Process for CO2 capture using carbonates and biocatalysts

• US 10,226,733 B2
• Filed: 11/23/2016
• Issued: 03/12/2019
• Est. Priority Date: 08/04/2009
• Status: Active Grant

• Current Assignee: Saipem SPA (Saipem)
• Original Assignee: CO2 Solutions Inc.
• Inventors: Fradette, Sylvie, Gingras, Julie, Carley, Jonathan, Kelly, Glenn R., Ceperkovic, Olivera
• Primary Examiner(s): Yamasaki, Robert J
• Application Number:
  US15/359,868
• Publication Number:
  US 20170072362A1
• Time in Patent Office: 839 Days
• Field of Search: None
• CPC Class Codes: B01D 2251/206 Ammonium compounds
• CPC Class Codes: B01D 2251/304 of sodium
• CPC Class Codes: B01D 2251/306 of potassium
• CPC Class Codes: B01D 2251/606 Carbonates
• CPC Class Codes: B01D 2252/20494 Amino acids, their salts or derivatives
• CPC Class Codes: B01D 2252/205 Other organic compounds not covered by B01D2252/00 - B01D2252/20494
• CPC Class Codes: B01D 2252/602 Activators, promoting agents, catalytic agents or enzymes
• CPC Class Codes: B01D 2255/804 Enzymatic
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/84 Biological processes
• CPC Class Codes: B01D 53/96 Regeneration, reactivation or recycling of reactants
• CPC Class Codes: C12N 9/88 Lyases (4.)
• CPC Class Codes: C12Y 402/01001 Carbonate dehydratase (4.2.1.1), i.e. carbonic anhydrase
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02P 20/59 Biological synthesis; Biological purification

Abstract

A formulation and process for capturing CO₂ use an absorption mixture containing water, biocatalysts and a carbonate compound. The process includes contacting a CO₂-containing gas with the absorption mixture to enable dissolution and transformation of CO₂ into bicarbonate and hydrogen ions, thereby producing a CO₂-depleted gas and an ion-rich solution, followed by subjecting the ion-rich solution to desorption. The biocatalyst improves absorption of the mixture comprising carbonate compounds and the carbonate compound promotes release of the bicarbonate ions from the ion-rich solution during desorption, producing a CO₂ gas stream and an ion-depleted solution.

Claims

1. An enzymatic process for CO2 capture, comprising:

supplying a CO2 containing gas into a lower portion of an absorption unit;

supplying an absorption solution comprising sodium or potassium carbonate into an upper portion of the absorption unit;

counter-currently and directly contacting the CO2 containing gas and the absorption solution in the absorption unit in the presence of carbonic anhydrase while operating at an absorption pressure to enable dissolution and biocatalytic transformation of CO2 into bicarbonate and hydrogen ions, thereby producing a CO2 depleted gas and an ion-loaded solution;

removing the ion-loaded solution from the lower portion of the absorption unit;

supplying the ion-loaded solution to an upper portion of a desorption unit;

desorbing CO2 from the ion-loaded solution in the desorption unit operated at a desorption pressure that is lower than the absorption pressure, to produce desorbed CO2 gas, water vapor, and a regenerated absorption solution;

removing the regenerated absorption solution from a lower portion of the desorption unit;

removing a gas stream comprising the desorbed CO2 gas and the water vapor from the desorption unit; and

recycling at least part of the regenerated absorption solution back as at least part of the absorption solution fed into the absorption unit; and

wherein the carbonic anhydrase is provided to be flowable with the absorption solution and circulates with the ion-loaded solution and the regenerated solution through the absorption unit and the desorption unit.

2. The process of claim 1, further comprising:

cooling the gas stream to produce condensed water and dry gaseous CO2; and

feeding the condensed water back into the desorption unit.

3. The process of claim 2, further comprising supplying the dry gaseous CO2 to a compression process.

4. The process of claim 1, wherein the regenerated absorption solution is pumped back as part of the absorption solution.

5. The process of claim 1, wherein the absorption solution comprises potassium carbonate.

6. The process of claim 1, wherein the carbonic anhydrase is dissolved in the absorption solution.

7. The process of claim 1, wherein the carbonic anhydrase is supported by micro-particles that are carried with the absorption solution.

8. The process of claim 1, further comprising:

cooling the gas stream to produce condensed water and dry gaseous CO2.

9. The process of claim 1, wherein the desorption unit comprises a reboiler and a portion of the regenerated absorption solution is directed toward the reboiler for heating to a temperature enabling CO2 desorption.

10. The process of claim 9, further comprising separating the carbonic anhydrase from the portion of the regenerated absorption solution fed into the reboiler.

11. The process of claim 10, wherein the separating is performed using a filter.

12. The process of claim 1, wherein the absorption solution comprises potassium carbonate that is provided in the absorption solution in a concentration of at least about 0.1M.