Biochars and biochar treatment processes

• US 10,252,951 B2
• Filed: 10/01/2015
• Issued: 04/09/2019
• Est. Priority Date: 06/06/2011
• Status: Active Grant

• Current Assignee: Carbon Technology Holding LLC
• Original Assignee: Cool Planet Energy Systems, Inc.
• Inventors: Bontchev, Ranko Panayotov, Kim, Han Suk, Belcher, Richard Wilson, Jarand, Mark L.
• Primary Examiner(s): Langel, Wayne A
• Application Number:
  US14/873,053
• Publication Number:
  US 20160023959A1
• Time in Patent Office: 1,286 Days
• CPC Class Codes: C05D 9/00 Other inorganic fertilisers
• CPC Class Codes: C05D 9/02 containing trace elements
• CPC Class Codes: C05F 11/00 Other organic fertilisers
• CPC Class Codes: C05F 11/02 from peat, brown coal, and similar vegetable deposits
• CPC Class Codes: C05F 11/08 Organic fertilisers containing added bacterial cultures, mycelia or the like
• CPC Class Codes: C05G 3/00 Mixtures of one or more fertilisers with additives not having a specially fertilising activity
• CPC Class Codes: C05G 3/80 Soil conditioners
• CPC Class Codes: C09K 17/04 applied in a physical form other than a solution or a grout, e.g. as granules or gases
• CPC Class Codes: C10B 53/02 of cellulose-containing material production of pyroligneous acid C10C5/00
• CPC Class Codes: C10B 57/02 Multi-step carbonising or coking processes
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02P 20/145 the feedstock being materials of biological origin
• CPC Class Codes: Y10S 71/903 Soil conditioner

Abstract

Treated biochar and methods for treating biochar are provided. The method for treating the biochar includes forcing, assisting or accelerating the movement of an infiltrant into the pores of the biochar, whereby the treatment affects properties of the biochar that provide for a more reliable and predictable biochar for use in various applications, including, but not limited to, agricultural applications.

Claims

1. A method for treating a porous carbonaceous material having a plurality of pores for use for facilitating plant growth, the method comprising the steps of:

placing the porous carbonaceous material in a vessel capable of sustaining pressure change, where the vessel has an original pressure;

adding a treating liquid to the vessel at the vessel'"'"'s original pressure, where the treating liquid is water; and

varying the pressure in the vessel where such pressure in the vessel is varied for a predetermined period of at least 60 seconds before ceasing such pressure variation and returning the pressure in the vessel to its original pressure or to atmospheric pressure without removing the porous carbonaceous material or treating liquid from the vessel, wherein the pressure in the vessel is changed using a mechanism other than exclusively through the use of steam, and where at least a portion of the treating liquid is forced into the pores of the porous carbonaceous materials when the pressure in the vessel is varied to wash the pores of the porous carbonaceous material and remove phytotoxic compounds from the pores of the porous carbonaceous material.

2. The method of claim 1 where the treating liquid is added to the vessel before the pressure in the vessel is changed.

3. The method of claim 1 where the treating liquid is added to the vessel while the pressure in the vessel is changed.

4. The method of claim 1 where acetic acid is added to the treating liquid.

5. The method of claim 4 where the treating liquid adjusts the pH of the surface of the pores of the porous carbonaceous material.

6. The method of claim 1 further comprising the steps of moisture adjusting the porous carbonaceous material by at least partially drying the porous carbonaceous material.

7. The method of claim 6 where the pressure is changed in the vessel by either pulling a vacuum on the vessel or applying positive pressure on the content of the vessel.

8. The method of claim 6 further comprising the steps of inoculating the pores of the porous carbonaceous material with an additive.

9. The method of claim 8 where the porous carbonaceous material is inoculated by placing the porous carbonaceous material in a vessel;

adding inoculate solution to the vessel; and

changing the pressure in the vessel.

10. The method of claim 9 where the additive is selected from the group consisting of water, liquid inorganic and organic compounds of different composition and polarity, water solutions of salts, water solutions of acids, water solutions of bases, water solutions of organic compounds, water solutions of inorganic compounds, liquid organic compounds, liquid inorganic compounds, solvents, mineral oils, organic oils, turpentine, olive oil, palm oil, mineral extracts, organic extracts, extracts containing organic compounds, extracts of inorganic compounds, slurries, suspensions, slurries comprising solid phases including inorganic oxides, hydroxides, salts, organometallic complexes, nano-dispersed solids, micro-dispersed solids, carbon-based clusters, and fine particles, and supercritical liquids.

11. The method of claim 1 further comprising the step of adding a surfactant solution to the vessel.

12. The method of claim 1 where the phytotoxic compounds removed from the pores are soluble in the treating liquid.

13. The method of claim 1 where the treated liquid is added to the vessel prior to placing the porous carbonaceous material in the vessel.

14. A method for treating a porous carbonaceous material having a plurality of pores, the method comprising combining the porous carbonaceous material with an infiltrant and then forcing, assisting or accelerating the movement of at least part of the infiltrant into the pores of the porous carbonaceous material by applying a vacuum or positive pressure to the environment surrounding the porous carbonaceous material and the infiltrant for a predetermined time to wash the pores of the porous carbonaceous material with the infiltrant and then ceasing the application of the vacuum or positive pressure while the porous carbonaceous material is still combined with the infiltrant, and where the method does not include the exclusive use of steam to force, assist or accelerate movement of the infiltrant into the pores of the porous carbonaceous material, and where at least 10% of the pores by volume are filled by the infiltrant remaining in the pores of the porous carbonaceous material after the vacuum or positive pressure is applied for such predetermined time;

and drying the porous carbonaceous material to a moisture content of 10-50% by weight.

15. The method of claim 14 where the infusion treatment process uses a surfactant to assist the infiltrant into the pores of the porous carbonaceous material.

16. The method of claim 14 where the infiltrant contains an acidic or alkaline water based solution.

17. The method of claim 14 where vacuum or positive pressure is applied to the environment surrounding the pores and is applied at temperatures of less than 100 degrees Celsius.

18. A method for treating a porous carbonaceous material having a plurality of pores for use for facilitating plant growth, the method comprising the steps of:

placing the porous carbonaceous material in a vessel capable of sustaining pressure change, where the porous carbonaceous material has an initial pH;

adding a treating liquid to the vessel, where the treating liquid is an acidic or alkaline water based solution water; and

changing the pressure in the vessel after the treating liquid is added to the vessel through a mechanism other than exclusively through the use of steam in order to infuse at least part of the treating liquid into the pores of the porous carbonaceous material in the vessel, wherein infusing the treating liquid into the pores of the porous carbonaceous material changes the initial pH of the porous carbonaceous material in the vessel and then adjusting the moisture of the porous carbonaceous material to 30-50% by weight by removing at least part of the treating liquid infused into the pores of the porous carbonaceous material using a centrifugal dewatering system.

19. The method of claim 18, where, after the porous carbonaceous material is moisture adjusted, the porous carbonaceous material and an additive are placed in the vessel and the pressure in the vessel is again changed to infuse at least part of the additive into the pores of the porous carbonaceous material in the vessel.