Biodegradable sheet

• US 10,239,292 B2
• Filed: 10/27/2014
• Issued: 03/26/2019
• Est. Priority Date: 10/27/2013
• Status: Active Grant

• Current Assignee: TIPA Corp. Ltd.
• Original Assignee: TIPA Corp. Ltd.
• Inventors: Nissenbaum, Daphna, Neuman, Tal, Pelled, Dori, Garty, Shai, Konieczny, Nili
• Primary Examiner(s): Loewe, Robert S
• Application Number:
  US15/030,613
• Publication Number:
  US 20160257098A1
• Time in Patent Office: 1,611 Days
• Field of Search: None
• CPC Class Codes: B29C 48/022 characterised by the choice of material
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/92 Measuring, controlling or regulating
• CPC Class Codes: B32B 2250/02 2 layers
• CPC Class Codes: B32B 2250/03 3 layers
• CPC Class Codes: B32B 2250/04 4 layers
• CPC Class Codes: B32B 2250/05 5 or more layers
• CPC Class Codes: B32B 2250/40 Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
• CPC Class Codes: B32B 2255/10 on synthetic resin layer or on natural or synthetic rubber layer
• CPC Class Codes: B32B 2255/205 Metallic coating
• CPC Class Codes: B32B 2262/06 Vegetal fibres
• CPC Class Codes: B32B 2262/062 Cellulose fibres, e.g. cotton
• CPC Class Codes: B32B 2262/065 Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
• CPC Class Codes: B32B 2262/067 Wood fibres
• CPC Class Codes: B32B 2262/10 Inorganic fibres
• CPC Class Codes: B32B 2262/101 Glass fibres
• CPC Class Codes: B32B 2262/105 Ceramic fibres
• CPC Class Codes: B32B 2262/106 Carbon fibres, e.g. graphite fibres
• CPC Class Codes: B32B 2262/108 Rockwool fibres
• CPC Class Codes: B32B 2264/06 Vegetal particles
• CPC Class Codes: B32B 2264/067 : Wood particles
• CPC Class Codes: B32B 2264/10 : Inorganic particles
• CPC Class Codes: B32B 2264/104 : Oxysalt, e.g. carbonate, sulfate, phosphate or nitrate particles
• CPC Class Codes: B32B 2264/105 : Metal
• CPC Class Codes: B32B 2264/107 : Ceramic
• CPC Class Codes: B32B 2270/00 : Resin or rubber layer containing a blend of at least two different polymers
• CPC Class Codes: B32B 2307/31 : Heat sealable
• CPC Class Codes: B32B 2307/54 : Yield strength; Tensile strength
• CPC Class Codes: B32B 2307/546 : Flexural strength; Flexion stiffness
• CPC Class Codes: B32B 2307/704 : Crystalline
• CPC Class Codes: B32B 2307/7163 : Biodegradable
• CPC Class Codes: B32B 2307/7244 : Oxygen barrier
• CPC Class Codes: B32B 2307/7246 : Water vapor barrier
• CPC Class Codes: B32B 2307/7265 : Non-permeable
• CPC Class Codes: B32B 2307/73 : Hydrophobic
• CPC Class Codes: B32B 2307/732 : Dimensional properties
• CPC Class Codes: B32B 2439/00 : Containers; Receptacles
• CPC Class Codes: B32B 2439/70 : Food packaging
• CPC Class Codes: B32B 27/08 : of synthetic resin
• CPC Class Codes: B32B 27/22 : using plasticisers
• CPC Class Codes: B32B 27/28 : comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
• CPC Class Codes: B32B 27/306 : comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 27/36 : comprising polyesters
• CPC Class Codes: B32B 27/365 : comprising polycarbonates
• CPC Class Codes: B32B 7/12 : using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: B65D 65/46 : Applications of disintegrable, dissolvable or edible materials
• CPC Class Codes: B65D 65/466 : Bio- or photodegradable packaging materials
• CPC Class Codes: C08J 2300/16 : Biodegradable polymers
• CPC Class Codes: C08J 2367/02 : Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: C08J 2367/04 : Polyesters derived from hydroxy carboxylic acids, e.g. lactones C08J2367/06 takes precedence
• CPC Class Codes: C08J 2400/16 : Biodegradable polymers
• CPC Class Codes: C08J 2467/04 : Polyesters derived from hydroxy carboxylic acids, e.g. lactones C08J2467/06 takes precedence
• CPC Class Codes: C08J 5/18 : Manufacture of films or sheets
• CPC Class Codes: C08J 7/042 : with two or more layers, where at least one layer of a composition contains a polymer binder
• CPC Class Codes: C08L 101/16 : the macromolecular compounds being biodegradable
• CPC Class Codes: Y02W 90/10 : Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

Abstract

Disclosed is a biodegradable sheet comprising at least one layer which is a direct contact layer, intended to successfully contact materials, such as liquids, while maintaining the mechanical properties of the sheet and to extend the biodegradable sheet shelf life. The direct contact layer may comprise a hydrophobic polymer selected from poly(epsilon-caprolactone) (PCL) polyhydroxybutyrate (PHB), Polydioxanone (PDO) polyglycolic acid (PGA), polybutylene succinate (PBS), polybutylene succinate adipate (PBSA), poly lactic acid (PLA), polybutylene adipate terphtalate (PBAT), polyhydroxyalkanoates (PHA), such as polyhydroxybutyrates (PHB), polyhydroxyvalerates (PHV), and polyhydroxybutyrate-hydroxyvalerate copolymers (PHBV) or any mixture thereof. The biodegradable sheet may further comprise surface treated nanoclay particles, PVOH grafted with a crosslinker and PBS or PBSA The biodegradable sheet may further include at least one metalized, biodegradable, laminate layer.

