Methods for manufacturing bulked continuous filament

• US 10,239,247 B2
• Filed: 03/29/2017
• Issued: 03/26/2019
• Est. Priority Date: 05/31/2012
• Status: Active Grant

• Current Assignee: Aladdin Manufacturing Corporation (Mohawk Industries Incorporated)
• Original Assignee: Mohawk Industries Incorporated
• Inventors: Clark, Thomas R.
• Primary Examiner(s): Tentoni, Leo B
• Application Number:
  US15/473,385
• Publication Number:
  US 20170203486A1
• Time in Patent Office: 727 Days
• Field of Search: 264 401, 264101, 264102, 264140, 2641761, 26421121, 26421122, 26421123
• CPC Class Codes: B29B 13/06 by drying B29B13/08 takes precedence ; drying moulded articles or half products B29C37/0092
• CPC Class Codes: B29B 17/0026 by agglomeration or compacting
• CPC Class Codes: B29B 17/02 Separating plastics from other materials
• CPC Class Codes: B29B 17/0412 to large particles, e.g. beads, granules, flakes, slices
• CPC Class Codes: B29B 2013/005 Degassing undesirable residual components, e.g. gases, unreacted monomers, from material to be moulded
• CPC Class Codes: B29B 2017/0015 Washing, rinsing
• CPC Class Codes: B29B 2017/0279 Optical identification, e.g. cameras or spectroscopy
• CPC Class Codes: B29B 2017/0289 Washing the materials in liquids
• CPC Class Codes: B29B 7/485 with three or more shafts provided with screws
• CPC Class Codes: B29B 7/86 for working at sub- or superatmospheric pressure B01F33/70 takes precedence
• CPC Class Codes: B29C 2791/003 Making articles of indefinite length B29C53/48 takes precedence
• CPC Class Codes: B29C 2791/006 Using vacuum
• CPC Class Codes: B29C 2948/922 Viscosity; Melt flow index [MFI]; Molecular weight
• CPC Class Codes: B29C 2948/92514 Pressure
• CPC Class Codes: B29C 2948/92838 Raw material pre-treatment, e.g. drying or cleaning
• CPC Class Codes: B29C 37/006 Degassing moulding material or draining off gas during moulding venting means in moulds B29C33/10
• CPC Class Codes: B29C 48/0022 combined with cutting
• CPC Class Codes: B29C 48/02 Small extruding apparatus, e.g. handheld, toy or laboratory extruders
• CPC Class Codes: B29C 48/022 characterised by the choice of material
• CPC Class Codes: B29C 48/05 Filamentary, e.g. strands
• CPC Class Codes: B29C 48/144 : at the plasticising zone
• CPC Class Codes: B29C 48/267 : Intermediate treatments, e.g. relaxation, annealing or decompression step for the melt B29C48/76 takes precedence
• CPC Class Codes: B29C 48/38 : using two or more serially arranged screws in the same barrel
• CPC Class Codes: B29C 48/385 : using two or more serially arranged screws in separate barrels
• CPC Class Codes: B29C 48/40 : using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
• CPC Class Codes: B29C 48/404 : the screws having non-intermeshing parts
• CPC Class Codes: B29C 48/425 : using three or more screws serially arranged screws B29C48/38, B29C48/385
• CPC Class Codes: B29C 48/43 : Ring extruders
• CPC Class Codes: B29C 48/435 : Sub-screws
• CPC Class Codes: B29C 48/44 : Planetary screws
• CPC Class Codes: B29C 48/69 : Filters or screens for the moulding material
• CPC Class Codes: B29C 48/70 : comprising means for dividing, distributing and recombining melt flows
• CPC Class Codes: B29C 48/92 : Measuring, controlling or regulating
• CPC Class Codes: B29D 99/0078 : Producing filamentary materials
• CPC Class Codes: B29K 2067/003 : PET, i.e. poylethylene terephthalate
• CPC Class Codes: B29K 2105/26 : Scrap or recycled material
• CPC Class Codes: B29L 2031/731 : Filamentary material, i.e. comprised of a single element, e.g. filaments, strands, threads, fibres cables B29L2031/707
• CPC Class Codes: C08J 11/04 : of polymers
• CPC Class Codes: C08J 2367/02 : Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: D01D 1/103 : De-aerating
• CPC Class Codes: D01D 1/106 : Filtering
• CPC Class Codes: D01D 5/08 : Melt spinning methods D01D5/0023 takes precedence
• CPC Class Codes: D01F 6/62 : from polyesters
• CPC Class Codes: D02G 3/24 : Bulked yarns or threads, e.g. formed from staple fibre components with different relaxation characteristics
• CPC Class Codes: Y02P 20/143 : the feedstock being recycled material, e.g. plastics
• CPC Class Codes: Y02W 30/62 : Plastics recycling; Rubber recycling

Abstract

A method of manufacturing bulked continuous carpet filament which, in various embodiments, comprises: (A) grinding recycled PET bottles into a group of flakes; (B) washing the flakes; (C) identifying and removing impurities, including impure flakes, from the group of flakes; (D) passing the flakes through a PET crystallizer; (E) passing the group of flakes through an MRS extruder while maintaining the pressure within the MRS portion of the MRS extruder below about 18 millibars; (F) passing the resulting polymer melt through at least one filter having a micron rating of less than about 50 microns; and (G) forming the recycled polymer into bulked continuous carpet filament that consists essentially of recycled PET.

