Method of measuring the ratio of isotopologue concentrations in the gas phase
First Claim
1. A method of measuring a ratio of concentrations of two isotopologues of a chemical species in a first gas mixture using a first optical absorption spectroscopy based gas analyzer, the method comprising the steps of:
- i) measuring optical absorption spectra of the first gas mixture in a first spectral range containing a first rotational-vibrational line of a first rotational-vibrational band of a first isotopologue and in a second spectral range containing a second rotational-vibrational line of a second rotational-vibrational band of a second isotopologue at a first gas temperature;
ii) based on the measured spectra determining the line intensity of the first rotational-vibrational line of the first rotational-vibrational band of the first isotopologue and the line intensity of the second rotational-vibrational line of the second rotational-vibrational band of the second isotopologue at the first gas temperature;
iii) determining a first ratio of the line intensity of the first rotational-vibrational line and the line intensity of the second rotational-vibrational line at the first gas temperature;
iv) comparing the first ratio to a second ratio of the line intensity of a third rotational-vibrational line of a third rotational-vibrational band of the first isotopologue and the line intensity of a fourth rotational-vibrational line of a fourth rotational-vibrational band of the second isotopologue in a second gas mixture at a second gas temperature, the second gas mixture having a known ratio of concentrations of two said isotopologues, wherein the second ratio was determined using a second optical absorption spectroscopy based gas analyzer;
v) calculating the ratio of concentrations of the said isotopologues in the first gas mixture.
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Abstract
Method of measuring a ratio of concentrations of two isotopologues of a chemical species in a first gas mixture using an optical absorption spectroscopy based gas analyzer; the method includes measuring the line intensity of a rotational-vibrational line of one isotopologue and the line intensity of another rotational-vibrational line of another isotopologue. The method also includes determining the ratio of two line intensities and comparing it with another ratio measured using another gas analyzer for a gas mixture with known concentration of isotopologues. The second ratio can be measured for the same pair of lines or for different pair of lines. The second ratio can be measured at the same gas temperature or at different gas temperature. The method includes determining a ratio of concentrations of two isotopologues based on two ratios of line intensities and two temperatures.
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Citations
14 Claims
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1. A method of measuring a ratio of concentrations of two isotopologues of a chemical species in a first gas mixture using a first optical absorption spectroscopy based gas analyzer, the method comprising the steps of:
- i) measuring optical absorption spectra of the first gas mixture in a first spectral range containing a first rotational-vibrational line of a first rotational-vibrational band of a first isotopologue and in a second spectral range containing a second rotational-vibrational line of a second rotational-vibrational band of a second isotopologue at a first gas temperature;
ii) based on the measured spectra determining the line intensity of the first rotational-vibrational line of the first rotational-vibrational band of the first isotopologue and the line intensity of the second rotational-vibrational line of the second rotational-vibrational band of the second isotopologue at the first gas temperature;
iii) determining a first ratio of the line intensity of the first rotational-vibrational line and the line intensity of the second rotational-vibrational line at the first gas temperature;
iv) comparing the first ratio to a second ratio of the line intensity of a third rotational-vibrational line of a third rotational-vibrational band of the first isotopologue and the line intensity of a fourth rotational-vibrational line of a fourth rotational-vibrational band of the second isotopologue in a second gas mixture at a second gas temperature, the second gas mixture having a known ratio of concentrations of two said isotopologues, wherein the second ratio was determined using a second optical absorption spectroscopy based gas analyzer;
v) calculating the ratio of concentrations of the said isotopologues in the first gas mixture. - View Dependent Claims (2, 3, 4)
- i) measuring optical absorption spectra of the first gas mixture in a first spectral range containing a first rotational-vibrational line of a first rotational-vibrational band of a first isotopologue and in a second spectral range containing a second rotational-vibrational line of a second rotational-vibrational band of a second isotopologue at a first gas temperature;
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5. A method of measuring a ratio of concentrations of two isotopologues of a chemical species in a first gas mixture using a first optical absorption spectroscopy based gas analyzer, the method comprising the steps of:
- i) measuring an optical absorbance of the first gas mixture at a first wavelength in a first spectral range containing a first rotational-vibrational line of a first rotational-vibrational band of a first isotopologue and an optical absorbance of the first gas mixture at a second wavelength in a second spectral range containing a second rotational-vibrational line of a second rotational-vibrational band of a second isotopologue at a first gas temperature and at a first gas pressure;
ii) determining a first ratio of two said optical absorbances at the first gas temperature;
iii) comparing the first ratio to a second ratio of the optical absorbance at the first wavelength and the optical absorbance at the second wavelength of a second gas mixture at a second gas temperature and a second gas pressure, where the second gas mixture having a known ratio of concentrations of two said isotopologues, wherein the second ratio was determined using a second optical absorption spectroscopy based gas analyzer;
iv) calculating the ratio of concentrations of the said isotopologues in the first gas mixture. - View Dependent Claims (6, 7, 8)
- i) measuring an optical absorbance of the first gas mixture at a first wavelength in a first spectral range containing a first rotational-vibrational line of a first rotational-vibrational band of a first isotopologue and an optical absorbance of the first gas mixture at a second wavelength in a second spectral range containing a second rotational-vibrational line of a second rotational-vibrational band of a second isotopologue at a first gas temperature and at a first gas pressure;
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9. A method for defining a primary optical transfer standard of the ratio of concentrations of two gaseous isotopologues of a chemical species, the method comprising the steps of:
- i) converting a first isotopic standard medium into a gas phase medium by producing a first gaseous isotopologue and a second gaseous isotopologue containing the type of atoms defined for the isotopic standard by first medium, unless the first medium is already in the gas phase;
ii) transferring gaseous isotopologues produced in the previous step into an optical absorption based gas analyzer, iii) stabilizing the gas temperature of the gas transferred into the said gas analyzer at a first temperature, iv) measuring rotational-vibrational absorption spectra of the said gas in a first spectral range containing a first rotational-vibrational line of a first rotational-vibrational band of the first isotopologue and in a second spectral range containing of a second rotational-vibrational line of a second rotational-vibrational band of the second isotopologue at the first gas temperature;
v) based on the said spectra determining the line intensity of the first rotational-vibrational line of the first rotational-vibrational band of the first isotopologue and the line intensity of the second rotational-vibrational line of the second rotational-vibrational band of the second isotopologue at the first gas temperature;
vi) defining a first ratio of the line intensity of the first rotational-vibrational line and the line intensity of the second rotational-vibrational line at the first gas temperature;
vii) defining the primary optical transfer standard of the ratio of concentrations of two gaseous isotopologues as the first ratio of the line intensity of the first rotational-vibrational line of the first rotational-vibrational band of the first isotopologue and the line intensity of the second rotational-vibrational line of the second rotational-vibrational band of the second isotopologue at the first gas temperature. - View Dependent Claims (10, 11, 12, 13, 14)
- i) converting a first isotopic standard medium into a gas phase medium by producing a first gaseous isotopologue and a second gaseous isotopologue containing the type of atoms defined for the isotopic standard by first medium, unless the first medium is already in the gas phase;
Specification