heat exchange surface of claim 1, wherein the heat exchange surface is a boiling surface in a main condenser of the air separation unit and is configured to boil oxygen.

7. The heat exchange surface of claim 1, wherein the surface of the substrate is an inner surface of a heat exchanger tube.

8. The heat exchange surface of claim 7, wherein the heat exchange tube further includes a heat input surface that forms an outer surface of the heat exchange tube configured to transfer heat from a nitrogen stream.

9. The heat exchange surface of claim 7, wherein said inner diameter of the heat exchange tube is less than or equal to 1.0 inches.

10. The heat exchange surface of claim 1, wherein the surface is integrated with a distillation column of the air separation unit.

11. The heat exchange surface of claim 1, wherein said heat exchange surface is disposed within a main condenser of the air separation unit.

12. The heat exchange surface of claim 1, wherein said heat exchange surface is an inner surface of a heat exchange tube in a shell and tube heat exchanger of the air separation unit.

13. The heat exchange surface of claim 1, wherein said heat exchange surface is an outer surface of a heat exchange tube in a shell and tube heat exchanger of the air separation unit.

14. A shell and tube heat exchanger for use in an air separation unit, comprising:

a shell;

a plurality of heat exchange tubes disposed and retained within the shell, each heat exchange tube having a boiling surface and a heat input surface, the shell and tube heat exchanger configured to allow a one fluid to flow through the heat exchange tubes and another fluid to flow within the shell and outside the heat exchange tubes; and

a porous coating applied to the boiling surface of each of the plurality of heat exchange tubes, the porous coating comprising aluminum, magnesium and tin metallic particles;

wherein the aggregate amount of magnesium metallic particles and tin metallic particles is not greater than 15 wt % of the weight of the porous coating;

wherein the aggregate amount of metallic particles that are aluminum or aluminum alloys is greater than 78 wt %;

wherein the porous coating has an average particle size diameter ranging from about 35 μ

m to about 55 μ

m;

wherein the porous coating has a thickness ranging from about 300 μ

m to about 400 μ

m;

wherein the porous coating has a median pore diameter ranging from about 7 μ

m to about 12 μ

m; and

wherein the porous coating has an overall porosity ranging from about 40% to about 60% based on the overall volume of the porous coating.

15. The shell and tube heat exchanger of claim 14, wherein the porous coating optionally includes metallic particles of copper, iron, or silicon, and wherein the aggregate amount of metallic particles that are copper, iron or silicon is less than 7 wt %.

16. The shell and tube heat exchanger of claim 14, wherein the magnesium metallic particles range from about 0.1 wt % to about 10 wt % of the porous coating, and the tin metallic particles range from about 0.1 wt % to about 5 wt % of the porous coating.

17. The shell and tube heat exchanger of claim 14, wherein the shell and tube heat exchanger is a main condenser of the air separation unit.

18. The shell and tube heat exchanger of claim 14 wherein the boiling surface is configured to boil oxygen.

19. The shell and tube heat exchanger of claim 14 wherein the heat input surface is configured to transfer heat from a nitrogen stream.

20. The shell and tube heat exchanger of claim 14, wherein the boiling surface is an inner surface of each of the plurality of the heat exchanger tubes and the heat input surface is an outer surface of each of the plurality heat exchange tubes.