Claims

1. A method of manufacturing bulked continuous carpet filament, the method comprising:

(A) providing a PET crystallizer;

(B) passing a plurality of flakes of recycled PET through the PET crystallizer to at least partially dry the plurality of flakes of recycled PET;

(C) at least partially melting the plurality of flakes into a polymer melt;

(D) providing a multi-rotating screw (MRS) extruder comprising;

an MRS Section comprising;

a plurality of satellite screws, each of the plurality of satellite screws being at least partially housed within a respective extruder barrel and mounted to rotate about its respective central axis; and

a satellite screw extruder support system that is adapted to orbitally rotate each of the plurality of satellite screws about a main axis as each of the plurality of satellite screws rotate about its respective central axis, the main axis being substantially parallel to each respective central axis;

a first single-screw extruder section comprising a first single extruder screw for melting the plurality of flakes of recycled PET to form a polymer melt and feeding the polymer melt into the MRS section;

a second single-screw extruder section comprising a second single extruder screw for transporting the polymer melt away from the MRS section; and

a vacuum pump in communication with the MRS section that is adapted to maintain a pressure within the MRS Section below a pressure of about 25 millibars as the polymer melt passes through the MRS Section;

(E) using the vacuum to reduce a pressure within the MRS Section to below about 25 millibars;

(F) after the step of passing the plurality of flakes through the PET crystallizer, melting the plurality of flakes of recycled PET to form a polymer melt and, while maintaining the pressure within the MRS Section below about 25 millibars, passing the polymer melt through the MRS Section so that at least a portion of the polymer melt passes through each the respective extruder barrel; and

(G) after the step of passing the polymer melt through the MRS extruder, forming the polymer melt into bulked continuous carpet filament.

2. The method of claim 1, wherein the PET crystallizer comprises:

a hopper screw configured to feed the plurality of flakes into the PET crystallizer; and

a blower configured to blow hot air over the plurality of flakes as the plurality of flakes pass through the crystallizer.

3. The method of claim 2, wherein the crystallizer is configured to maintain a temperature of between about 140 degrees Celsius and about 180 Celsius within the crystallizer.

4. The method of claim 3, wherein:

the MRS Section comprises a vacuum attachment portion defining an opening in a housing of the MRS Section; and

the vacuum pump is coupled to the vacuum attachment portion and is in communication with the interior of the MRS section via the opening.

5. The method of claim 1, wherein the crystallizer is configured to at least partially crystallize the plurality of flakes.

6. The method of claim 1, wherein the plurality of satellite screws comprise eight satellite screws.

7. The method of claim 6, wherein the crystallizer is configured to reduce a moisture content of the plurality of flakes to between about 30 ppm and about 50 ppm.

8. A method of manufacturing carpet filament comprising the steps of:

(A) grinding a plurality of recycled PET bottles into a group of polymer flakes;

(B) washing the group of polymer flakes to remove at least a portion of one or more contaminants from a surface of the flakes, the group of flakes comprising a first plurality of flakes that consist essentially of PET and a second plurality of flakes that do not consist essentially of PET;

(C) after the step of washing the first plurality of flakes;

(i) scanning the washed group of flakes to identify the second plurality of flakes,

(ii) separating the second plurality of flakes from the first plurality of flakes;

(D) providing a PET crystallizer;

(E) passing the first plurality of flakes through the PET crystallizer to at least partially dry the first plurality of flakes;

(F) melting the second plurality of flakes to produce a polymer melt;

(G) providing an extruder that extrudes material in a plurality of different extrusion streams and comprises;

at least four satellite screws wherein each respective satellite screw of the at least four satellite screws is mounted to rotate about its respective central axis; and

a single screw drum mounted to rotate about its central axis, wherein;

the central axis of the single screw drum is parallel to each respective central axis of the at least four satellite screws;

the at least four satellite screws are arranged within the single screw drum and at least partially housed within respective extruder barrels; and

each of the at least four satellite screws is configured to rotate about its the respective axis while the single screw drum rotates about the central axis of the single screw drum;

(H) reducing a pressure within the extruder to between about 0 millibars and about 18 millibars;

(I) while maintaining the pressure within the extruder between about 0 millibars and about 18 millibars, passing the polymer melt through the extruder so that the polymer melt is divided into a plurality of extrusion streams and at least a portion of the polymer melt passes through each of the at least four satellite screws, each having a pressure between about 0 millibars and about 18 millibars;

(J) after passing the polymer melt through the extruder, filtering the polymer melt through at least one filter; and

(K) after passing the polymer melt through the filter, forming the polymer melt into bulked continuous carpet filament.