Claims

1. A multi-layered biodegradable sheet, wherein at least one layer of the multi-layered biodegradable sheet comprises a first hydrophobic polymer selected from the group consisting of poly(epsilon-caprolactone) (PCL), a polyhydroxyalkanoate (PHA) and a mixture thereof, and a second hydrophobic polymer selected from the group consisting of polybutylene succinate (PBS), polybutylene succinate adipate (PBSA), poly lactic acid (PLA), polybutylene adipate terephthalate (PBAT), polydioxanone (PDO), polyglycolic acid (PGA) and any mixture thereof, and wherein the multi-layered biodegradable sheet comprises at least one additional layer comprising a polymer selected from the group consisting of PBS, PBSA, and any mixture thereof,

wherein the first hydrophobic polymer is present in said at least one layer in an amount of about 5% w/w to about 45% w/w.

2. The multi-layered biodegradable sheet of claim 1, wherein the PHA in said at last one layer is selected from the group consisting of polyhydroxybutyrate (PHB), polyhydroxyvalerate (PHV), polyhydroxybutyrate-hydroxyvalerate copolymers (PHBV);

and any mixture thereof.

3. The multi-layered biodegradable sheet of claim 1, wherein the second hydrophobic polymer in said at least one layer is selected from the group consisting of PLA, PBS, PBSA and PBAT.

4. The multi-layered biodegradable sheet of claim 3, wherein the second hydrophobic polymer is present in said at least one layer in an amount of about 55% w/w to about 95% w/w of the weight of the layer.

5. The multi-layered biodegradable sheet of claim 1, wherein the second hydrophobic polymer in said at least one layer is a mixture of PBS and PBSA, a mixture of PBS and PLA, a mixture of PBSA and PLA or a mixture of PBAT and PLA.

6. The multi-layered biodegradable sheet of claim 1, consisting of 2, 3, 4, 5, 6 or 7 layers.

7. The multi-layered biodegradable sheet of claim 6, wherein the sheet is a two-layered sheet, comprising a first layer comprising about 70%-80% w/w PBS or PBSA and about 20%-30% PLA and a second layer comprising about 15%-25% w/w PLA, about 50%-60% w/w PBS or PBSA and about 5%-30% w/w PCL.

8. The multi-layered biodegradable sheet of claim 6, wherein the sheet is a three layered sheet, comprising a first layer comprising about 70%-80% w/w PBS or PBSA and about 20%-30% PLA;

a second layer comprising about 70%-80% w/w PBS or PBSA and about 20%-30% PLA; and

a third layer comprising about 5%-45% w/w PCL or PHA and about 55% to about 80% w/w PLA, PBS, PBSA, PBAT or a mixture thereof, wherein the second layer is an internal layer and the third layer is the contact layer.

9. The multi-layered biodegradable sheet of claim 6, said at least one additional layer comprising about 100% w/w PBS or PBSA.

10. The multi-layered biodegradable sheet of claim 6, wherein the sheet is a three layered sheet comprising a third layer comprising about 15%-25% w/w PBSA or PLA, about 50%-60% w/w PBAT or PBS and about 5%-30% PCL.

11. The multi-layered biodegradable sheet of claim 6, comprising a three layered sheet comprising a first layer comprising about 15%-25% w/w PBSA, about 50%-60% w/w PBS and about 20%-30% PCL.

12. The multi-layered biodegradable sheet of claim 6, wherein the sheet is a five-layered sheet, optionally comprising a first layer and a fifth layer comprising about 25% w/w of a first hydrophobic polymer and about 75% of a mixture of a second hydrophobic polymer selected from the group consisting of a mixture of PBS and PBSA, a mixture of PBS and PLA, a mixture of PBSA and PLA, and a mixture of PBAT and PLA;

and wherein the first layer or fifth layer is a contact layer.

13. The multi-layered biodegradable sheet of claim 12, further comprising a hydrophilic polymer selected from polyvinyl alcohol (PVOH) and ethylene vinyl alcohol (EVOH) or any mixtures thereof.

14. The multi-layered biodegradable sheet of claim 13, further comprising an internal layer comprising about 70%-99% PVOH and 1%-30% PBS or PBSA or PLA or PBAT or PCL.

15. The multi-layered biodegradable sheet of claim 6, wherein the sheet is a five-layered sheet comprising a first layer and a fifth layer comprising about 40% w/w of a first hydrophobic polymer and about 60% of a second hydrophobic polymer selected from the group consisting of PBS, PBSA, PLA and PBAT and wherein the first or fifth layer is a contact layer.

16. The multi-layered biodegradable sheet of claim 15, further comprising a hydrophilic polymer selected from PVOH and EVOH and any mixtures thereof.

17. The multi-layered biodegradable sheet of claim 16, further comprising an internal layer comprising about 70%-99% PVOH and 1%-30% PBS or PBSA or PLA or PBAT or PCL.

18. The multi-layered biodegradable sheet of claim 1, further comprising a contact layer comprising about between 5% w/w to about 45% w/w PCL or PHA or a mixture thereof;

and a mixture of PBS and PBSA, a mixture of PBS and PLA, a mixture of PBSA and PLA, or a mixture of PBAT and PLA, in an amount of about 95% w/w to about 55% w/w.

19. The multi-layered biodegradable sheet of claim 1, wherein at least one layer consists of about 60% PLA and about 40% PCL w/w of the layer.