9. The method of claim 8, wherein reducing the pressure within the extruder to between about 0 millibars and about 18 millibars comprises:

determining a source of the recycled PET bottles;

at least partially in response to determining that the source of the recycled PET bottles comprises deposit PET bottles, reducing the pressure within the extruder to a first pressure between about 0 millibars and about 18 millibars; and

at least partially in response to determining that the source of the recycled PET bottles comprises deposit curbside recycled PET bottles, reducing the pressure within the extruder to a second pressure between about 0 millibars and about 18 millibars.

10. The method of claim 9 wherein the first pressure is greater than the second pressure.

11. The method of claim 8, wherein the crystallizer comprises:

a hopper screw configured to feed the plurality of flakes into the crystallizer; and

a blower configured to blow hot air over the plurality of flakes as the plurality of flakes pass through the crystallizer.

12. The method of claim 11, wherein the crystallizer is configured to maintain a temperature of between about 140 degrees Celsius and about 180 degrees Celsius within the crystallizer.

13. The method of claim 8, wherein each of the at least four satellite screws is adapted to rotate in a direction that is the same as a direction in which the single screw drum is adapted to rotate.

14. The method of claim 8, wherein the crystallizer is configured to at least partially crystallize the plurality of flakes.

15. The method of claim 8, wherein the crystallizer is configured to reduce a moisture content of the plurality flakes to between about 30 ppm and about 50 ppm.

16. The method of claim 15, wherein the crystallizer is configured to sufficiently reduce the moisture content of the plurality of flakes such that the plurality of flakes do not substantially stick to one another.

17. A method of manufacturing bulked continuous carpet filament, the method comprising:

(A) providing a PET crystallizer that comprises;

(i) a hopper screw configured to feed a plurality of flakes into the crystallizer; and

(ii) at least one heating element configured to increase a temperature within the PET crystallizer;

(B) passing a plurality of flakes consisting essentially of PET flakes through the PET crystallizer to at least partially dry the first plurality of flakes;

(C) after passing the plurality of flakes though the PET crystallizer, melting the plurality of flakes to form a polymer melt;

(D) providing a multi-screw extruder that comprises;

(i) a first satellite screw extruder, the first satellite screw extruder comprising a first satellite screw that is mounted to rotate about a central axis of the first satellite screw;

(ii) a second satellite screw extruder, the second satellite screw extruder comprising a second satellite screw that is mounted to rotate about a central axis of the second satellite screw;

(iii) a third satellite screw extruder, the third satellite screw extruder comprising a third satellite screw that is mounted to rotate about a central axis of the third satellite screw;

(iv) a fourth satellite screw extruder, the fourth satellite screw extruder comprising a fourth satellite screw that is mounted to rotate about a central axis of the fourth satellite screw, wherein the first satellite screw, the second satellite screw, the third satellite screw, and the fourth satellite screw are disposed at least partially within respective extruder barrels;

(v) a satellite screw extruder support system that is adapted to rotate the first, second, third, and fourth satellite screws about a main axis while the first, second, third and fourth satellite screws are rotating about their respective central axes, the main axis being substantially parallel to;

(a) the central axis of the first satellite screw;

(b) the central axis of the second satellite screw;

(c) the central axis of the third satellite screw; and

(d) the central axis of the fourth satellite screw; and

(vi) a pressure regulation system that is adapted to maintain a pressure within the first, second, third, and fourth satellite screw extruders between about 0 millibars and about 25 millibars;

(E) using the pressure regulation system to reduce a pressure within the first, second, third, and fourth satellite screw extruders to between about 0 millibars and about 25 millibars;

(F) while maintaining the pressure within the first, second, third, and fourth satellite screw extruders between about 0 millibars and about 25 millibars, passing the polymer melt through the multi-screw extruder so that;

(1) a first portion of the melt passes through the first satellite screw extruder, (2) a second portion of the melt passes through the second satellite screw extruder, (3) a third portion of the melt passes through the third satellite screw extruder, and (4) a fourth portion of the melt passes through the fourth satellite screw extruder; and

(G) after the step of passing the polymer melt through the multi-screw extruder, forming the polymer melt into bulked continuous carpet filament.

18. The method of claim 17, wherein the at least one heating element is configured to maintain a temperature of between about 140 degrees Celsius and about 180 degrees Celsius within the crystallizer.

19. The method of claim 18, wherein the at least one heating element comprises at least one infrared heating element.

20. The method of claim 17, wherein:

the crystallizer is configured to reduce a moisture content of the plurality of flakes to between about 30 ppm and about 50 ppm; and

passing the plurality of flakes consisting essentially of recycled PET through the PET crystallizer to at least partially dry the plurality of flakes comprises reducing the moisture content of the plurality of flakes to between about 30 ppm and about 50 ppm.